Differential cross sections for muonic atom scattering in solid hydrogenic targets

The differential cross sections for low-energy muonic hydrogen atom scattering in solid molecular H$_2$, D$_2$ and T$_2$ targets under low pressure have been calculated for various temperatures. The polycrystalline fcc and hcp structure of the solid hydrogenic targets are considered. The Bragg and phonon scattering processes are described using the Debye model of a solid. The calculated cross sections are used for Monte Carlo simulations of the muonic atom slowing down in these targets. They have been successfully applied for a description of the production of the muonic atom beams in the multilayer hydrogenic crystals.Comment: 23 pages, 19 figures, 2 table

Mechanistic origin of the stereodivergence in decarboxylative allylation

A stereochemical test has been used to probe the mechanism of decarboxylative allylation. This probe suggests that the mechanism of DcA reactions can change based on the substitution pattern at the α-carbon of the nucleophile, however reaction via stabilized malonate nucleophiles is the lower energy pathway. Lastly, this mechanistic proposal has predictive power and can be used to explain chemoselectivities in decarboxylative reactions that were previously confounding

Модернизация технологического процесса механической обработки детали ступица КЗК 12-0602605 с разработкой проекта участка цеха, средств технологического оснащения и исследованием электрохимического шлифования

Bimetallic Pd/Cu and Pd/Ag catalytic systems were used for borylation of propargylic alcohol derivatives. The substrate scope includes even terminal alkynes. The reactions proceed stererospecifically with formal S(N)2' pathways to give allenyl boronates. Opening of propargyl epoxides leads to 1,2-diborylated butadienes probably via en allenylboronate intermediate.AuthorCount:4;</p

Propagation of uncertainty in a rotating pipe mechanism to generate an impinging swirling jet flow for heat transfer from a flat plate

In Computational Fluid Dynamics (CFD) studies composed of the coupling of different simulations, the uncertainty in one stage may be propagated to the following stage and affect the accuracy of the prediction. In this paper, a framework for uncertainty quantification in the computational heat transfer by forced convection is applied to the two-step simulation of the mechanical design of a swirling jet flow generated by a rotating pipe (Simulation 1) impinging on a flat plate (Simulation 2). This is the first probabilistic uncertainty analysis on computational heat transfer by impinging jets in the literature. The conclusion drawn from the analysis of this frequent engineering application is that the simulated system does not exhibit a significant sensitivity to stochastic variations of model input parameters, over the tested uncertainty ranges. Additionally, a set of non-linear regression models for the stochastic velocity and turbulent profiles for the pipe nozzle are created and tested, since impinging jets for heat transfer at Reynolds number of Re = 23000 are very frequent in the literature, but stochastic inlet conditions have never been provided. Numerical results demonstrate a negligible difference in the predicted convective heat transfer with respect to the use of the profiles simulated via CFD. These suggested surrogate models can be directly embedded onto other engineering applications (e.g. arrays of jets, jet flows impinging on plates with different shapes, inlet piping in combustion, chemical mixing, etc.) in which a realistic swirling flow under uncertainty can be of interest

Atomic collision experiment using ultra-slow antiproton beams

The development of techniques to decelerate, cool and confine antiprotons in vacuo with an electromagnetic trap has opened a new research field of atomic physics of 'cold' antiprotons, including synthesis of antihydrogen atoms. At the Antiproton Decelerator (AD) facility at CERN, we the MUSASHI group of ASACUSA collaboration have so far achieved efficient confinement of millions of antiprotons in a Multi-Ring electrode Trap (MRT) installed in a superconducting magnet of 2.5 T, by a sequential combination of the AD (down to 5.3 MeV), an RFQD (Radio-Frequency Quadrupole Decelerator; down to 50–120 keV) and the MRT. Antiprotons, cooled to energies less than an electronvolt by preloaded electrons in the trap, was then extracted out of the magnetic field and transported along a 3-m beamline as a monoenergetic beam of 10–500 eV. With this unique ultra-low-energy antiproton beam, we are now planning the first atomic collision experiments under single collision conditions, to measure ionization and atomic capture cross sections of antiprotons against helium atoms. A supersonic atomic gas-jet target is prepared and crossed with the antiproton beam. Antiprotons as well as electrons emitted during the reaction will be detected by a microchannel plate (MCP) while the antiproton annihilation will be recognized by detection of annihilation products—mostly pions—by surrounding scintillation counters. When the antiproton is captured, it forms a neutral antiprotonic helium atom, some in a metastable state whose level structures have been well studied with spectroscopic methods. Severe identification of particles and atoms plays an essential role in the design of the experiment, to distinguish the small number of reaction events out of a huge pile of background events. Our strategies for our near-future experiments are discussed