11 research outputs found

    Cross-cutting principles for planetary health education

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    Since the 2015 launch of the Rockefeller Foundation Lancet Commission on planetary health,1 an enormous groundswell of interest in planetary health education has emerged across many disciplines, institutions, and geographical regions. Advancing these global efforts in planetary health education will equip the next generation of scholars to address crucial questions in this emerging field and support the development of a community of practice. To provide a foundation for the growing interest and efforts in this field, the Planetary Health Alliance has facilitated the first attempt to create a set of principles for planetary health education that intersect education at all levels, across all scales, and in all regions of the world—ie, a set of cross-cutting principles

    Organic carbon dataset of paper submitted to Journal of Geophysical Research: Biogeosciences entitled "Seasonal and Spatial Variability of Dissolved Carbon Concentration and Composition in Lake Michigan Tributaries"

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    Dissolved organic matter (DOM) is a complex mixture of many compounds, and its composition dictates numerous reactions in the environment. Large lakes and marine coastlines receive DOM from watersheds that differ widely in their land cover, with potential implications for both the quantity and composition of carbon inputs. Seasonal variation in DOM quantity and composition may also differ among tributaries and be mediated by land cover. Here, we quantify spatial (i.e., among tributary) and seasonal variation in DOM concentration, DOM composition based on ultraviolet-visible spectroscopy, and alkalinity across 101 tributaries of Lake Michigan, one of the world’s largest lakes, using a synoptic sampling approach. Wetland land cover has the largest effect on DOM, producing high concentrations of DOM that is more aromatic and larger in apparent molecular weight. Seasonal variation is also pronounced, with concentrations and aromaticity of DOM peaking in fall across most tributaries. Watershed lithology and land cover both affect alkalinity, with higher values associated with the geography of carbonate bedrock and in urbanized watersheds. Watershed land cover has a larger affect than season on all organic carbon parameters. However, seasonal variation is especially important for DOM composition. This disparity suggests that environmental processing of DOM within river channels mediates its composition more than its concentrations. Considering the wide range of land cover and lithology around Lake Michigan and other large water bodies, accounting for both spatial and seasonal dynamics is essential for understanding controls on DOM delivery.SMB was supported by NSF CBET (1802388). Additional funding for this work was provided by a Department of Interior Northeast Climate Adaptation Science Center graduate fellowship to RJM. Additional funds were provided to RJM through a UW-Madison Department of Zoology Graduate Fellowship

    Mechanosynthesis of a Coamorphous Formulation of Creatine with Citric Acid and Humidity–Mediated Transformation into a Cocrystal

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    We report a simple, efficient, and scalable mechanochemical method of preparation of new creatine fitness supplement with increased solubility (compared to the creatine monohydrate) and decreased acidity (compared to creatine hydrochloride)

    Peritectic Phase Transition of Benzene and Acetonitrile and Formation of a Cocrystal Relevant to Titan, Saturn’s Icy Moon

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    Benzene and acetonitrile are two of the most commonly used solvents found in almost every chemical laboratory. Titan, Saturn’s icy moon, is one other place in the Solar system that has even larger amounts of these compounds, together with many other hydrocarbons. On Titan, organic molecules are produced in the atmosphere and carried by methane rainfall to the surface, where they either dissolve in the lakes, deposit as sandy dunes, or solidify as minerals with complex composition and structure. In order to untangle these structural complexities a reliable model of the phase behavior of these compounds at temperatures relevant to Titan is crucial. We therefore report the composition–temperature binary phase diagram of acetonitrile and benzene, and provide a detailed account of the structure and composition of the phases. This work is based on differential scanning calorimetry and in situ powder diffraction analyses with synchrotron X-ray radiation and supported by theoretical modeling. Benzene and acetonitrile were found to undergo a peritectic reaction into a cocrystal with a 1:3 acetonitrile:benzene stoichiometry. The crystal structure was solved and refined in the polar space group, R3, and the solution was confirmed and optimized by energy minimization calculations. To mimic the environment on Titan more accurately, we tested the stability of the structure under liquid ethane. The diffraction data indicate that the cocrystal undergoes further change upon contact with ethane. These results provide new insights into the structure and stability of a potential mineral on Titan, and contribute to the fundamental knowledge of some of the smallest organic molecule

    Relationship between Inertial features of the upper extremity and simple reaction time in boys and girls aged 17-18

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    The latent period of visual sensor motor reaction depends, in part, on the sensory and integrative processes in the brain, but is also influenced by the rate of the muscle contraction. There is no clear evidence in the literature whether the rotational inertia of segments of limbs has any direct effect on the reaction time. The aim of our study was to identify this relationship . The study involved 566 right handed students aged 16–17 of both genders beginning their post puberty period. Reaction time was measured during experimental adduction of the forearm and hand, using a special rotating handle and lever connected to a computer that recorded the reaction time (~1 ms). Calculations of the rotational inertia were carried out using regression models by Zatsiorsky and other authors. Each gender group was divided into three subgroups: with high, medium and low values of rotational inertia. It was found that individuals with high values of rotational inertia of forearm and wrist demonstrated significantly longer reaction times. This pattern was apparent in both gender groups. Although males illustrated greater values of rotational inertia than females they demonstrated relatively shorter reaction times. This contradiction can be explained by greater muscle power of young men. We recommend taking into account the amount of rotational inertia of the responsive segment in all kinds of research which require measurement of reaction time. The article was translated by the authors
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