Desorption of CO and O2 interstellar ice analogs

Solid O2 has been proposed as a possible reservoir for oxygen in dense clouds through freeze-out processes. The aim of this work is to characterize quantitatively the physical processes that are involved in the desorption kinetics of CO-O2 ices by interpreting laboratory temperature programmed desorption (TPD) data. This information is used to simulate the behavior of CO-O2 ices under astrophysical conditions. The TPD spectra have been recorded under ultra high vacuum conditions for pure, layered and mixed morphologies for different thicknesses, temperatures and mixing ratios. An empirical kinetic model is used to interpret the results and to provide input parameters for astrophysical models. Binding energies are determined for different ice morphologies. Independent of the ice morphology, the desorption of O2 is found to follow 0th-order kinetics. Binding energies and temperature-dependent sticking probabilities for CO-CO, O2-O2 and CO-O2 are determined. O2 is slightly less volatile than CO, with binding energies of 912+-15 versus 858+-15 K for pure ices. In mixed and layered ices, CO does not co-desorb with O2 but its binding energies are slightly increased compared with pure ice whereas those for O2 are slightly decreased. Lower limits to the sticking probabilities of CO and O2 are 0.9 and 0.85, respectively, at temperatures below 20K. The balance between accretion and desorption is studied for O2 and CO in astrophysically relevant scenarios. Only minor differences are found between the two species, i.e., both desorb between 16 and 18K in typical environments around young stars. Thus, clouds with significant abundances of gaseous CO are unlikely to have large amounts of solid O2.Comment: 8 pages + 2 pages online material, 8 figures (1 online), accepted by A&

Dielectric-barrier discharges in two-dimensional lattice potentials

We use a pin-grid electrode to introduce a corrugated electrical potential into a planar dielectric-barrier discharge (DBD) system, so that the amplitude of the applied electric field has the profile of a two-dimensional square lattice. The lattice potential provides a template for the spatial distribution of plasma filaments in the system and has pronounced effects on the patterns that can form. The positions at which filaments become localized within the lattice unit cell vary with the width of the discharge gap. The patterns that appear when filaments either overfill or under-fill the lattice are reminiscent of those observed in other physical systems involving 2d lattices. We suggest that the connection between lattice-driven DBDs and other areas of physics may benefit from the further development of models that treat plasma filaments as interacting particles.Comment: 4 pages, 4 figure

Self-Organized Assemblies Of Colloidal Particles Obtained From An Aligned Chromonic Liquid Crystal Dispersion

The behavior of mono-disperse colloidal particles in a chromonic liquid crystal was investigated. Poly(methyl methacrylate) spherical particles with three different functionalizations, with and without surface charges, were utilized in the nematic and columnar phases of disodium cromoglycate solutions. The nematic phase was completely aligned parallel to the glass substrates by a simple rubbing technique, and the columnar phase showed regions of similar alignment. The behavior of the colloidal particles in the chromonic liquid crystal depended critically on the functionality, with bromine functionalized particles not dispersing at all, and cationic trimethylammonium and epoxy functionalized particles dispersing well in the isotropic phase of the liquid crystal. At the transition to the nematic and especially the columnar phase, the colloidal particles were expelled into the remaining isotropic phase. Since the columnar phase grew in parallel ribbons, the colloidal particles ended up in chain-like assemblies. Such behavior opens the possibility of producing patterned assemblies of colloidal particles by taking advantage of the self-organized structure of chromonic liquid crystals

Observation Of Light Diffusion And Correlation Transport In Nematic Liquid Crystals

Light diffusion and temporal correlation transport are studied in an orientationally ordered multiply scattering medium. In particular, we experimentally demonstrate the anisotropic diffusion of light through a turbid nematic liquid crystal, and we measure the temporal correlations of these diffused speckle fields for the first time. The measurements are shown to provide useful information about this material, specifically the average rotational viscosity of the director. Computer simulations corroborate both the experimental observations and a more rigorous analytic theoretical formulation of this problem

Effective index of refraction, optical rotation, and circular dichroism in isotropic chiral liquid crystals

