How speed of sound measurements could bring constraints on the composition of Titan's seas

The hydrocarbons seas of Titan, discovered by Cassini/Huygens mission are among the most mysterious and interesting features of this moon. In the future, a possible dedicated planetary probe, will certainly measure the speed of sound in this cryogenic liquid, as it was planned in the case of a Huygens landing into a sea. Previous theoretical studies of such acoustic measurements were based on rather simple models, leading in some cases to unphysical situations. Employed in a vast body of chemical engineering works, the state of the art PC-SAFT model has been recently introduced in studies aimed at Titan. Here, I revisit the issue of the speed of sound in Titan's liquids, in the light of this theory. I describe, in detail, the derivation of the speed of sound from the chosen equation of state and the potential limitations of the approach. To make estimations of the composition of a ternary liquid mixture N2:CH4:C2H6 from speed of sound measurements an original inversion algorithm is proposed. It is shown that 50 measures between 90 K and 100 K are enough to ensure an accuracy of the derived compositions better than 10%. The influence of the possible presence of propane is also investigated.Comment: 7 pages, 5 figures, accepted in MNRA

Dust photophoretic transport around a T Tauri star: Implications for comets composition

There is a growing body of evidences for the presence of crystalline material in comets. These crystals are believed to have been annealed in the inner part of the proto-solar nebula, while comets should have been formed in the outer regions. Several transport processes have been proposed to reconcile these two facts; among them a migration driven by photophoresis. The primarily goal of this work is to assess whether disk irradiation by a Pre-Main Sequence star would influence the photophoretic transport. To do so, we have implemented an evolving 1+1D model of an accretion disk, including advanced numerical techniques, undergoing a time-dependent irradiation, consistent with the evolution of the proto-Sun along the Pre-Main Sequence. The photophoresis is described using a formalism introduced in several previous works. Adopting the opacity prescription used in these former studies, we find that the disk irradiation enhances the photophoretic transport: the assumption of a disk central hole of several astronomical units in radius is no longer strictly required, whereas the need for an ad hoc introduction of photoevaporation is reduced. However, we show that a residual trail of small particles could annihilate the photophoretic driven transport via their effect on the opacity. We have also confirmed that the thermal conductivity of transported aggregates is a crucial parameter which could limit or even suppress the photophoretic migration and generate several segregation effects

Volatile inventories in clathrate hydrates formed in the primordial nebula

Examination of ambient thermodynamic conditions suggest that clathrate hydrates could exist in the martian permafrost, on the surface and in the interior of Titan, as well as in other icy satellites. Clathrate hydrates probably formed in a significant fraction of planetesimals in the solar system. Thus, these crystalline solids may have been accreted in comets, in the forming giant planets and in their surrounding satellite systems. In this work, we use a statistical thermodynamic model to investigate the composition of clathrate hydrates that may have formed in the primordial nebula. In our approach, we consider the formation sequence of the different ices occurring during the cooling of the nebula, a reasonable idealization of the process by which volatiles are trapped in planetesimals. We then determine the fractional occupancies of guests in each clathrate hydrate formed at given temperature. The major ingredient of our model is the description of the guest-clathrate hydrate interaction by a spherically averaged Kihara potential with a nominal set of parameters, most of which being fitted on experimental equilibrium data. Our model allows us to find that Kr, Ar and N$_2$ can be efficiently encaged in clathrate hydrates formed at temperatures higher than $\sim$ 48.5 K in the primitive nebula, instead of forming pure condensates below 30 K. However, we find at the same time that the determination of the relative abundances of guest species incorporated in these clathrate hydrates strongly depends on the choice of the parameters of the Kihara potential and also on the adopted size of cages. Indeed, testing different potential parameters, we have noted that even minor dispersions between the different existing sets can lead to non-negligible variations in the determination of the volatiles trapped in clathrate hydrates formed in the primordial nebula.Comment: Accepted for publication in Faraday Discussion

The spectral catalogue of INTEGRAL gamma-ray bursts: results of the joint IBIS/SPI spectral analysis

We present the updated INTEGRAL catalogue of gamma-ray bursts (GRBs) observed between December 2002 and February 2012. The catalogue contains the spectral parameters for 59 GRBs localized by the INTEGRAL Burst Alert System (IBAS). We used the data from the two main instruments on board the INTEGRAL satellite: the spectrometer SPI (SPectrometer on INTEGRAL) nominally covering the energy range 18 keV - 8 MeV, and the imager IBIS (the Imager on Board the INTEGRAL Satellite) operating in the range from 15 keV to 10 MeV. For the spectral analysis we applied a new data extraction technique, developed in order to explore the energy regions of highest sensitivity for both instruments, SPI and IBIS. It allowed us to perform analysis of the GRB spectra over a broad energy range and to determine the bursts' spectral peak energies. The spectral analysis was performed on the whole sample of GRBs triggered by IBAS, including all the events observed in period December 2002 - February 2012. The catalogue contains the trigger times, burst coordinates, positional errors, durations and peak fluxes for 28 unpublished GRBs observed between September 2008 and February 2012. The light curves in 20 - 200 keV energy band of these events were derived using IBIS data. We compare the prompt emission properties of the INTEGRAL GRB sample with the BATSE and Fermi samples.Comment: 16 pages, 40 figures, accepted for publication in Astronomy & Astrophysic

