42 research outputs found
Rheological and electrical analysis in carbon nanofibre reinforced polypropylene composites
Two different types of carbon nanofibers (CNF) were incorporated in the same polypropylene
(PP) matrix by twin-screw extrusion. The electrical characterization of both CNFs / PP
composites as a function of volume fraction show different electrical performance:
conducting and non-conducting. The objective of this work is to study the rheological
behaviour of both composites with the aim of relating it to the electrical behaviour. The
results indicate that the rheological behaviours are different, suggesting that rheology
differentiates the microstructural variations responsible for the electrical performance.
Furthermore, the main rheological parameters were correlated to the electrical conductivity.
The results show that G´/ G´´ and G´ are the most sensitive parameters when compared to the
onset of electrical percolation. Finally, in spite of the intrinsic measuring differences between
electrical and rheological analysis, the two calculated thresholds are very similar: ~ 0.5 for
the rheological and ~ 0.4 for the electrical.Financial support for this work has been provided by Consellería de Educación e Ordenación
Universitaria, Xunta de Galicia through grant CN2011/008