Cluster Based Symbolic Representation for Skewed Text Categorization

In this work, a problem associated with imbalanced text corpora is addressed. A method of converting an imbalanced text corpus into a balanced one is presented. The presented method employs a clustering algorithm for conversion. Initially to avoid curse of dimensionality, an effective representation scheme based on term class relevancy measure is adapted, which drastically reduces the dimension to the number of classes in the corpus. Subsequently, the samples of larger sized classes are grouped into a number of subclasses of smaller sizes to make the entire corpus balanced. Each subclass is then given a single symbolic vector representation by the use of interval valued features. This symbolic representation in addition to being compact helps in reducing the space requirement and also the classification time. The proposed model has been empirically demonstrated for its superiority on bench marking datasets viz., Reuters 21578 and TDT2. Further, it has been compared against several other existing contemporary models including model based on support vector machine. The comparative analysis indicates that the proposed model outperforms the other existing models.Comment: 14 Pages, 15 Figures, 1 Table, Conference: RTIP2

Kinetics and mechanism of oxidation of erythro-series pentoses and hexoses by N-chloro-p-toluenesulfonamide

The kinetics and mechanism of oxidation of D-glucose, D-mannose, D-fructose, D-arabinose, and D-ribose with chloramine-T in alkaline medium were studied. The rate law, rate = k Chloramine-T] Sugar] HO-](2), was observed. The rate of the reaction was influenced by a change in ionic strength of the medium, and the dielectric effect was found to be negative. The latter enabled the computation of d(AB), the size of the activated complex. The reaction rate was almost doubled in deuterium oxide. Activation energies were calculated from the Arrhenius plots. HPLC and GLC-MS analyses of the products indicated that the sugars were oxidized to a mixture of aldonic acids, consisting of arabinonic, ribonic, erythronic, and glyceric acids. Based on these data, a plausible mechanism involving the aldo-enolic anions of pentoses and keto-enolic anions of hexoses is suggested. (C) 1998 Elsevier Science Ltd. All rights reserved

Synthesis and characterization of palladium(II) complexes with 1,​2-​bis(N-​methylbenzimidazolyl)​benzene

Palladium(II) salts react with a bidentate N-​heterocycle 1,​2-​bis(N-​methylbenzimidazolyl)​benzene (N-​N) to yield complexes of the compn. PdX2(N-​N) (X = Cl, Br or ClO4)​. A cationic complex, [Pd(cod)​(cotl)​]​ClO4 (cod = 1,​5-​cyclooctadiene, cotl = cyclooctenyl, C8H13-​) undergoes substitution of cod with N-​N to produce [Pd(cotl)​(N-​N)​]​ClO4. Dihalobridged binuclear complexes [PdX(cotl)​]​2 (X = Cl or Br) react with N-​N to give complexes of the types [Pd2Cl2(cotl)​(N-​N)​]​Cl and [{PdBr(cotl)​}​2(N-​N)​]​

Multicenter Validation of the Vasoactive-Ventilation-Renal Score as a Predictor of Prolonged Mechanical Ventilation After Neonatal Cardiac Surgery