An estimate of the chemical composition of Titan's lakes

Hundreds of radar-dark patches interpreted as lakes have been discovered in the north and south polar regions of Titan. We have estimated the composition of these lakes by using the direct abundance measurements from the Gas Chromatograph Mass Spectrometer (GCMS) aboard the Huygens probe and recent photochemical models based on the vertical temperature profile derived by the Huygens Atmospheric Structure Instrument (HASI). Thermodynamic equilibrium is assumed between the atmosphere and the lakes, which are also considered as nonideal solutions. We find that the main constituents of the lakes are ethane (C2H6) (~76-79%), propane (C3H8) (~7-8%), methane (CH4) (~5-10%), hydrogen cyanide (HCN) (~2-3%), butene (C4H8) (~1%), butane (C4H10) (~1%) and acetylene (C2H2) (~1%). The calculated composition of lakes is then substantially different from what has been expected from models elaborated prior to the exploration of Titan by the Cassini-Huygens spacecraft.Comment: 5 pages, 2 figures, accepted in ApJ

Monte-Carlo simulations of the background of the coded-mask camera for X- and Gamma-rays on-board the Chinese-French GRB mission SVOM

For several decades now, wide-field coded mask cameras have been used with success to localise Gamma-ray bursts (GRBs). In these instruments, the event count rate is dominated by the photon background due to their large field of view and large effective area. It is therefore essential to estimate the instrument background expected in orbit during the early phases of the instrument design in order to optimise the scientific performances of the mission. We present here a detailed study of the instrument background and sensitivity of the coded-mask camera for X- and Gamma-rays (CXG) to be used in the detection and localisation of high-redshift GRBs on-board the international GRB mission SVOM. To compute the background spectrum, a Monte-Carlo approach was used to simulate the primary and secondary interactions between particles from the main components of the space environment that SVOM will encounter along its Low Earth Orbit (LEO) (with an altitude of 600 km and an inclination of ~ 30 deg) and the body of the CXG. We consider the detailed mass model of the CXG in its latest design. According to our results, i) the design of the passive shield of the camera ensures that in the 4-50 keV imaging band the cosmic X-Gamma-ray background is dominant whilst the internal background should start to become dominant above 70-90 keV; ii) the current camera design ensures that the CXG camera will be more sensitive to high-redshift GRBs than the Swift Burst Alert Telescope thanks to a low-energy threshold of 4 keV.Comment: 16 pages, 10 figures (1 colour), accepted for publication in Nuclear Instruments and Methods in Physics Research: Section

Quantum transport of two-dimensional Dirac fermions in SrMnBi2

We report two-dimensional quantum transport in SrMnBi$_2$ single crystals. The linear energy dispersion leads to the unusual nonsaturated linear magnetoresistance since all Dirac fermions occupy the lowest Landau level in the quantum limit. The transverse magnetoresistance exhibits a crossover at a critical field $B^*$ from semiclassical weak-field $B^2$ dependence to the high-field linear-field dependence. With increase in the temperature, the critical field $B^*$ increases and the temperature dependence of $B^*$ satisfies quadratic behavior which is attributed to the Landau level splitting of the linear energy dispersion. The effective magnetoresistant mobility $\mu_{MR}\sim 3400$ cm$^2$/Vs is derived. Angular dependent magnetoresistance and quantum oscillations suggest dominant two-dimensional (2D) Fermi surfaces. Our results illustrate the dominant 2D Dirac fermion states in SrMnBi$_2$ and imply that bulk crystals with Bi square nets can be used to study low dimensional electronic transport commonly found in 2D materials like graphene.Comment: 5 papges, 4 figure

The INTEGRAL/SPI response and the Crab observations

The Crab region was observed several times by INTEGRAL for calibration purposes. This paper aims at underlining the systematic interactions between (i) observations of this reference source, (ii) in-flight calibration of the instrumental response and (iii) the development and validation of the analysis tools of the SPI spectrometer. It first describes the way the response is produced and how studies of the Crab spectrum lead to improvements and corrections in the initial response. Then, we present the tools which were developed to extract spectra from the SPI observation data and finally a Crab spectrum obtained with one of these methods, to show the agreement with previous experiments. We conclude with the work still ahead to understand residual uncertainties in the response.Comment: 4 pages, 4 figures, Proc. of the 5th INTEGRAL Workshop (Feb. 16-20 2004), to be published by ES