244 research outputs found

    Historical Biomass Burning: Late 19th Century Pioneer Agriculture Revolution in Northern Hemisphere Ice Core Data and its Atmospheric Interpretation

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    Ice core data from Yukon and Greenland spanning from ∼1750 to 1950 indicate that between ∼1850 and ≤1910 a clear atmospheric signal exists of an episodic biomass burning event that is referred to as the Pioneer Agriculture Revolution. This is best seen in NH4+ ion and particulate concentrations but also in some limited black carbon concentration data, where for all three quantities maximum levels reach about 3 times the prerevolution background concentrations. Tree cellulose δ13C data and some early, controversial, French, air CO2 data, occurring within the same time interval, are interpreted as providing other independent evidence for the same, mainly North American, late 19th century biomass burning event. Some hitherto problematic northern hemisphere ice core derived CO2 concentration data may now be interpreted as containing a biomass burn signal, and these data are compared, especially as to the time of occurrence, with all the other results. A global carbon cycle model simulation of atmospheric CO2 mixing ratios using a maximum input of 3 Gt(C)/yr at northern midlatitudes produces “anomalous” CO2 levels close to some of the ice core carbon dioxide values. However, other values in this data set do not reasonably represent fully mixed atmospheric values. This suggests that these values might be transients but still “tracers” for biomass burning. Nevertheless, it appears possible that interhemispheric CO2 gradients of similar magnitude to the present one could have existed briefly late last century

    Southern Ocean bottom water characteristics in CMIP5 models

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    Southern Ocean deep water properties and formation processes in climate models are indicative of their capability to simulate future climate, heat and carbon uptake, and sea level rise. Southern Ocean temperature and density averaged over 1986–2005 from 15 CMIP5 (Coupled Model Intercomparison Project Phase 5) climate models are compared with an observed climatology, focusing on bottom water. Bottom properties are reasonably accurate for half the models. Ten models create dense water on the Antarctic shelf, but it mixes with lighter water and is not exported as bottom water as in reality. Instead, most models create deep water by open ocean deep convection, a process occurring rarely in reality. Models with extensive deep convection are those with strong seasonality in sea ice. Optimum bottom properties occur in models with deep convection in the Weddell and Ross Gyres. Bottom Water formation processes are poorly represented in ocean models and are a key challenge for improving climate predictions

    Plasmonically Enhanced Reflectance of Heat Radiation from Low-Bandgap Semiconductor Microinclusions

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    Increased reflectance from the inclusion of highly scattering particles at low volume fractions in an insulating dielectric offers a promising way to reduce radiative thermal losses at high temperatures. Here, we investigate plasmonic resonance driven enhanced scattering from microinclusions of low-bandgap semiconductors (InP, Si, Ge, PbS, InAs and Te) in an insulating composite to tailor its infrared reflectance for minimizing thermal losses from radiative transfer. To this end, we compute the spectral properties of the microcomposites using Monte Carlo modeling and compare them with results from Fresnel equations. The role of particle size-dependent Mie scattering and absorption efficiencies, and, scattering anisotropy are studied to identify the optimal microinclusion size and material parameters for maximizing the reflectance of the thermal radiation. For composites with Si and Ge microinclusions we obtain reflectance efficiencies of 57 - 65% for the incident blackbody radiation from sources at temperatures in the range 400 - 1600 {\deg}C. Furthermore, we observe a broadbanding of the reflectance spectra from the plasmonic resonances due to charge carriers generated from defect states within the semiconductor bandgap. Our results thus open up the possibility of developing efficient high-temperature thermal insulators through use of the low-bandgap semiconductor microinclusions in insulating dielectrics.Comment: Main article (8 Figures and 2 Tables) + Supporting Information (8 Figures

    Annotations for Rule-Based Models

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    The chapter reviews the syntax to store machine-readable annotations and describes the mapping between rule-based modelling entities (e.g., agents and rules) and these annotations. In particular, we review an annotation framework and the associated guidelines for annotating rule-based models of molecular interactions, encoded in the commonly used Kappa and BioNetGen languages, and present prototypes that can be used to extract and query the annotations. An ontology is used to annotate models and facilitate their description

    The 1979-2005 Greenland ice sheet melt extent from passive microwave data using an improved version of the melt retrieval XPGR algorithm

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    Analysis of passive microwave satellite observations over the Greenland ice sheet reveals a significant increase in surface melt over the period 1979-2005. Since 1979, the total melt area was found to have increased +1.22 x 10ˆ7 kmˆ2. An improved version of the cross-polarized gradient ratio (XPGR) technique is used to identify the melt from the brightness temperatures. The improvements in the melt retrieval XPGR algorithm as well as the surface melt acceleration are discussed with results from a coupled atmosphere-snow regional climate model. From 1979 to 2005, the ablation period increases everywhere over the melt zone except in the regions where the model simulates an increased summer snowfall. Indeed, more snowfall in summer decreases the liquid water content of the snowpack, raises the albedo and therefore reduces the melt. Finally, this melt acceleration over the Greenland ice sheet is highly correlated with both Greenland and global warming suggesting a continuing surface melt increase in the future.Peer reviewe

    Whispering gallery modes in photoluminescence and Raman spectra of a spherical microcavity with CdTe quantum dots: anti-Stokes emission and interference effects

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    We have studied the photoluminescence and Raman spectra of a system consisting of a polystyrene latex microsphere coated by CdTe colloidal quantum dots. The cavity-induced enhancement of the Raman scattering allows the observation of Raman spectra from only a monolayer of CdTe quantum dots. Periodic structure with very narrow peaks in the photoluminescence spectra of a single microsphere was detected both in the Stokes and anti-Stokes spectral regions, arising from the coupling between the emission of quantum dots and spherical cavity modes
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