369 research outputs found
Gas-grain models for interstellar anion chemistry
Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be
abundant in a variety of interstellar clouds. In order to explain their large
abundances in the denser (prestellar/protostellar) environments, new chemical
models are constructed that include gas-grain interactions. Models including
accretion of gas-phase species onto dust grains and cosmic-ray-induced
desorption of atoms are able to reproduce the observed anion-to-neutral ratios,
as well as the absolute abundances of anionic and neutral carbon chains, with a
reasonable degree of accuracy. Due to their destructive effects, the depletion
of oxygen atoms onto dust results in substantially greater polyyne and anion
abundances in high-density gas (with n_{H_2} >~ 10^5 cm^{-3}). The large
abundances of carbon-chain-bearing species observed in the envelopes of
protostars such as L1527 can thus be explained without the need for warm
carbon-chain chemistry. The C6H- anion-to-neutral ratio is found to be most
sensitive to the atomic O and H abundances and the electron density. Therefore,
as a core evolves, falling atomic abundances and rising electron densities are
found to result in increasing anion-to-neutral ratios. Inclusion of cosmic-ray
desorption of atoms in high-density models delays freeze-out, which results in
a more temporally-stable anion-to-neutral ratio, in better agreement with
observations. Our models include reactions between oxygen atoms and
carbon-chain anions to produce carbon-chain-oxide species C6O, C7O, HC6O and
HC7O, the abundances of which depend on the assumed branching ratios for
associative electron detachment
Isotopic Anomalies in Primitive Solar System Matter: Spin-state Dependent Fractionation of Nitrogen and Deuterium in Interstellar Clouds
Organic material found in meteorites and interplanetary dust particles is
enriched in D and 15N. This is consistent with the idea that the functional
groups carrying these isotopic anomalies, nitriles and amines, were formed by
ion-molecule chemistry in the protosolar nebula. Theoretical models of
interstellar fractionation at low temperatures predict large enrichments in
both D and 15N and can account for the largest isotopic enrichments measured in
carbonaceous meteorites. However, more recent measurements have shown that, in
some primitive samples, a large 15N enrichment does not correlate with one in
D, and that some D-enriched primitive material displays little, if any, 15N
enrichment. By considering the spin-state dependence in ion-molecule reactions
involving the ortho and para forms of H2, we show that ammonia and related
molecules can exhibit such a wide range of fractionation for both 15N and D in
dense cloud cores. We also show that while the nitriles, HCN and HNC, contain
the greatest 15N enrichment, this is not expected to correlate with extreme D
enrichment. These calculations therefore support the view that Solar System 15N
and D isotopic anomalies have an interstellar heritage. We also compare our
results to existing astronomical observations and briefly discuss future tests
of this model.Comment: Submitted to ApJ
Models for Cometary Comae Containing Negative Ions
The presence of negative ions (anions) in cometary comae is known from Giotto mass spectrometry of IP/Halley. The anions O(-), OH(-), C(-), CH(-) and CN(-) have been detected, as well as unidentified anions with masses 22-65 and 85-110 amu [I]. Organic molecular anions such as C4H(-) and C6H(-) are known to have a significant impact on the charge balance of interstellar clouds and circumstellar envelopes and have been shown to act as catalysts for the gas phase synthesis of larger hydrocarbon molecules in the ISM, but their importance in cometary comae has not yet been fully explored. We present details of our new models for the chemistry of cometary comae that include atomic and molecular anions. We calculate the impact of these anions on the charge balance and examine their importance for cometary coma chemistry
Searching for Bio-Precursors and Complex Organic Molecules in Space using the GBT
Using the latest microwave receiver technology, large organic molecules with abundances as low as approx. 10(exp -11) times that of molecular hydrogen are detectable in cold interstellar clouds via their rotational emission line spectra. We report new observations to search for complex molecules, including molecules of possible pre-biotic importance, using the newly-commissioned Kband focal plane array (KFPA) of the NRAO Robert C. Byrd Green Bank Telescope. Spectra are presented of the dense molecular cloud TMC-1, showing strict upper limits on the level of emission from nitrogen-bearing rings pyrimidine, quinoline and iso-quinoline, carbon-chain oxides C60, C70, HC60 and HC70, and the carbon-chain anion C4H-. The typical RMS brightness temperature noise levels we achieved are approx. 1 mK at around 20 GHz
fcpowered rbs data analysis and system optimization