This paper concerns optical properties of the isotropic phase above the isotropic-cholesteric transition and of the blue phase BP III. We introduce an effective index, which describes spatial dispersion effects such as optical rotation, circular dichroism, and the modification of the average index due to the fluctuations. We derive the wavelength dependance of these spatial dispersion effects quite generally without relying on an expansion in powers of the chirality and without assuming that the pitch of the cholesteric $P$ is much shorter than the wavelength of the light $\lambda$, an approximation which has been made in previous studies of this problem. The theoretical predictions are supported by comparing them with experimental spectra of the optical activity in the BP III phase.Comment: 15 pages and 7 figures. Submitted to PR

Columnar Molecular Aggregation In The Aqueous Solutions Of Disodium Cromoglycate

Stack, chimneylike, and threadlike assemblies have previously been proposed for the structure of disodium cromoglycate (DSCG) aggregates in aqueous solutions. The results of the synchrotron x-ray scattering investigations reported here reveal the formation of simple columnar assemblies with pi-pi stacking at a separation of 3.4 angstrom between the DSCG molecules. Lateral separation between the assemblies is concentration and temperature dependent, varying from similar to 35 to 42 angstrom in the orientationally ordered nematic (N) phase and from 27 to 32 angstrom in the columnar or middle (M) phase having long range lateral positional order. The assemblies\u27 length depends on concentration and consists of similar to 23 molecules in the N phase, becoming three to ten times larger in the M phase. The scission energy is concentration dependent in the N phase with values similar to 7.19 +/- 0.14 k(B)T (15 wt%), 2.73 +/- 0.4 k(B)T (20 wt%), and 3.05 +/- 0.2 k(B)T (25 wt%). Solutions of all concentrations undergo a spinodal decomposition at temperatures above similar to 40 degrees C, resulting in DSCG-rich regions with the M phase and water-rich regions in the N and isotropic phases

Drawing induced texture and the evolution of superconductive properties with heat treatment time in powder-in-tube in-situ processed MgB2 strands

Monocore powder-in-tube MgB2 strands were cold-drawn and heat-treated at 600C and 700C for times of up to 71 hours and structure-property relationships examined. Drawing-induced elongation of the Mg particles led, after HT, to a textured macrostructure consisting of elongated polycrystalline MgB2 fibers separated by elongated pores. The superconducting Tc, Jc and Fp were correlated with the macrostructure and grain size. Grain size increased with HT time at both 600C and 700C. Jc and hence Fp decreased monotonically but not linearly with grain size. Overall, it was observed that at 700C, the MgB2 reaction was more or less complete after as little as 30 min; at 600C, full reaction completion did not occur until 71 h. into the HT. Transport, Jct(B) was measured in a perpendicular applied field, and the magnetic critical current densities, Jcm\bot(B) and Jcm{\phi}(B), were measured in perpendicular and parallel (axial) applied fields, respectively. Particularly noticeable was the premature dropoff of Jcm\bot(B) at fields well below the irreversibility field of Jct(B). This effect is attributed to the fibrous macrostructure and its accompanying anisotropic connectivity. Magnetic measurements with the field directed along the strand axis yielded a critical density, Jcm\bot(B), for current flowing transversely to the strand axis that was less than and dropped off more rapidly than Jct(B). In the conventional magnetic measurement, the loop currents that support the magnetization are restricted by the lower of Jct(B) and Jcm{\phi} (B). In the present case the latter, leading to the premature dropoff of the measured Jcm(B) compared to Jct(B) with increasing field. This result is supported by Kramer plots of the Jcm{\phi} (B) and Jct(B) data which lead to an irreversibility field for transverse current that is very much less than the usual transport-measured longitudinal one, Birr,t.Comment: 41 pages, 14 figure

Superconducting Microwave Cavity Made of Bulk MgB2

We report the successful manufacture and characterization of a microwave resonant cylindrical cavity made of bulk MgB2 superconductor (Tc = 38.5 K), which has been produced by the Reactive Liquid Mg Infiltration technique. The quality factor of the cavity for the TE011 mode, resonating at 9.79 GHz, has been measured as a function of the temperature. At T = 4.2 K, the unloaded quality factor is 2.2x10^5; it remains of the order of 10^5 up to T ~ 30 K. We discuss the potential performance improvements of microwave cavities built from bulk MgB2 materials produced by reactive liquid Mg infiltration.Comment: 7 pages, 2 embedded figures, accepted for publication in Supercond. Sci. Techno