Suspect screening and total oxidizable precursor (TOP) assay as tools for characterization of per- and polyfluoroalkyl substance (PFAS)-contaminated groundwater and treated landfill leachate

Landfill facilities are a major source of release of per- and polyfluoroalkyl substances (PFAS) to the surrounding environment. In this study, landfill leachate treated in a conventional wastewater treatment plant and PFAScontaminated groundwater were subjected to suspect screening analysis and semi-quantification using total oxidizable precursor (TOP) assay and liquid chromatography coupled to high-resolution mass spectrometry (LCHRMS). TOP assays yielded expected results for legacy PFAS and their precursors, but showed no discernible evidence of degradation of perfluoroethylcyclohexane sulfonic acid. TOP assays also produced significant evidence of presence of precursors in both treated landfill leachate and groundwater, but the majority of precursors had probably degraded into legacy PFAS after many years in the landfill. Suspect screening identified a total of 28 PF AS, of which six were not included in the targeted method and were identified with confidence level (CL) ≥3. Semi-quantification of these six compounds showed very low concentrations, indicating that they are not as great a concern as the target PFAS

On the nature of amorphous polymorphism of water

We report elastic and inelastic neutron scattering experiments on different amorphous ice modifications. It is shown that an amorphous structure (HDA') indiscernible from the high-density phase (HDA), obtained by compression of crystalline ice, can be formed from the very high-density phase (vHDA) as an intermediate stage of the transition of vHDA into its low-density modification (LDA'). Both, HDA and HDA' exhibit comparable small angle scattering signals characterizing them as structures heterogeneous on a length scale of a few nano-meters. The homogeneous structures are the initial and final transition stages vHDA and LDA', respectively. Despite, their apparent structural identity on a local scale HDA and HDA' differ in their transition kinetics explored by in situ experiments. The activation energy of the vHDA-to-LDA' transition is at least 20 kJ/mol higher than the activation energy of the HDA-to-LDA transition

Experimental observation of an enhanced anisotropic magnetoresistance in non-local configuration

We compare non-local magnetoresistance measurements in multi-terminal Ni nanostructures with corresponding local experiments. In both configurations, the measured voltages show the characteristic features of anisotropic magnetoresistance (AMR). However, the magnitude of the non-local AMR signal is up to one order of magnitude larger than its local counterpart. Moreover, the non-local AMR increases with increasing degree of non-locality, i.e., with the separation between the region of the main current flow and the voltage measurement region. All experimental observations can be consistently modeled in terms of current spreading in a non-isotropic conductor. Our results show that current spreading can significantly enhance the magnetoresistance signal in non-local experiments

Magnetic microstructure and magnetotransport in Co2FeAl Heusler compound thin films

We correlate simultaneously recorded magnetotransport and spatially resolved magneto optical Kerr effect (MOKE) data in Co2FeAl Heusler compound thin films micropatterned into Hall bars. Room temperature MOKE images reveal the nucleation and propagation of domains in an externally applied magnetic field and are used to extract a macrospin corresponding to the mean magnetization direction in the Hall bar. The anisotropic magnetoresistance calculated using this macrospin is in excellent agreement with magnetoresistance measurements. This suggests that the magnetotransport in Heusler compounds can be adequately simulated using simple macrospin models, while the magnetoresistance contribution due to domain walls is of negligible importance

Spin Wave Excitation in Magnetic Insulator Thin Films by Spin-Transfer Torque

We describe excitation of dipole-exchange spin waves in insulating magnetic thin films by spin current injection at the surface of the film. An easy-axis magnetic surface anisotropy can induce a non-chiral surface spin wave mode with penetration depth inversely proportional to the strength of the surface anisotropy, which strongly reduces the critical current and enhances the excitation power. The importance of the interface spin wave modes on the excitation spectrum is reduced by spin pumping, which depends on the quality of the interface as expressed by the spin mixing conductance.Comment: 19 pages, 10 figure

Local charge and spin currents in magnetothermal landscapes

A scannable laser beam is used to generate local thermal gradients in metallic (Co2FeAl) or insulating (Y3Fe5O12) ferromagnetic thin films. We study the resulting local charge and spin currents that arise due to the anomalous Nernst effect (ANE) and the spin Seebeck effect (SSE), respectively. In the local ANE experiments, we detect the voltage in the Co2FeAl thin film plane as a function of the laser spot position and external magnetic field magnitude and orientation. The local SSE effect is detected in a similar fashion by exploiting the inverse spin Hall effect in a Pt layer deposited on top of the Y3Fe5O12. Our findings establish local thermal spin and charge current generation as well as spin caloritronic domain imaging

Giant magnetic anisotropy changes in Sr2CrReO6 thin films on BaTiO3

The integration of ferromagnetic and ferroelectric materials into hybrid heterostructures yields multifunctional systems with improved or novel functionality. We here report on the structural, electronic and magnetic properties of the ferromagnetic double perovskite Sr2CrReO6, grown as epitaxial thin film onto ferroelectric BaTiO3. As a function of temperature, the crystal-structure of BaTiO3 undergoes phase transitions, which induce qualitative changes in the magnetic anisotropy of the ferromagnet. We observe abrupt changes in the coercive field of up to 1.2T along with resistance changes of up to 6.5%. These results are attributed to the high sensitivity of the double perovskites to mechanical deformation.Comment: 3 figure

Epitaxial growth and magnetic properties of Sr2CrReO6 thin films

The double perovskite Sr2CrReO6 is an interesting material for spintronics, showing ferrimagnetism up to 635 K with a predicted high spin polarization of about 86%. We fabricated Sr2CrReO6 epitaxial films by pulsed laser deposition on (001)-oriented SrTiO3 substrates. Phase-pure films with optimum crystallographic and magnetic properties were obtained by growing at a substrate temperature of 700 degree C in pure O2 of 6.6x10-4 mbar. The films are c-axis oriented, coherently strained, and show less than 20% anti-site defects. The magnetization curves reveal high saturation magnetization of 0.8 muB per formula unit and high coercivity of 1.1 T, as well as a strong magnetic anisotropy.Comment: accepted for publicatio

Scaling behavior of the spin pumping effect in ferromagnet/platinum bilayers

We systematically measured the DC voltage V_ISH induced by spin pumping together with the inverse spin Hall effect in ferromagnet/platinum bilayer films. In all our samples, comprising ferromagnetic 3d transition metals, Heusler compounds, ferrite spinel oxides, and magnetic semiconductors, V_ISH invariably has the same polarity. V_ISH furthermore scales with the magnetization precession cone angle with a universal prefactor, irrespective of the magnetic properties, the charge carrier transport mechanism or type. These findings quantitatively corroborate the present theoretical understanding of spin pumping in combination with the inverse spin Hall effect