724 research outputs found
Tunable dipolar magnetism in high-spin molecular clusters
We report on the Fe17 high-spin molecular cluster and show that this system
is an exemplification of nanostructured dipolar magnetism. Each Fe17 molecule,
with spin S=35/2 and axial anisotropy as small as D=-0.02K, is the magnetic
unit that can be chemically arranged in different packing crystals whilst
preserving both spin ground-state and anisotropy. For every configuration,
molecular spins are correlated only by dipolar interactions. The ensuing
interplay between dipolar energy and anisotropy gives rise to macroscopic
behaviors ranging from superparamagnetism to long-range magnetic order at
temperatures below 1K.Comment: Replaced with version accepted for publication in Physical Review
Letter
The changing pattern of domestic cannabis cultivation in the UK and its impact on the cannabis market
With improvements in both technology and information cannabis is being increasingly grown indoors for domestic use, rather than being imported. This study examines 50 cannabis farms detected by an English police force, and examines the characteristics of the 61 suspects associated with them. The study highlights a UK pattern in domestic cultivation, that is moving away from large scale commercial cultivation, at times co-ordinated by South East Asian organised crime groups, to increased cultivation within residential premises by British citizens. Offenders range from those who have no prior criminal history to those who are serious and persistent offenders. The ramifications for law enforcement agencies and policy formers are discussed
Examining the Seyfert - Starburst Connection with Arcsecond Resolution Radio Continuum Observations
We compare the arcsecond-scale circumnuclear radio continuum properties
between five Seyfert and five starburst galaxies, concentrating on the search
for any structures that could imply a spatial or causal connection between the
nuclear activity and a circumnuclear starburst ring. No evidence is found in
the radio emission for a link between the triggering or feeding of nuclear
activity and the properties of circumnuclear star formation. Conversely, there
is no clear evidence of nuclear outflows or jets triggering activity in the
circumnuclear rings of star formation. Interestingly, the difference in the
angle between the apparent orientation of the most elongated radio emission and
the orientation of the major axis of the galaxy is on average larger in
Seyferts than in starburst galaxies, and Seyferts appear to have a larger
physical size scale of the circumnuclear radio continuum emission. The
concentration, asymmetry, and clumpiness parameters of radio continuum emission
in Seyferts and starbursts are comparable, as are the radial profiles of radio
continuum and near-infrared line emission. The circumnuclear star formation and
supernova rates do not depend on the level of nuclear activity. The radio
emission usually traces the near-infrared Br-gamma and H2 1-0 S(1) line
emission on large spatial scales, but locally their distributions are
different, most likely because of the effects of varying local magnetic fields
and dust absorption and scattering.Comment: 21 pages, 10 figures. Accepted for publication in the Astronomical
Journa
The Nature of Composite LINER/HII Galaxies, As Revealed from High-Resolution VLA Observations
A sample of 37 nearby galaxies displaying composite LINER/HII and pure HII
spectra was observed with the VLA in an investigation of the nature of their
weak radio emission. The resulting radio contour maps overlaid on optical
galaxy images are presented here, together with an extensive literature list
and discussion of the individual galaxies. Radio morphological data permit
assessment of the ``classical AGN'' contribution to the global activity
observed in these ``transition'' LINER galaxies. One in five of the latter
objects display clear AGN characteristics: these occur exclusively in
bulge-dominated hosts.Comment: 31 pages, 27 figures, accepted by ApJ
Observations of the 6 Centimeter Lines of OH in Evolved (OH/IR) Stars
Recent observational and theoretical advances have called into question
traditional OH maser pumping models in evolved (OH/IR) stars. The detection of
excited-state OH lines would provide additional constraints to discriminate
amongst these theoretical models. In this Letter, we report on VLA observations
of the 4750 MHz and 4765 MHz lines of OH toward 45 sources, mostly evolved
stars. We detect 4765 MHz emission in the star forming regions Mon R2 and LDN
1084, but we do not detect excited-state emission in any evolved stars. The
flux density and velocity of the 4765 MHz detection in Mon R2 suggests that a
new flaring event has begun.Comment: 4 pages, to appear in ApJ
Legal determinants of external finance revisited : the inverse relationship between investor protection and societal well-being
This paper investigates relationships between corporate governance traditions and quality of life as measured by a number of widely reported indicators. It provides an empirical analysis of indicators of societal health in developed economies using a classification based on legal traditions. Arguably the most widely cited work in the corporate governance literature has been the collection of papers by La Porta et al. which has shown, inter alia, statistically significant relationships between legal traditions and various proxies for investor protection. We show statistically significant relationships between legal traditions and various proxies for societal health. Our comparative evidence suggests that the interests of investors may not be congruent with the interests of wider society, and that the criteria for judging the effectiveness of approaches to corporate governance should not be restricted to financial metrics
