1,643 research outputs found

    Simulating the Phases of the Moon Shortly After Its Formation

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    The leading theory for the origin of the Moon is the giant impact hypothesis, in which the Moon was formed out of the debris left over from the collision of a Mars-sized body with the Earth. Soon after its formation, the orbit of the Moon may have been very different than it is today. We have simulated the phases of the Moon in a model for its formation wherein the Moon develops a highly elliptical orbit with its major axis tangential to the Earth's orbit. This note describes these simulations and their pedagogical value.Comment: 4 pages, 2 figure

    Selecting between two transition states by which water oxidation intermediates on an oxide surface decay

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    While catalytic mechanisms on electrode surfaces have been proposed for decades, the pathways by which the product's chemical bonds evolve from the initial charge-trapping intermediates have not been resolved in time. Here, we discover a reactive population of charge-trapping intermediates with states in the middle of a semiconductor's band-gap to reveal the dynamics of two parallel transition state pathways for their decay. Upon photo-triggering the water oxidation reaction from the n-SrTiO3 surface with band-gap, pulsed excitation, the intermediates' microsecond decay reflects transition state theory (TST) through: (1) two distinct and reaction dependent (pH, T, Ionic Strength, and H/D exchange) time constants, (2) a primary kinetic salt effect on each activation barrier and an H/D kinetic isotope effect on one, and (3) realistic activation barrier heights (0.4 - 0.5 eV) and TST pre-factors (10^11 - 10^12 Hz). A photoluminescence from midgap states in n-SrTiO3 reveals the reaction dependent decay; the same spectrum was previously assigned by us to hole-trapping at parallel Ti-O(dot)-Ti (bridge) and perpendicular Ti-O(dot) (oxyl) O-sites using in situ ultrafast vibrational and optical spectroscopy. Therefore, the two transition states are naturally associated with the decay of these respective intermediates. Furthermore, we show that reaction conditions select between the two pathways, one of which reflects a labile intermediate facing the electrolyte (the oxyl) and the other a lattice oxygen (the bridge). Altogether, we experimentally isolate an important activation barrier for water oxidation, which is necessary for designing water oxidation catalysts with high O2 turn over. Moreover, in isolating it, we identify competing mechanisms for O2 evolution at surfaces and show how to use reaction conditions to select between them

    Decomposition-aggregation stability analysis

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    This report presents the development and description of the decomposition aggregation approach to stability investigations of high dimension mathematical models of dynamic systems. The high dimension vector differential equation describing a large dynamic system is decomposed into a number of lower dimension vector differential equations which represent interconnected subsystems. Then a method is described by which the stability properties of each subsystem are aggregated into a single vector Liapunov function, representing the aggregate system model, consisting of subsystem Liapunov functions as components. A linear vector differential inequality is then formed in terms of the vector Liapunov function. The matrix of the model, which reflects the stability properties of the subsystems and the nature of their interconnections, is analyzed to conclude over-all system stability characteristics. The technique is applied in detail to investigate the stability characteristics of a dynamic model of a hypothetical spinning Skylab

    Push-pull switching power amplifier

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    A true push-pull switching power amplifier is disclosed utilizing two dc-to-dc converters. Each converter is comprised of two inductances, one inductance in series with a DC source and the other inductor in series with the output load, and an electrical energy transferring device with storage capability, namely storage capacitance, with suitable switching means between the inductances to obtain DC level conversion, where the switching means allows bidirectional current (and power) flow, and the switching means of one dc-to-dc converter is driven by the complement of a square-wave switching signal for the other dc-to-dc converter for true push-pull operation. For reduction of current ripple, the inductances in each of the two converters may be coupled, and with proper design of the coupling, the ripple can be reduced to zero at either the input or the output, but preferably the output

    PEMANFAATAN E-APPLICATION DALAM PENINGKATAN PROSES AUDIT MUTU INTERNAL (STUDI KASUS : UNIVERSITAS BINA

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    Paper ini menampilkan tulisan mengenai penggunaan e-application untuk membantu pelaksanaan audit mutu internal, yang merupakan salah satu syarat yang harus dipenuhi dalam persyaratan Sistem Penjaminan Mutu ISO 9000. E-application yang digunakan selain sebagai data repository juga digunakan sebagai workflow. Dimana workflow yang dibuat akan memastikan bahwa perbaikan dijalankan sesuai dengan yang telah direncanakan. Sebagai salah satu persyaratan dokumentasi ISO dalam Klausul 4.2.4(p.3 ) bahwa sebuah dokumen harus dapat dilakukan telusur jejak, maka penggunaan e-application ini sangat membantu dalam melakukan telusur jejak. Selain itu, e-application memudahkan auditor dan auditee dalam mengisi hasil audit, dikarenakan dapat diakses dari manapun serta dikarenakan berbasis web, maka dapat dilakukan dari computer mana saja tanpa harus dilakukan instalasi terlebih dahulu. e-application yang dikembangkan ini berfungsi sebagai workflow dan data repository sehingga dapat digunakan sebagai bagian dari monitoring dan data history yang ada akan sangat membantu untuk memperbaiki kinerja unit tersebut terlebih kinerja universitas Bina Nusantara
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