Ionic Capillary Evaporation in Weakly Charged Nanopores

Using a variational field theory, we show that an electrolyte confined to a neutral cylindrical nanopore traversing a low dielectric membrane exhibits a first-order ionic liquid-vapor pseudo-phase-transition from an ionic-penetration "liquid" phase to an ionic-exclusion "vapor" phase, controlled by nanopore-modified ionic correlations and dielectric repulsion. For weakly charged nanopores, this pseudotransition survives and may shed light on the mechanism behind the rapid switching of nanopore conductivity observed in experiments.Comment: This version is accepted for publication in PR

Bubbly cavitating flow generation and investigation of its erosional nature for biomedical applications

This paper was presented at the 2nd Micro and Nano Flows Conference (MNF2009), which was held at Brunel University, West London, UK. The conference was organised by Brunel University and supported by the Institution of Mechanical Engineers, IPEM, the Italian Union of Thermofluid dynamics, the Process Intensification Network, HEXAG - the Heat Exchange Action Group and the Institute of Mathematics and its Applications.The paper presents a study of the generation of hydrodynamic bubbly cavitation in microchannels to investigate the destructive energy output resulting from this phenomenon and its potential use in biomedical applications. The research performed in this study includes the experimental results from bubbly cavitation experiments and the findings showing the destructive effects of bubbly cavitating flow on selected specimens and cells. The bubbles caused by hydrodynamic cavitation are highly destructive at the surfaces of the target medium on which they are carefully focused. The resulting destructive energy output could be effectively used for good means such as destroying kidney stones or killing infected cancer cells. Motivated by this potential, the cavitation damage (material removal) to cancerous cells and chalk pieces having similar material properties as calcium phosphate in human bones was investigated. Also the potential of hydrodynamic bubbly cavitation generated at the microscale for biomedical treatments was revealed using the microchannel configuration of a microorifice (with an inner diameter of 0.147 mm and a length of 1.52cm).This work was supported by Sabancı University Internal Grant for Research Program under Grant FRG-C47004

Optical implementations of two-dimensional fractional Fourier transforms and linear canonical transforms with arbitrary parameters

Cataloged from PDF version of article.We provide a general treatment of optical two-dimensional fractional Fourier transforming systems. We not only allow the fractional Fourier transform orders to be specified independently for the two dimensions but also allow the input and output scale parameters and the residual spherical phase factors to be controlled. We further discuss systems that do not allow all these parameters to be controlled at the same time but are simpler and employ a fewer number of lenses. The variety of systems discussed and the design equations provided should be useful in practical applications for which an optical fractional Fourier transforming stage is to be employed. © 1998 Optical Society of Americ

Variational approach for electrolyte solutions: from dielectric interfaces to charged nanopores

A variational theory is developed to study electrolyte solutions, composed of interacting point-like ions in a solvent, in the presence of dielectric discontinuities and charges at the boundaries. Three important and non-linear electrostatic effects induced by these interfaces are taken into account: surface charge induced electrostatic field, solvation energies due to the ionic cloud, and image charge repulsion. Our variational equations thus go beyond the mean-field theory. The influence of salt concentration, ion valency, dielectric jumps, and surface charge is studied in two geometries. i) A single neutral air-water interface with an asymmetric electrolyte. A charge separation and thus an electrostatic field gets established due to the different image charge repulsions for coions and counterions. Both charge distributions and surface tension are computed and compared to previous approximate calculations. For symmetric electrolyte solutions close to a charged surface, two zones are characterized. In the first one, with size proportional to the logarithm of the coupling parameter, strong image forces impose a total ion exclusion, while in the second zone the mean-field approach applies. ii) A symmetric electrolyte confined between two dielectric interfaces as a simple model of ion rejection from nanopores. The competition between image charge repulsion and attraction of counterions by the membrane charge is studied. For small surface charge, the counterion partition coefficient decreases with increasing pore size up to a critical pore size, contrary to neutral membranes. For larger pore sizes, the whole system behaves like a neutral pore. The prediction of the variational method is also compared with MC simulations and a good agreement is observed.Comment: This version is accepted for publication in Phys. Rev. E

Reprint of: The potential role of desalination in managing flood risks from dam overflows: the case of Sydney, Australia

© 2016 Elsevier Ltd Shifting climate patterns are causing extreme drought and flooding across the globe. This combined with the world's burgeoning population and insatiable thirst for water requires water service providers to think differently about the limited resources they manage. In Australia, the severe drought at the beginning of the century caused dams to fall to record levels. In response, many state governments invested heavily in rain-independent supplies such as desalination to augment and diversify traditional sources. However, extreme rainfall soon followed the drought, filled reservoirs and caused flooding in many locations leaving billions of dollars worth of damage and new water infrastructure standing idle. This is the case in Sydney, where the new desalination plant is still not used and the potential for major flooding has raised concerns over the safety of the large population downstream of the dam. This paper explores the growing need to understand the relationship between drought, flooding and infrastructure optimisation. The paper focuses on Sydney to illustrate the application of a system dynamics model. The new model explores options for raising the dam wall, offering airspace to assist flood protection, in contrast to options to lower the dam full supply level and utilise idle desalination capacity to fill the water security gap created. The illustrative results, using publicly available data, find that by lowering the dam water levels and operating desalination, significant flood protection can be achieved at a similar cost to raising the dam wall. The paper demonstrates the importance of optimising existing and new water resources for multiple purposes and how system dynamics modelling can assist water service providers in these complex investigations

