Carbon nanotube induced polymer crystallization: The formation of nanohybrid shish–kebabs

AbstractCarbon nanotubes (CNTs) have attracted tremendous attention in recent years because of their superb optical, electronic and mechanical properties. In this article, we aim to discuss CNT-induced polymer crystallization with the focus on the newly discovered nanohybrid shish–kebab (NHSK) structure, wherein the CNT serves as the shish and polymer crystals are the kebabs. Polyethylene (PE) and Nylon 6,6 were successfully decorated on single-walled carbon nanotubes (SWNTs), multi-walled carbon nanotubes (MWNTs), and vapor grown carbon nanofibers (CNFs). The formation mechanism was attributed to “size-dependent soft epitaxy”. Polymer CNT nanocomposites (PCNs) containing PE, Nylon 6,6 were prepared using a solution blending technique. Both pristine CNTs and NHSKs were used as the precursors for the PCN preparation. The impact of CNTs on the polymer crystallization behavior will be discussed. Furthermore, four different polymers were decorated on CNTs using the physical vapor deposition method, forming a two-dimensional NHSK structure. These NHSKs represent a new type of nanoscale architecture. A variety of possible applications will be discussed

Progressive Failure Simulation of Security Cable Barriers

Perimeter security cable barriers are widely used by various agencies all over the world to defeat threat vehicle penetration. New barrier designs require crash test validation prior to implementation. Full-scale vehicular crash tests are costly, whereas designs via finite element simulations are time consuming and require specialized skills. Based on full-scale crash tests, an innovative and simple algorithm has been developed to model the progressive failure of security cable barriers. A multi-body approach based on the first principles of physics was developed to substantially reduce computer runtime. The solution algorithm uses a large number of small time steps. Nonlinear vehicle and cable forces and deformations are calculated based on compatibility conditions. This methodology has been validated against three full-scale crash tests. This cable barrier model, displaying simulation results graphically in a time series, provides realistic response parameters of a security cable barrier design in less than 10 minutes of runtime with reasonable accuracy

MELD score predicts short-term outcomes after surgical management of proximal humerus fractures: a matched analysis

ObjectiveWe aimed to evaluate the difference in 30-day outcomes after surgical management of proximal humerus fractures (PHFs) between patients with and without chronic liver disease as defined by a MELD score greater than 10.DesignThis was a retrospective database review.SettingAll centers participating in the American College of Surgeons National Surgical Quality Improvement Program database were included.Patients/participantsPatients with proximal humerus fractures who (1) underwent ORIF, HA, or SA and (2) had calculable MELD scores were included.InterventionOpen reduction and internal fixation, hemiarthroplasty, or shoulder arthroplasty was used for treatment.Main outcome measurementsThirty-day complications, mortality, readmission, and reoperation rates were measured.ResultsOf the total 1732 PHF patients identified, 300 had a MELD score higher than 10. After propensity matching by significant covariates, MELD score higher than 10 was found to be significantly associated with higher rates of 30-day mortality, 30-day readmission, transfusion within 72 hours, and systemic complications. Among patients with a MELD score higher than 10, treatment with SA or HA instead of ORIF was associated with a higher rate of transfusion and longer operative time. There were no significant differences between treatment cohorts regarding mortality, reoperation, readmission, or complications.ConclusionsA MELD score higher than 10 is associated with higher risk of surgical complications, transfusion, and death in patients undergoing surgery for proximal humerus fractures. Among patients with a MELD score higher than 10, ORIF was associated with a lower transfusion rate and shorter operative time than arthroplasty or hemiarthroplasty.Level of evidencePrognostic Level III

Quantitative microstructure characterization of Ag nanoparticle sintered joints for power die attachment

The samples of sintered Ag joints for power die attachments were prepared using paste of Ag nanoparticles at 240 °C and 5 MPa for 3 to 17 minutes. Their microstructural features were quantitatively characterized with scanning elec-tronic microscopy, transmission electron microscopy, X-ray diffraction and image analysis method. The resulting nor-malized thickness, pore size and porosity decreased, and grain size increased with increasing the sintering time. A time dependence of the form t1/n with n close to 2 or 3 can be further derived for the kinetics of the thinning, densification and grain growth within the sintered Ag joints

Effect of fiber inclination on crack bridging stress in brittle fiber reinforced brittle matrix composites

behavior of brittle matrix composites is strongly affected by the bridging of cracks by fibers. In random fiber composites, fibers can lie at an angle to the crack plane. Under such conditions, the bridging stress for a certain crack opening is governed by various micromechanisms including fiber debonding, fiber bending and rupture as well as matrix spalling. While fiber debonding has been widely investigated, the coupled fiber bending/matrix spalling mechanism has received little attention. In this paper, the fiber bending/matrix spalling mechanism is analyzed by treating the fiber as a beam bent on an elastic foundation with variable stiffness and the possibility of spalling. The foundation stiffness and spalling criterion are derived from a finite element analysis. The bridging stress due to bending alone as well as the total bridging stress are then obtained for the case with brittle fibers. Through this analysis, the effect of various microstructural parameters (such as fiber and matrix moduli, matrix spalling strain and fiber/matrix interfacial friction) on the behavior of random fiber composites can be studied. Prediction of maximum bridging stress for inclined fibers based on the present model is shown to be in good agreement with experimental results.Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/29939/1/0000296.pd

Investigation of campylobacter concisus gastric epithelial pathogenicity using AGS cells

Campylobacter concisus is an oral bacterium. Recent studies suggest that C. concisus may be involved in human gastric diseases. The mechanisms, however, by which C. concisus causes human gastric diseases have not been investigated. Here we examined the gastric epithelial pathogenicity of C. concisus using a cell culture model. Six C. concisus strains and the human gastric epithelial cell line AGS cells were used. IL-8 produced by AGS cells after incubation with C. concisus was measured using enzyme-linked immunosorbent assay (ELISA), and AGS cell apoptosis was determined by caspase 3/7 activities. The effects of C. concisus on actin arrangement in AGS cells was determined using fluorescence staining. The effects of C. concisus on global gene expression in AGS cells was determined by transcriptomic analysis and quantitative real-time PCR (qRT-PCR). The role of the upregulated CYP1A1 gene in gastric cancer survival was assessed using the Kaplan-Meier method. C. concisus induced production of IL-8 by AGS cells with strain variation. Significantly increased caspase 3/7 activities were observed in AGS cells incubated with C. concisus strains when compared to AGS cells without bacteria. C. concisus induced actin re-arrangement in AGS cells. C. concisus upregulated 30 genes in AGS cells and the upregulation of CYP1A1 gene was confirmed by qRT-PCR. The Kaplan-Meier analysis showed that upregulation of CYP1A1 gene is associated with worse survival in gastric cancer patients. Our findings suggest that C. concisus may play a role in gastric inflammation and the progression of gastric cancer. Further investigation in clinical studies is warranted