Current rectification in a single molecule diode: the role of electrode coupling

We demonstrate large rectification ratios (> 100) in single-molecule junctions based on a metal-oxide cluster (polyoxometalate), using a scanning tunneling microscope (STM) both at ambient conditions and at low temperature. These rectification ratios are the largest ever observed in a single-molecule junction, and in addition these junctions sustain current densities larger than 10^5 A/cm^2. By following the variation of the I-V characteristics with tip-molecule separation we demonstrate unambiguously that rectification is due to asymmetric coupling to the electrodes of a molecule with an asymmetric level structure. This mechanism can be implemented in other type of molecular junctions using both organic and inorganic molecules and provides a simple strategy for the rational design of molecular diodes

Layered gadolinium hydroxides for low-temperature magnetic cooling

Layered gadolinium hydroxides have revealed to be excellent candidates for cryogenic magnetic refrigeration. These materials behave as pure 2D magnetic systems with a Heisenberg-Ising critical crossover, induced by dipolar interactions. This 2D character and the possibility offered by these materials to be delaminated open the possibility of rapid heat dissipation upon substrate deposition

Possible Magnetic Chirality in Optically Chiral Magnet [Cr(CN)6_6][Mn(SS)-pnH(H2_2O)](H2_2O) Probed by Muon Spin Rotation and Relaxation

Local magnetic fields in a molecule-based optically chiral magnet [Cr(CN)$_6$][Mn($S$)-pnH(H$_2$O)](H$_2$O) (GN-S) and its enantiomer (GN-R) are studied by means of muon spin rotation and relaxation (muSR). Detailed analysis of muon precession signals under zero field observed below T_c supports the average magnetic structure suggested by neutron powder diffraction. Moreover, comparison of muSR spectra between GN-S and GN-R suggests that they are a pair of complete optical isomers in terms of both crystallographic and magnetic structure. Possibility of magnetic chirality in such a pair is discussed.Comment: 5 pages, 5 figures, submitted to J. Phys. Soc. Jp

A practical methodology of design of off-line reservoirs for reducing maximum water levels in urban channels

Indexación: Scopus.Flooding can often occur in many places due to the increasing trend of rainfall events (climate change), the urbanization process of a catchment area, or by an undersized urban channel. Reservoirs are used for limiting flooding since they can store an enough water volume. This research presents a practical procedure for sizing off-line reservoirs with an application in urban channels for places with space limitations. A complete formulation is presented, which can be easily used for designers and engineers for computing dimensions of off-line reservoirs. The formulation is applied to a case study located at the Cartagena de Indias, Colombia.https://www.sciencedirect.com/science/article/pii/S1877050920317439?via%3Dihu

Scanning tunneling spectroscopy of layers of superconducting 2H-TaSe2_\textbf{2}: Evidence for a zero bias anomaly in single layers

We report a characterization of surfaces of the dichalcogenide TaSe$_2$ using scanning tunneling microscopy and spectroscopy (STM/S) at 150 mK. When the top layer has the 2H structure and the layer immediately below the 1T structure, we find a singular spatial dependence of the tunneling conductance below 1 K, changing from a zero bias peak on top of Se atoms to a gap in between Se atoms. The zero bias peak is additionally modulated by the commensurate $3a_0 \times 3a_0$ charge density wave of 2H-TaSe$_2$. Multilayers of 2H-TaSe$_2$ show a spatially homogeneous superconducting gap with a critical temperature also of 1 K. We discuss possible origins for the peculiar tunneling conductance in single layers.Comment: 10 pages, 10 figure

Design of an Information System for optimizing the Programming of nursing work shifts

Health institutions operate twenty-four hours a day, seven days a week. They face a demand that fluctuates daily. Unlike jobs with fixed hours and obligatory days off, in health, operational continuity is required. The allocation for nursing shifts generates a rotation of people for health services according to legal and casuistic guidelines. Assigning and planning shifts results in a workload that takes an average of five to six extra hours. Existing applications offer a partial solution because they do not consider the news and contingencies of a health service. A web application is presented that, given a list of nurses, historical shifts and restrictions, a work shift planning is generated. This application comes to support the current shift allocation method based on electronic spreadsheets. The development consists of two modules. The first module has a shift allocation algorithm developed in C ++ and the second module has a graphical interface. As a case study, a set of health services from Chile and Colombia was used. The services have a defined number of nurses, who work different shifts according to the role and need of the institution. The results obtained are similar to a historical one. The proposed system takes less time and delivers various files and parameters that can be useful for nurses, the service and the health institutio

Photovoltaic module segmentation and thermal analysis tool from thermal images

The growing interest in the use of clean energy has led to the construction of increasingly large photovoltaic systems. Consequently, monitoring the proper functioning of these systems has become a highly relevant issue.In this paper, automatic detection, and analysis of photovoltaic modules are proposed. To perform the analysis, a module identification step, based on a digital image processing algorithm, is first carried out. This algorithm consists of image enhancement (contrast enhancement, noise reduction, etc.), followed by segmentation of the photovoltaic module. Subsequently, a statistical analysis based on the temperature values of the segmented module is performed.Besides, a graphical user interface has been designed as a potential tool that provides relevant information of the photovoltaic modules.Comment: 7 pages, 12 Figure

MAPPER, a low-level geographic information system

A Low-Level Geographic Information System (LL-GIS) was developed to provide a simple low-cost mapping program which can be executed in any personal computer, by individuals with different levels of knowledge in computing. MAPPER is an add-on module of FishBase - a global database with key information on the biology of fish - where it creates on-screen maps with information on biodiversity and the occurrence of species. In another application, MAPPER is used to display and analyzed geographical information on the Philippines