Objectives: We sought to validate the Vasoactive-Ventilation-Renal score, a novel disease severity index, as a predictor of outcome in a multicenter cohort of neonates who underwent cardiac surgery. Design: Retrospective chart review. Setting: Seven tertiary-care referral centers. Patients: Neonates defined as age less than or equal to 30 days at the time of cardiac surgery. Interventions: Ventilation index, Vasoactive-Inotrope Score, serum lactate, and Vasoactive-Ventilation-Renal score were recorded for three postoperative time points: ICU admission, 6 hours, and 12 hours. Peak values, defined as the highest of the three measurements, were also noted. Vasoactive-Ventilation-Renal was calculated as follows: ventilation index + Vasoactive-Inotrope Score + Δ creatinine (change in creatinine from baseline × 10). Primary outcome was prolonged duration of mechanical ventilation, defined as greater than 96 hours. Receiver operative characteristic curves were generated, and abilities of variables to correctly classify prolonged duration of mechanical ventilation were compared using area under the curve values. Multivariable logistic regression modeling was also performed. Measurements and Main Results: We reviewed 275 neonates. Median age at surgery was 7 days (25th–75th percentile, 5–12 d), 86 (31%) had single ventricle anatomy, and 183 (67%) were classified as Society of Thoracic Surgeons-European Association for Cardio-Thoracic Surgery Congenital Heart Surgery Mortality Category 4 or 5. Prolonged duration of mechanical ventilation occurred in 89 patients (32%). At each postoperative time point, the area under the curve for prolonged duration of mechanical ventilation was significantly greater for the Vasoactive-Ventilation-Renal score as compared to the ventilation index, Vasoactive-Inotrope Score, and serum lactate, with an area under the curve for peak Vasoactive-Ventilation-Renal score of 0.82 (95% CI, 0.77–0.88). On multivariable analysis, peak Vasoactive-Ventilation-Renal score was independently associated with prolonged duration of mechanical ventilation, odds ratio (per 1 unit increase): 1.08 (95% CI, 1.04–1.12). Conclusions: In this multicenter cohort of neonates who underwent cardiac surgery, the Vasoactive-Ventilation-Renal score was a reliable predictor of postoperative outcome and outperformed more traditional measures of disease complexity and severity

Long-term application of fertilizers on chemical and biological properties of an Alfisol

A long term fertilizer experiment (30 years) at Bengaluru had been started during 1986 with eleven treat-ments and four replications in an Alfisol on finger millet (Elusine coracana) maize (Zea mays) cropping sequence. The results of the ongoing experiment after 27 cycles of finger millet and maize on changes in soil chemical proper-ties revealed that application of inorganics alone resulted in impaired soil fertility status (soil pH, organic carbon con-tent and available nutrients in soil were decreased) over balanced fertilizer application. There was a decline in soil reaction over the initial status and the maximum decrease was observed in 100 % NP (-1.46), 100 % N (-1.20) and other treatments. Application of 100 % NPK+FYM+lime maintained the soil pH (6.2) compared to all the other treat-ments. Organic carbon content of soil in all the treatments was higher (6.46 g kg-1) compared to the initial status; however, maximum increase in organic carbon content was registered on application of NPK+FYM. Application of 10 t ha-1 along with recommended dose of fertilizers and lime was found promising in term of sustaining crop and soil productivity

Lepidorbitoides (Foraminifera) from the lower Maastrichtian Kallankuruchchi Formation, Cauvery Basin, India: Morphometry and paleobiogeography

The southernmost occurrence of the early Maastrichtian larger benthic foraminifera (LBF) in Tethys is known from the Kallankuruchchi Formation in the Cauvery Basin, SE India, represented by Lepidorbitoides-Siderolites assemblages. The systematics, age and paleobiogeography of Lepidorbitoides here have as yet remained unresolved due to lack of information particularly on the nepionic arrangement, whereas their links with the Western Tethyan and Caribbean biogeographic domains were speculated. Lepidorbitoides, studied from the same level in seven samples in two separate areas, invariably possess quadriserial nepionts and adauxiliary chamberlets, whose mean number ranges from 3.79 to 4.67. The ratio between the sample means of the internal diameter of deuteroconch and protoconch varies between 1.72 and 1.86. The equatorial layer in the early stage consists of arcuate chambers with basal stolons, and ogival-to spatulate chamberlets with annular and oblique stolons in the later stages. These features are consistent with the phylogenetically advanced members of the Western Tethyan Lepidorbitoides lineage, such as L. minor (Schlumberger) and L. socialis (Leymerie), and all samples were assigned to the transitional development stages of these species based on the morphometry. The taxonomic status of some Lepidorbitoides species, originally described from the Kallankuruchchi Formation and widely adopted in previous works, such as L. blanfordi (Rao) and L. inornata (Rao), are not justified. We extend the geographic range of Western Tethyan Lepidorbitoides to southern India. © 2017 Elsevier Lt