A secular increase in continental crust nitrogen during the Precambrian

Recent work indicates the presence of substantial geologic nitrogen reservoirs in the mantle and continental crust. Importantly, this geologic nitrogen has exchanged between the atmosphere and the solid Earth over time. Changes in atmospheric nitrogen (i.e. atmospheric mass) have direct effects on climate and biological productivity. It is difficult to constrain, however, the evolution of the major nitrogen reservoirs through time. Here we show a secular increase in continental crust nitrogen through Earth history recorded in glacial tills (2.9 Ga to modern), which act as a proxy for average upper continental crust composition. Archean and earliest Palaeoproterozoic tills contain 66 $\pm$ 100 ppm nitrogen, whereas Neoproterozoic and Phanerozoic tills contain 290 $\pm$ 165 ppm nitrogen, whilst the isotopic composition has remained constant at ~4\permil. Nitrogen has accumulated in the continental crust through time, likely sequestered from the atmosphere via biological fixation. Our findings support dynamic, non-steady state behaviour of nitrogen through time, and are consistent with net transfer of atmospheric N to geologic reservoirs over time.Comment: 14 pages, 2 figures, 2 tables, supplemental informatio

Effects of Ozone Levels on Climate Through Earth History

Molecular oxygen in our atmosphere has increased from less than a part per million in the Archean Eon, to a fraction of a percent in the Proterozoic, and finally to modern levels during the Phanerozoic. While oxygen itself has only minor radiative and climatic effects, the accompanying ozone has important consequences for Earth climate. Using the Community Earth System Model (CESM), a 3-D general circulation model, we test the effects of various levels of ozone on Earth's climate. When CO2 is held constant, the global mean surface temperature decreases with decreasing ozone, with a maximum drop of ~3.5 K at near total ozone removal. By supplementing our GCM results with 1-D radiative flux calculations, we are able to test which changes to the atmosphere are responsible for this temperature change. We find that the surface temperature change is caused mostly by the stratosphere being much colder when ozone is absent; this makes it drier, substantially weakening the greenhouse effect. We also examine the effect of the structure of the upper troposphere and lower stratosphere on the formation of clouds, and on the global circulation. At low ozone, both high and low clouds become more abundant, due to changes in the tropospheric stability. These generate opposing short-wave and long-wave radiative forcings that are nearly equal. The Hadley circulation and tropospheric jet streams are strengthened, while the stratospheric polar jets are weakened, the latter being a direct consequence of the change in stratospheric temperatures. This work identifies the major climatic impacts of ozone, an important piece of the evolution of Earth's atmosphere.</p

Low Simulated Radiation Limit for Runaway Greenhouse Climates

Terrestrial planet atmospheres must be in long-term radiation balance, with solar radiation absorbed matched by thermal radiation emitted. For hot moist atmospheres, however, there is an upper limit on the thermal emission which is decoupled from the surface temperature. If net absorbed solar radiation exceeds this limit the planet will heat uncontrollably, the so-called \runaway greenhouse". Here we show that a runaway greenhouse induced steam atmosphere may be a stable state for a planet with the same amount of incident solar radiation as Earth has today, contrary to previous results. We have calculated the clear-sky radiation limits at line-by-line spectral resolution for the first time. The thermal radiation limit is lower than previously reported (282 W/sq m rather than 310W/sq m) and much more solar radiation would be absorbed (294W/sq m rather than 222W/sq m). Avoiding a runaway greenhouse under the present solar constant requires that the atmosphere is subsaturated with water, and that cloud albedo forcing exceeds cloud greenhouse forcing. Greenhouse warming could in theory trigger a runaway greenhouse but palaeoclimate comparisons suggest that foreseeable increases in greenhouse gases will be insufficient to do this

Faint young Sun paradox remains

The Sun was fainter when the Earth was young, but the climate was generally at least as warm as today; this is known as the `faint young Sun paradox'. Rosing et al. [1] claim that the paradox can be resolved by making the early Earth's clouds and surface less reflective. We show that, even with the strongest plausible assumptions, reducing cloud and surface albedos falls short by a factor of two of resolving the paradox. A temperate Archean climate cannot be reconciled with the low level of CO2 suggested by Rosing et al. [1]; a stronger greenhouse effect is needed.Comment: 3 pages, no figures. In press in Nature. v2 corrects typo in author list in original submissio

A 1D microphysical cloud model for Earth, and Earth-like exoplanets. Liquid water and water ice clouds in the convective troposphere

One significant difference between the atmospheres of stars and exoplanets is the presence of condensed particles (clouds or hazes) in the atmosphere of the latter. The main goal of this paper is to develop a self-consistent microphysical cloud model for 1D atmospheric codes, which can reproduce some observed properties of Earth, such as the average albedo, surface temperature, and global energy budget. The cloud model is designed to be computationally efficient, simple to implement, and applicable for a wide range of atmospheric parameters for planets in the habitable zone. We use a 1D, cloud-free, radiative-convective, and photochemical equilibrium code originally developed by Kasting, Pavlov, Segura, and collaborators as basis for our cloudy atmosphere model. The cloud model is based on models used by the meteorology community for Earth's clouds. The free parameters of the model are the relative humidity and number density of condensation nuclei, and the precipitation efficiency. In a 1D model, the cloud coverage cannot be self-consistently determined, thus we treat it as a free parameter. We apply this model to Earth (aerosol number density 100 cm^-3, relative humidity 77 %, liquid cloud fraction 40 %, and ice cloud fraction 25 %) and find that a precipitation efficiency of 0.8 is needed to reproduce the albedo, average surface temperature and global energy budget of Earth. We perform simulations to determine how the albedo and the climate of a planet is influenced by the free parameters of the cloud model. We find that the planetary climate is most sensitive to changes in the liquid water cloud fraction and precipitation efficiency. The advantage of our cloud model is that the cloud height and the droplet sizes are self-consistently calculated, both of which influence the climate and albedo of exoplanets.Comment: To appear in Icaru

Tidal Venuses: Triggering a Climate Catastrophe via Tidal Heating

Traditionally stellar radiation has been the only heat source considered capable of determining global climate on long timescales. Here we show that terrestrial exoplanets orbiting low-mass stars may be tidally heated at high enough levels to induce a runaway greenhouse for a long enough duration for all the hydrogen to escape. Without hydrogen, the planet no longer has water and cannot support life. We call these planets "Tidal Venuses," and the phenomenon a "tidal greenhouse." Tidal effects also circularize the orbit, which decreases tidal heating. Hence, some planets may form with large eccentricity, with its accompanying large tidal heating, and lose their water, but eventually settle into nearly circular orbits (i.e. with negligible tidal heating) in the habitable zone (HZ). However, these planets are not habitable as past tidal heating desiccated them, and hence should not be ranked highly for detailed follow-up observations aimed at detecting biosignatures. Planets orbiting stars with masses <0.3 solar masses may be in danger of desiccation via tidal heating. We apply these concepts to Gl 667C c, a ~4.5 Earth-mass planet orbiting a 0.3 solar mass star at 0.12 AU. We find that it probably did not lose its water via tidal heating as orbital stability is unlikely for the high eccentricities required for the tidal greenhouse. As the inner edge of the HZ is defined by the onset of a runaway or moist greenhouse powered by radiation, our results represent a fundamental revision to the HZ for non-circular orbits. In the appendices we review a) the moist and runaway greenhouses, b) hydrogen escape, c) stellar mass-radius and mass-luminosity relations, d) terrestrial planet mass-radius relations, and e) linear tidal theories. [abridged]Comment: 59 pages, 11 figures, accepted to Astrobiology. New version includes an appendix on the water loss timescal