Investigation of graphene as electrode in n-type OFETs and its use in nanometric devices

This work aims to investigate the use of CVD-graphene as electrode material in nanometric channel n-type Organic Field Effect Transistors (OFETs) based on thermally evaporated thin films of the perylene-3,4,9,10-tetracarboxylic acid diimide derivatives (PDIF-CN2 and PDI8-CN2). We firstly explored the electrical response of nano devices with standard bottom-contact/ distributed bottom gate architecture. By a thorough comparison with short channel transistors made with gold electrodes, output characteristics of the graphene-based devices suggests that SCLC contribution is suppressed. Moreover, current on/off ratios independent of the channel length (L) and enhanced response for high longitudinal biases are demonstrated for (L) down to 140 nm. Further advances have been reached by the use of a proper device architecture for nano devices with patterned local gate tracks and an ultra-thin films (8nm) of Hafnium Dioxide as high-k gate dielectric. The largely improved gate modulation results in a proper output currents saturation for channel length down to 200nm, with supply biases of few volts. Through impedance spectroscopy, overlap capacitances and the overall AC response of CVD-graphene electrodes have been investigated as well. The cut-off frequency of the nanodevice has been indirectly evaluated considering the DC transconductance and the measured overlap capacitance of the graphene electrodes. Values of the order of 150 kHz has been obtained for channel lengths of 200nm. Lastly, the organic/graphene interfaces and their injection and extraction phenomena have been further investigated in micrometric architectures. In particular, the problem of contact resistances have been analyzed via Scanning Kelvin Probe Force Microscopy (SKPFM) and the energetics of the interfaces has been reconstructed by the analysis of UV Photoelectron Spectroscopy (UPS) and X-ray Photoelectron Spectroscopy (XPS)

Perylene-diimide molecules with cyano functionalization for electron-transporting transistors

Core-cyanated perylene diimide (PDI_CY) derivatives are molecular compounds exhibiting an uncommon combination of appealing properties, including remarkable oxidative stability, high electron affinities, and excellent self-assembling properties. Such features made these compounds the subject of study for several research groups aimed at developing electron-transporting (n-type) devices with superior charge transport performances. After about fifteen years since the first report, field-effect transistors based on PDI_CY thin films are still intensely investigated by the scientific community for the attainment of n-type devices that are able to balance the performances of the best p-type ones. In this review, we summarize the main results achieved by our group in the fabrication and characterization of transistors based on PDI8-CN2 and PDIF-CN2 molecules, undoubtedly the most renowned compounds of the PDI_CY family. Our attention was mainly focused on the electrical properties, both at the micro and nanoscale, of PDI8-CN2 and PDIF-CN2 films deposited using different evaporation techniques. Specific topics, such as the contact resistance phenomenon, the bias stress effect, and the operation in liquid environment, have been also analyzed

Correction: Space-charge accumulation and band bending at conductive P3HT/PDIF-CN₂ interfaces investigated by scanning-Kelvin probe microscopy

Correction for 'Space-charge accumulation and band bending at conductive P3HT/PDIF-CN2 interfaces investigated by scanning-Kelvin probe microscopy' by Federico Chianese et al., J. Mater. Chem. C, 2021, DOI: 10.1039/d1tc04840f

Investigation of dark count rate in NbRe microstrips for single photon detection

Superconducting microstrip single photon detectors (SMSPDs) received great interest since they are expected to combine the excellent performance of superconducting nanostrip single photon detectors with the possibility to cover large active areas using low-cost fabrication techniques. In this work, we fabricated SMSPDs based on NbRe to investigate the role of vortices in the dark counts events in this innovative material and in devices with micrometer size. We realized devices with different layouts, namely single microstrips and pairs of parallel microstrips. The energy barriers related to the motion of single vortices or vortex-antivortex pairs, responsible of detection events, have been determined and compared with the ones of similar devices based on different materials, such as MoSi, WSi and NbN. The analysis confirms the high potential of NbRe for the realization of superconducting single photon detectors with large areas

Notulae to the Italian native vascular flora: 10

In this contribution, new data concerning the distribution of native vascular flora in Italy are presented. It includes new records, confirmations, exclusions, and status changes to the Italian administrative regions for taxa in the genera Artemisia, Chaetonychia, Cirsium, Cynanchum, Genista, Hieracium, Iberis, Melica, Misopates, Myosotis, Thalictrum, Trifolium, Utricularia, Veronica, and Vicia. Nomenclatural and distribution updates, published elsewhere, and corrigenda are provided as supplementary material

Notulae to the Italian native vascular flora: 4

In this contribution new data concerning the distribution of native vascular flora in Italy are presented. It includes new records, exclusion, extinction and confirmations to the Italian administrative regions for taxa in the genera Androsace, Artemisia, Fragaria, Melampyrum, Myosotis, Petrorhagia, Phillyrea, Rosa, Rumex, Spiranthes, Trifolium, and Vicia. Furthermore, a new combination in the genus Omalotheca is proposed

POLIMORFISMO DELL'ALFA S1 CASEINA E PARAMETRI DI COAGULAZIONE DEL LATTE DI CAPRA

SALSOMAGGIORE TERM

Molecular Doping of CVD-Graphene Surfaces by Perfluoroalkyl-Substituted Perylene Diimides Derivatives

Non-covalent π-π and dipolar interactions with small aromatic molecules have been widely demonstrated to be a valid option to tune graphene work functions without adding extrinsic scattering centers for charge carriers. In this work, we investigated the interaction between a CVD-graphene monolayer and a thermally evaporated sub-monolayer and the following few-layer thin films of similar perylene diimide derivatives: PDI8-CN2 and PDIF-CN2. The molecular influence on the graphene work function was estimated by XPS and UPS analysis and by investigating the surface potentials via scanning Kelvin probe force microscopy. The perfluorinated decoration and the steric interaction in the early stages of the film growth determined a positive work function shift as high as 0.7 eV in the case of PDIF-CN2, with respect to the value of 4.41 eV for the intrinsic graphene. Our results unambiguously highlight the absence of valence band shifts in the UPS analysis, indicating the prevalence of dipolar interactions between the graphene surface and the organic species enhanced by the presence of the fluorine-enriched moieties