Abstract The previous works on the use of PEM Fuel Cell based power supply system for the operation of off-grid RBS (Radio Base Stations) sites showed a strong influence of system design parameters on the energy conversion performance. In this paper a perturbation of system design is performed through validated models to understand better the variability of performance over a full year operation. Results show that a ratio of energy produced by fossil over energy produced by renewables sources of 0.2 can be reached slightly increasing the photovoltaic plant size without affecting drastically the renewable exploitation. Moreover a positive Net Present Value can be achieved in comparison with the traditional diesel genset solution (from 260k€ to 350k€). The NPV value increases with the PV size and with a reduction of the battery size that leads to a steep reduction in the RES exploitation. Therefore, an optimum has to be sought as a compromise between the two aspects
Negative Ion Chemistry in the Coma of Comet 1P/Halley
Negative ions (anions) were identified in the coma of comet 1P/Halley from in-situ measurements performed by the Giotto spacecraft in 1986. These anions were detected with masses in the range 7-110 amu, but with insufficient mass resolution to permit unambiguous identification. We present details of a new chemical-hydrodynamic model for the coma of comet Halley that includes - for the first time - atomic and molecular anions, in addition to a comprehensive hydrocarbon chemistry. Anion number densities arc calculated as a function of radius in the coma, and compared with the Giotto results. Important anion production mechanisms arc found to include radiative electron attachment, polar photodissociation, dissociative electron attachment, and proton transfer. The polyyne anions C4H(-) and C6H(-) arc found to be likely candidates to explain the Giotto anion mass spectrum in the range 49-73 amu. Thc CN(-) anion probably makes a significant contribution to the mass spectrum at 26 amu. Larger carbon-chain anions such as C8H(1) can explain the peak near 100 amu provided there is a source of large carbon-chain-bearing molecules from the cometary nucleus
On the ubiquity of molecular anions in the dense interstellar medium
Results are presented from a survey for molecular anions in seven nearby
Galactic star-forming cores and molecular clouds. The hydrocarbon anion C6H- is
detected in all seven target sources, including four sources where no anions
have been previously detected: L1172, L1389, L1495B and TMC-1C. The C6H-/C6H
column density ratio is greater than about 1.0% in every source, with a mean
value of 3.0% (and standard deviation 0.92%). Combined with previous
detections, our results show that anions are ubiquitous in dense clouds
wherever C6H is present. The C6H-/C6H ratio is found to show a positive
correlation with molecular hydrogen number density, and with the apparent age
of the cloud. We also report the first detection of C4H- in TMC-1 (at 4.8-sigma
confidence), and derive an anion-to-neutral ratio C4H-/C4H = (1.2 +- 0.4) x
10^-5 (= 0.0012 +- 0.0004%). Such a low value compared with C6H- highlights the
need for a revised radiative electron attachment rate for C4H. Chemical model
calculations show that the observed C4H- could be produced as a result of
reactions of oxygen atoms with C5H- and C6H-
An Analysis of 3D Simulation of SI Combustion with an Improved Version of the Kiva 3V Code: Numerical Formulation and Experimental Validation
The correct simulation of combustion process allows to better face several SI engines design problems, not only for innovative mixture formation concepts (stratified or
ultra-lean charge), but for traditional homogeneous mixture as well. Even though many commercial codes are able to describe the complex 3-D non reacting fluid dynamics in ICE, the simulation of high turbulent flame
propagation does not seem to be a completely solved problem yet.
In this work a comparison between two different turbulent combustion models (a characteristic time based one by Abraham and Reitz [2, 15, 16] and a flamelet based one by Cant and AbuOrf [4, 20]) has been performed using KIVA-3V code to assess simulation reliability. Models predictive capabilities have been tested with reference to specific data acquired at the engine test bench of Tor Vergata Mechanical Engineering Department on a Fiat Punto 1242 cc 8 valves SI engine over a wide range of operating conditions.
A generally good agreement has been observed
between experimental and numerical results obtained by using both the combustion models. In addition it can be noticed that, thanks to a more physical description of the local turbulent flame characteristics, Cant model seems to exhibit more predicting reliability in the whole engine operating field
Appendix to "Torque setpoint tracking for parallel hybrid electric vehicles using dynamic input allocation", published on IEEE Transactions on Control Systems Technology
A dynamic allocator is proposed in order to generalize a previously introduced strategy for input redundant plants, which applies to linear plants with multiple and redundant inputs. The theory is extended here to the case of multiple linear actuators, each of them with its own dynamics, acting on a nonlinear plant with strong input redundancy. In the HEV case the two redundant inputs are the ICE and EM torques and the two actuators with different dynamics are the two propulsion systems
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