First Time-dependent Study of H2 and H3+ Ortho-Para Chemistry in the Diffuse Interstellar Medium: Observations Meet Theoretical Predictions

The chemistry in the diffuse interstellar medium initiates the gradual increase of molecular complexity during the life cycle of matter. A key molecule that enables build-up of new molecular bonds and new molecules via proton-donation is H3+. Its evolution is tightly related to molecular hydrogen and thought to be well understood. However, recent observations of ortho and para lines of H2 and H3+ in the diffuse ISM showed a puzzling discrepancy in nuclear spin excitation temperatures and populations between these two key species. H3+, unlike H2, seems to be out of thermal equilibrium, contrary to the predictions of modern astrochemical models. We conduct the first time-dependent modeling of the para-fractions of H2 and H3+ in the diffuse ISM and compare our results to a set of line-of-sight observations, including new measurements presented in this study. We isolate a set of key reactions for H3+ and find that the destruction of the lowest rotational states of H3+ by dissociative recombination largely control its ortho/para ratio. A plausible agreement with observations cannot be achieved unless a ratio larger than 1:5 for the destruction of (1,1)- and (1,0)-states of H3+ is assumed. Additionally, an increased CR ionization rate to 10(-15) 1/s further improves the fit whereas variations of other individual physical parameters, such as density and chemical age, have only a minor effect on the predicted ortho/para ratios. Thus our study calls for new laboratory measurements of the dissociative recombination rate and branching ratio of the key ion H3+ under interstellar conditions.Comment: 27 pages, 6 figures, 3 table

Simplified Automatic Fault Detection in Wind Turbine Induction Generators

This paper presents a simplified automated fault detection scheme for wind turbine induction generators with rotor electrical asymmetries. Fault indicators developed in previous works have made use of the presence of significant spectral peaks in the upper sidebands of the supply frequency harmonics; however, the specific location of these peaks may shift depending on the wind turbine speed. As wind turbines tend to operate under variable speed conditions, it may be difficult to predict where these fault‐related peaks will occur. To accommodate for variable speeds and resulting shifting frequency peak locations, previous works have introduced methods to identify or track the relevant frequencies, which necessitates an additional set of processing algorithms to locate these fault‐related peaks prior to any fault analysis. In this work, a simplified method is proposed to instead bypass the issue of variable speed (and shifting frequency peaks) by introducing a set of bandpass filters that encompass the ranges in which the peaks are expected to occur. These filters are designed to capture the fault‐related spectral information to train a classifier for automatic fault detection, regardless of the specific location of the peaks. Initial experimental results show that this approach is robust against variable speeds and further shows good generalizability in being able to detect faults at speeds and conditions that were not presented during training. After training and tuning the proposed fault detection system, the system was tested on “unseen” data and yielded a high classification accuracy of 97.4%, demonstrating the efficacy of the proposed approach

Problematising international placements as a site of intercultural learning

This paper theorises some of the learning outcomes of a three-year project concerning student learning in international social work placements in Malaysia. The problematic issue of promoting cultural and intercultural competence through such placements is examined, where overlapping hegemonies are discussed in terms of isomorphism of social work models, that of the nation state, together with those relating to professional values and knowledge, and the tyrannies of received ideas. A critical discussion of cultural competence as the rationale for international placements is discussed in terms of the development of the graduating social worker as a self-reflexive practitioner. The development of sustainable international partnerships able to support student placement and the issue of non-symmetrical reciprocation, typical of wide socio-economic differentials across global regions, is additionally discussed

Predicting lung cancer recurrence from circulating tumour DNA. Commentary on 'Phylogenetic ctDNA analysis depicts early-stage lung cancer evolution'

No abstract available

Doping and Irradiation Controlled Vortex Pinning Behavior in BaFe2(As1-xPx)2 Single Crystals

We report on the systematic evolution of vortex pinning behavior in isovalent doped single crystals of BaFe2(As1-xPx)2. Proceeding from optimal doped to ovedoped samples, we find a clear transfor- mation of the magnetization hysteresis from a fishtail behavior to a distinct peak effect followed by a reversible magnetization and Bean Livingston surface barriers. Strong point pinning dominates the vortex behavior at low fields whereas weak collective pinning determines the behavior at higher fields. In addition to doping effects, we show that particle irradiation by energetic protons can tune vortex pinning in these materials.Comment: 4 pages, 4 figures,significant change of eraly version, accepted by PRB rapid communication