Gate-induced blueshift and quenching of photoluminescence in suspended single-walled carbon nanotubes

Gate-voltage effects on photoluminescence spectra of suspended single-walled carbon nanotubes are investigated. Photoluminescence microscopy and excitation spectroscopy are used to identify individual nanotubes and to determine their chiralities. Under an application of gate voltage, we observe slight blueshifts in the emission energy and strong quenching of photoluminescence. The blueshifts are similar for different chiralities investigated, suggesting extrinsic mechanisms. In addition, we find that the photoluminescence intensity quenches exponentially with gate voltage.Comment: 4 pages, 4 figure

Exciton diffusion in air-suspended single-walled carbon nanotubes

Direct measurements of the diffusion length of excitons in air-suspended single-walled carbon nanotubes are reported. Photoluminescence microscopy is used to identify individual nanotubes and to determine their lengths and chiral indices. Exciton diffusion length is obtained by comparing the dependence of photoluminescence intensity on the nanotube length to numerical solutions of diffusion equations. We find that the diffusion length in these clean, as-grown nanotubes is significantly longer than those reported for micelle-encapsulated nanotubes.Comment: 4 pages, 4 figure

High-Tc superconductivity in entirely end-bonded multi-walled carbon nanotubes

We report that entirely end-bonded multi-walled carbon nanotubes (MWNTs) can show superconductivity with the transition temperature Tc as high as 12K that is approximately 40-times larger than those reported in ropes of single-walled nanotubes. We find that emergence of this superconductivity is very sensitive to junction structures of Au electrode/MWNTs. This reveals that only MWNTs with optimal numbers of electrically activated shells, which are realized by the end-bonding, can allow the superconductivity due to inter shell effects.Comment: 5 page

Meissner effect in honeycomb arrays of multi-walled carbon nanotubes

We report Meissner effect for type-II superconductors with a maximum Tc of 19 K, which is the highest value among those in new-carbon related superconductors, found in the honeycomb arrays of multi-walled CNTs (MWNTs). Drastic reduction of ferromagnetic catalyst and efficient growth of MWNTs by deoxidization of catalyst make the finding possible. The weak magnetic anisotropy, superconductive coherence length (- 7 nm), and disappearance of the Meissner effect after dissolving array structure indicate that the graphite structure of an MWNT and those intertube coupling in the honeycomb array are dominant factors for the mechanism.Comment: 6 page

Enhancement of carbon nanotube photoluminescence by photonic crystal nanocavities

Photonic crystal nanocavities are used to enhance photoluminescence from single-walled carbon nanotubes. Micelle-encapsulated nanotubes are deposited on nanocavities within Si photonic crystal slabs and confocal microscopy is used to characterize the devices. Photoluminescence spectra and images reveal nanotube emission coupled to nanocavity modes. The cavity modes can be tuned throughout the emission wavelengths of carbon nanotubes, demonstrating the ability to enhance photoluminescence from a variety of chiralities.Comment: 4 pages, 3 figure

Controlled laser heating of carbon nanotubes

We investigate laser heating of double wall carbon nanotubes deposited on surfaces and immerged in liquids as a function of laser wavelength. Observing the Raman spectrum we find that laser heating of agglomerated double wall carbon nanotubes is six times larger at 488 nm than at 647 nm. The wavelength dependence of the Raman G band is linear in the visible spectral range. The frequency shift of the Raman G band obtained in methanol as a function of temperature is close to what is observed for graphite

Fe/Co Alloys for the Catalytic Chemical Vapor Deposition Synthesis of Single- and Double-Walled Carbon Nanotubes (CNTs). 1. The CNT−Fe/Co−MgO System

Mg0.90FexCoyO (x + y ) 0.1) solid solutions were synthesized by the ureic combustion route. Upon reduction at 1000 °C in H2-CH4 of these powders, Fe/Co alloy nanoparticles are formed, which are involved in the formation of carbon nanotubes, which are mostly single and double walled, with an average diameter close to 2.5 nm. Characterizations of the materials are performed using 57Fe Mo¨ssbauer spectroscopy and electron microscopy, and a well-established macroscopic method, based on specific-surface-area measurements, was applied to quantify the carbon quality and the nanotubes quantity. A detailed investigation of the Fe/Co alloys’ formation and composition is reported. An increasing fraction of Co2+ ions hinders the dissolution of iron in the MgO lattice and favors the formation of MgFe2O4-like particles in the oxide powders. Upon reduction, these particles form R-Fe/Co particles with a size and composition (close to Fe0.50Co0.50) adequate for the increased production of carbon nanotubes. However, larger particles are also produced resulting in the formation of undesirable carbon species. The highest CNT quantity and carbon quality are eventually obtained upon reduction of the iron-free Mg0.90Co0.10O solid solution, in the absence of clusters of metal ions in the starting material. Introduction Catalyti

Enhanced photo-sensitivity in a Si photodetector using a near-field assisted excitation

Silicon is an indispensable material in electric device technology. However, Si is an indirect bandgap material; therefore, its excitation efficiency, which requires phonon assistance, is low under propagating far-field light. To improve the excitation efficiency, herein we performed optical near-field excitation, which is confined in a nano-scale, where the interband transitions between different wave numbers are excited according to the uncertainty principle; thus, optical near-field can directly excite the carrier in the indirect bandgap. To evaluate the effect of optical near-field confined in a nano-scale, we fabricate the lateral Si p-n junction with Au nanoparticles as sources to generate the field confinement. We observed a 47.0% increase in the photo-sensitivity rate. In addition, by using the thin lateral p-n junction, which eliminates the far-field excitation, we confirmed a 42.3% increase in the photo-sensitivity rate