Repasivation of steel rebars after and electrochemical chlorides removal treatment by simultaneous application of calcium nitrite

The Electrochemical Removal of Chlorides (CE) can be proposed as methodology for the treatment of reinforced concrete structures affected by corrosion. This methodology is based on the temporary application of an external voltage between an external anode located on the concrete and the rebar connected as cathode. After the treatment, the extraction of chloride from the concrete level and the repassivation of the rebar are expected. The migration of ionic inhibitors to the rebar could be considered during the connection of an electric field to favour the regeneration of the passive film. In present work a novel methodology is proposed to enhance the efficiency of an Electrochemical Chloride Extraction treatment by simultaneous application of calcium nitrite. A fast repassivation of the rebar is reached after the CE treatment when the inhibitor is applied during the electric field connection. The penetration of the inhibitor near the rebar surface has been confirmed by. The new passive conditions of the steel rebar after the treatment were confirmed by electrochemical measurements. The penetration of the inhibitor near the rebar surface was assured by analysing of nitrite dissolved into the aqueous phase. The presence of nitrite promoted a faster regeneration of the passive film that is maintained in time

La Garza Real en España. I. Población reproductora (1950-2000)

En este trabajo se analiza la evolución de la población reproductora de Garza Real, Ardea cinerea, en España durante el período 1950-2000. El territorio español se ha dividido en siete grandes zonas: Norte, Levante, y las cuencas de los cinco grandes ríos (Guadalquivir, Guadiana, Tajo, Duero y Ebro). Los datos sobre colonias y número de parejas nidificantes fueron obtenidos a partir de prospecciones de los autores, de citas bibliográficas y de comunicaciones de organismos y personas conocedoras de las colonias. Es probable que ya antes de 1950 hubiera colonias ocupadas, pero se carece de datos publicados sobre ellas. En 1950 pudo haber 168 parejas reproductoras en 4 colonias, mientras que en 2000 hubo 4790 parejas en 75 colonias. Las subpoblaciones de garza real asentadas de las cuencas del Duero y Tajo parecen estar próximas al equilibrio numérico, mientras que las del Ebro, Guadalquivir y Levante han aumentado notablemente su tamaño en la década 1990-2000. La cuenca del Guadiana contenía relativamente pocas parejas en el período de estudio y en el Norte de España la población reproductora de la garza real es aún poco significativa

Effects of ion concentration and solvent composition on the properties of water-methanol solutions of NaCl. NPT molecular dynamics computer simulation results

Isothermal-isobaric molecular dynamics simulations are used to examine the microscopic structure and other properties of a model solution consisting of NaCl salt dissolved in water-methanol mixture. The SPC/E water model and the united atom model for methanol are combined with the force field for ions by Dang [J. Amer. Chem. Soc., 1995, 117, 6954] to describe the entire system. Our principal focus is to study the effects of two variables, namely, the solvent composition and ion concentrations on the solution's density, on the structural properties, self-diffusion coefficients of the species and the dielectric constant. Moreover, we performed a detailed analysis of the first coordination numbers of the species. Trends of the behaviour of the average number of hydrogen bonds between solvent molecules are evaluated.Comment: 18 pages, 13 figures, 1 tabl

Efficient plot-based floristic assessment of tropical forests

The tropical flora remains chronically understudied and the lack of floristic understanding hampers ecological research and its application for large-scale conservation planning. Given scarce resources and the scale of the challenge there is a need to maximize the efficiency of both sampling strategies and sampling units, yet there is little information on the relative efficiency of different approaches to floristic assessment in tropical forests. This paper is the first attempt to address this gap. We repeatedly sampled forests in two regions of Amazonia using the two most widely used plot-based protocols of floristic sampling, and compared their performance in terms of the quantity of floristic knowledge and ecological insight gained scaled to the field effort required. Specifically, the methods are assessed first in terms of the number of person-days required to complete each sample (‘effort’), secondly by the total gain in the quantity of floristic information that each unit of effort provides (‘crude inventory efficiency’), and thirdly in terms of the floristic information gained as a proportion of the target species pool (‘proportional inventory efficiency’). Finally, we compare the methods in terms of their efficiency in identifying different ecological patterns within the data (‘ecological efficiency’) while controlling for effort. There are large and consistent differences in the performance of the two methods. The disparity is maintained even after accounting for regional and site-level variation in forest species richness, tree density and the number of field assistants. We interpret our results in the context of selecting the appropriate method for particular research purposes

Not So Heavy Metals: Black Hole Feedback Enriches the Circumgalactic Medium

We examine the effects of supermassive black hole (SMBH) feedback on the circumgalactic medium (CGM) using a cosmological hydrodynamic simulation (Romulus25) and a set of four zoom-in "genetically modified" Milky-Way–mass galaxies sampling different evolutionary paths. By tracing the distribution of metals in the CGM, we show that O vi is a sensitive indicator of SMBH feedback. First, we calculate the column densities of O vi in simulated Milky-Way–mass galaxies and compare them with observations from the COS-Halos Survey. Our simulations show column densities of O vi in the CGM consistent with those of COS-Halos star-forming and quenched galaxies. These results contrast with those from previous simulation studies which typically underproduce CGM column densities of O vi. We determine that a galaxy's star formation history and assembly record have little effect on the amount of O vi in its CGM. Instead, column densities of O vi are closely tied to galaxy halo mass and BH growth history. The set of zoom-in, genetically modified Milky-Way–mass galaxies indicates that the SMBH drives highly metal-enriched material out into its host galaxy's halo, which in turn elevates the column densities of O vi in the CGM

Mediating Performance Through Virtual Agents

This paper presents the process of creation of virtual agents used in a virtual reality performance. The performance aimed to investigate how drama and performance could inform the creation of virtual agents and also how virtual reality could raise questions for drama and performance. The virtual agents were based on the performance of 2 actors. This paper describes the process of preparing the actors, capturing their performances and transferring them to the virtual agents. A second set of agents was created using non-professional 'naive performers' rather than actors