Modelling the behaviour of microbulk Micromegas in Xenon/trimethylamine gas

We model the response of a state of the art micro-hole single-stage charge amplication device (`microbulk' Micromegas) in a gaseous atmosphere consisting of Xenon/trimethylamine at various concentrations and pressures. The amplifying structure, made with photo-lithographic techniques similar to those followed in the fabrication of gas electron multipliers (GEMs), consisted of a 100 um-side equilateral-triangle pattern with 50 um-diameter holes placed at its vertexes. Once the primary electrons are guided into the holes by virtue of an optimized field configuration, avalanches develop along the 50 um-height channels etched out of the original doubly copper-clad polyimide foil. In order to properly account for the strong field gradients at the holes' entrance as well as for the fluctuations of the avalanche process (that ultimately determine the achievable energy resolution), we abandoned the hydrodynamic framework, resorting to a purely microscopic description of the electron trajectories as obtained from elementary cross-sections. We show that achieving a satisfactory description needs additional assumptions about atom-molecule (Penning) transfer reactions and charge recombination to be made

Physical exercise and prevention of falls. Effects of a Pilates training method compared with a general physical activity program A randomized controlled trial

Introduction: Falls are the leading cause of injury-related mortality and morbidity in the elderly. Physical activity plays a key role in the prevention of falls and stimulates postural control. The aim of this study was to compare a general physical activity program for the elderly with a Pilates program to evaluate the effects on balance and on reducing the risk of falling. Materials and Methods: Forty-six subjects were enrolled in this study, but only 41 were included in the study. The subjects were divided into 2 groups: Pilates group (P-G) and a group following a nonspecific program of physical activity (Pa-G). Each subject underwent the hand grip test, Berg balance scale test, and posturographic analysis. Results: Spearman correlation coefficient showed correlations between the following parameters: BBS versus hand grip test (r = 0.68); BBS versus ellipse surface area (r = -0.75). There were significant differences between groups after the exercise program: both groups showed an improvement in performance but the P-G recorded significantly better results than the Pa-G. Discussion and conclusions: This study confirmed that physical activity improves both balance and strength. However, our data show that Pilates has a greater effect on these physical abilities than a general physical activity program

Intersected EMG heatmaps and deep learning based gesture recognition

Hand gesture recognition in myoelectric based prosthetic devices is a key challenge to offering effective solutions to hand/lower arm amputees. A novel hand gesture recognition methodology that employs the difference of EMG energy heatmaps as the input of a specific designed deep learning neural network is presented. Experimental results using data from real amputees indicate that the proposed design achieves 94.31% as average accuracy with best accuracy rate of 98.96%. A comparison of experimental results between the proposed novel hand gesture recognition methodology and other similar approaches indicates the superior effectiveness of the new design

A new approach to sensitivity climatologies: the DTS-MEDEX-2009 campaign

Adaptive observation is an approach to improving the quality of numerical weather forecasts through the optimization of observing networks. It is sometimes referred to as Data Targeting (DT). This approach has been applied to high impact weather during specific field campaigns in the past decade. Adaptive observations may involve various types of observations, including either specific research observing platforms or routine observing platforms employed in an adaptive way. The North-Atlantic TReC 2003 and the EURORISK-PREVIEW 2008 exercises focused on the North-Atlantic and Western Europe areas using mainly routine observing systems. These campaigns also included Mediterranean cases. <br><br> The most recent campaign, DTS-MEDEX-2009, is the first campaign in which the DT method has been used to address exclusively Mediterranean high impact weather events. In this campaign, which is an important stage in the MEDEX development, only operational radiosonde stations and commercial aircraft data (AMDAR) have provided additional observations. Although specific diagnostic studies are needed to assess the impact of the extra-observations on forecast skill and demonstrate the effectiveness of DTS-MEDEX-2009, some preliminary findings can be deduced from a survey of this targeting exercise. <br><br> After a description of the data targeting system and some illustrations of particular cases, this paper attempts some comparisons of additional observation needs (through effectively deployed radio-soundings) with sensitivity climatologies in the Mediterranean. The first step towards a sensitivity climatology for Mediterranean cases of high impact weather is indirectly given by the frequency of extra-soundings launched from the network of radiosonde stations involved in the DTS-MEDEX-2009 campaign