1,438 research outputs found
Fast electrochemical doping due to front instability in organic semiconductors
The electrochemical doping transformation in organic semiconductor devices is
studied in application to light-emitting cells. It is shown that the device
performance can be significantly improved by utilizing new fundamental
properties of the doping process. We obtain an instability, which distorts the
doping fronts and increases the doping rate considerably. We explain the
physical mechanism of the instability, develop theory, provide experimental
evidence, and perform numerical simulations. We further show how improved
device design can amplify the instability thus leading to a much faster doping
process and device kinetics.Comment: 4 pages, 4 figure
Systematic Theory for Curriculum Development and Instruction in an Elementary School
Elementary Educatio
Synchronization of active mechanical oscillators by an inertial load
Motivated by the operation of myogenic (self-oscillatory) insect flight
muscle, we study a model consisting of a large number of identical oscillatory
contractile elements joined in a chain, whose end is attached to a damped
mass-spring oscillator. When the inertial load is small, the serial coupling
favors an antisynchronous state in which the extension of one oscillator is
compensated by the contraction of another, in order to preserve the total
length. However, a sufficiently massive load can sychronize the oscillators and
can even induce oscillation in situations where isolated elements would be
stable. The system has a complex phase diagram displaying quiescent,
synchronous and antisynchrononous phases, as well as an unsual asynchronous
phase in which the total length of the chain oscillates at a different
frequency from the individual active elements.Comment: 5 pages, 4 figures, To appear in Phys. Rev. Let
Inter-Intra Molecular Dynamics as an Iterated Function System
The dynamics of units (molecules) with slowly relaxing internal states is
studied as an iterated function system (IFS) for the situation common in e.g.
biological systems where these units are subjected to frequent collisional
interactions. It is found that an increase in the collision frequency leads to
successive discrete states that can be analyzed as partial steps to form a
Cantor set. By considering the interactions among the units, a self-consistent
IFS is derived, which leads to the formation and stabilization of multiple such
discrete states. The relevance of the results to dynamical multiple states in
biomolecules in crowded conditions is discussed.Comment: 7 pages, 7 figures. submitted to Europhysics Letter
Highly efficient organic light-emitting diodes and light-emitting electrochemical cells employing multiresonant thermally activated delayed fluorescent emitters with bulky donor or acceptor peripheral groups
Jingxiang Wang thanks the China Scholarship Council (202006250026). We thank the Engineering and Physical Sciences Research Council (EP/R035164/1, EP/W015137/1, and EP/W007517/1) for support. Ludvig Edman and Shi Tang acknowledge financial support from the Swedish Research Council (2019-02345 and 2021–04778), the Swedish Energy Agency (50779-1 and P2021-00032), the Wallenberg Initiative Materials Science for Sustainability (WISE) funded by the Knut and Alice Wallenberg Foundation (WISE-AP01-D02), and the European Research Council for an ERC Advanced Grant (Project 101096650).Multiresonant thermally activated delayed fluorescence (MR-TADF) emitters have been the focus of extensive design efforts as they are recognized to show bright, narrowband emission, which makes them very appealing for display applications. However, the planar geometry and relatively large singlet?triplet energy gap lead to, respectively, severe aggregation-caused quenching (ACQ) and slow reverse intersystem crossing (RISC). Here, a design strategy is proposed to address both issues. Two MR-TADF emitters triphenylphosphine oxide (TPPO)-tBu-DiKTa and triphenylamine (TPA)-tBu-DiKTa have been synthesized. Twisted ortho-substituted groups help increase the intermolecular distance and largely suppress the ACQ. In addition, the contributions from intermolecular charge transfer states in the case of TPA-tBu-DiKTa help to accelerate RISC. The organic light-emitting diodes (OLEDs) with TPPO-tBu-DiKTa and TPA-tBu-DiKTa exhibit high maximum external quantum efficiencies (EQEmax) of 24.4% and 31.0%, respectively. Notably, the device with 25 wt% TPA-tBu-DiKTa showed both high EQEmax of 28.0% and reduced efficiency roll-off (19.9% EQE at 1000 cd m?2) compared to the device with 5 wt% emitter (31.0% EQEmax and 11.0% EQE at 1000 cd m?2). The new emitters were also introduced into single-layer light-emitting electrochemical cells (LECs), equipped with air-stable electrodes. The LEC containing TPA-tBu-DiKTa dispersed at 0.5 wt% in a matrix comprising a mobility-balanced blend-host and an ionic liquid electrolyte delivered blue luminance with an EQEmax of 2.6% at 425 cd m?2. The high efficiencies of the OLEDs and LECs with TPA-tBu-DiKTa illustrate the potential for improving device performance when the DiKTa core is decorated with twisted bulky donors.Peer reviewe
Survival and residence times in disordered chains with bias
We present a unified framework for first-passage time and residence time of
random walks in finite one-dimensional disordered biased systems. The
derivation is based on exact expansion of the backward master equation in
cumulants. The dependence on initial condition, system size, and bias strength
is explicitly studied for models with weak and strong disorder. Application to
thermally activated processes is also developed.Comment: 13 pages with 2 figures, RevTeX4; v2:minor grammatical changes, typos
correcte
Glucocorticoid receptor Thr524 phosphorylation by MINK1 induces interactions with 14-3-3 protein regulators
The glucocorticoid receptor (GR) is a ligand-dependent transcription factor that plays a central role in inflammation. The GR activity is also modulated via protein-protein interactions, including binding of 14-3-3 proteins induced by GR phosphorylation. However, the specific phosphorylation sites on the GR that trigger these interactions and their functional consequences are less clear. Hence, we sought to examine this system in more detail. We used phosphorylated GR peptides, biophysical studies, and X-ray crystallography to identify key residues within the ligand-binding domain of the GR, T524 and S617, whose phosphorylation results in binding of the representative 14-3-3 protein 14-3-3ζ. A kinase screen identified misshapen-like kinase 1 (MINK1) as responsible for phosphorylating T524 and Rho-associated protein kinase 1 for phosphorylating S617; cell-based approaches confirmed the importance of both GR phosphosites and MINK1 but not Rhoassociated protein kinase 1 alone in inducing GR-14-3-3 binding. Together our results provide molecular-level insight into 14-3-3-mediated regulation of the GR and highlight both MINK1 and the GR-14-3-3 axis as potential targets for future therapeutic intervention
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