The remarkable asymmetric outflow from the Cygnus Egg Nebula
We present ground based continuum images in the infrared, from 1.2 to 19”m, and an H2 2.122”m line emission image of the post-AGB star AFGL2688, the Cygnus Egg Nebula. We show that the standard model of this source, comprising a fast wind focussed by a dense, equatorial, dusty torus into a bipolar flow at position angle 15 and close to the plane of the sky, cannot explain the combination of kinematic information from previous studies and morphological information in our own observations. Nor are the images consistent with a classical bipolar flow, since the apex of the two lobes observed in scattered light in the visible and near-IR are offset in R.A. with respect to one another. We suggest a model which is physically similar, but substantially different geometrically, in which there is a bipolar flow at a position angle closer to 60, rather than 15, still collimated by a dense, equatorial, dusty torus, but the opening angle of the cones out of which the fast bipolar flow is directed is closer to 90, rather than 20 or so as previously suggested. The bipolar flow axis is inclined by about 20-30, rather than in the plane of the sky as in previous models. The dust distribution in the nebula has to be extremely clumpy, and there is evidence that large scale mass loss from the progenitor AGB star occurred in discrete phases, recurring on a timescale of 750 years. This model implies a much lower velocity for the 'fast' bipolar outflow than does the standard model, which is consistent with very recent Nobeyama Millimetre Array images in 13CO emission. In support of our new model, we present a full radiative transfer model for the source, in axial symmetry, which reveals that the final phase of heavy mass loss included a superwind phase which lasted about two hundred years and removed about 0.7 M from the envelope of the progenitor AGB star. Our results imply that the progenitor star must have been a relatively high mass AGB star. Our radiative transfer model also demonstrates convincingly that, in contrast with previous models, the core of the nebula has to be exceptionally optically thick, with an optical depth greater than unity even at 10”m
Modelling Conformational Flexibility in a Spectrally Addressable Molecular Multi-Qubit Model System
Dipolar coupled multi-spin systems have the potential to be used as molecular qubits. Herein we report the synthesis of a molecular multi-qubit model system with three individually addressable, weakly interacting, spin (Formula presented.) centres of differing g-values. We use pulsed Electron Paramagnetic Resonance (EPR) techniques to characterise and separately address the individual electron spin qubits; CuII, Cr7Ni ring and a nitroxide, to determine the strength of the inter-qubit dipolar interaction. Orientation selective Relaxation-Induced Dipolar Modulation Enhancement (os-RIDME) detecting across the CuII spectrum revealed a strongly correlated CuII-Cr7Ni ring relationship; detecting on the nitroxide resonance measured both the nitroxide and CuII or nitroxide and Cr7Ni ring correlations, with switchability of the interaction based on differing relaxation dynamics, indicating a handle for implementing EPR-based quantum information processing (QIP) algorithms
The effects of remote ischaemic preconditioning on coronary artery function in patients with stable coronary artery disease
Background: Remote ischaemic preconditioning (RIPC) is a cardioprotective intervention invoking intermittent
periods of ischaemia in a tissue or organ remote from the heart. The mechanisms of this effect are incompletely
understood. We hypothesised that RIPC might enhance coronary vasodilatation by an endothelium-dependent
mechanism.
Methods: We performed a prospective, randomised, sham-controlled, blinded clinical trial. Patients with stable
coronary artery disease (CAD) undergoing elective invasive management were prospectively enrolled,
and randomised to RIPC or sham (1:1) prior to angiography. Endothelial-dependent vasodilator function
was assessed in a non-target coronary artery with intracoronary infusion of incremental acetylcholine doses
(10â6
, 10â5
, 10â4 mol/l). Venous blood was sampled pre- and post-RIPC or sham, and analysed for circulating
markers of endothelial function. Coronary luminal diameter was assessed by quantitative coronary angiography.
The primary outcome was the between-group difference in the mean percentage change in coronary luminal diameter
following the maximal acetylcholine dose (Clinicaltrials.gov identifier: NCT02666235).
Results: 75 patients were enrolled. Following angiography, 60 patients (mean ± SD age 57.5 ± 8.5 years; 80%
male) were eligible and completed the protocol (n = 30 RIPC, n = 30 sham). The mean percentage change in
coronary luminal diameter was â13.3 ± 22.3% and â2.0 ± 17.2% in the sham and RIPC groups respectively
(difference 11.32%, 95%CI: 1.2â 21.4, p = 0.032). This remained significant when age and sex were included as
covariates (difference 11.01%, 95%CI: 1.01â 21.0, p = 0.035). There were no between-group differences in
endothelial-independent vasodilation, ECG parameters or circulating markers of endothelial function.
Conclusions: RIPC attenuates the extent of vasoconstriction induced by intracoronary acetylcholine infusion. This
endothelium-dependent mechanism may contribute to the cardioprotective effects of RIP
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