649 research outputs found
Room temperature near-ultraviolet emission from In-rich InGaN/GaN multiple quantum wells
We grew In-rich InGaNGaN multiple quantum wells (MQWs) using growth interruption (GI) by metalorganic chemical vapor deposition. The quality of overgrown InGaNGaN QW layers in MQWs was largely affected by the crystalline quality and interfacial abruptness of the underlying QW layer. Introduction of 10 s GI was very effective in improving the crystalline quality and interfacial abruptness of InGaN QW layers, and we grew a ten periods of 1-nm -thick In-rich InGaNGaN MQW with 10 s GI and obtained a strong near-ultraviolet (UV) emission (~390 nm) at room temperature. We believe that use of less than 1-nm -thick In-rich InGaN MQW can be a candidate for near-UV source, which might replace the conventional low-indium content (<10%), thicker InGaN QW layer.open313
Electronic Liquid Crystal Phases of a Doped Mott Insulator
The character of the ground state of an antiferromagnetic insulator is
fundamentally altered upon addition of even a small amount of charge. The added
charges agglomerate along domain walls at which the spin correlations, which
may or may not remain long-ranged, suffer a phase shift. In two
dimensions, these domain walls are ``stripes'' which are either insulating, or
conducting, i.e. metallic rivers with their own low energy degrees of freedom.
However, quasi one-dimensional metals typically undergo a transition to an
insulating ordered charge density wave (CDW) state at low temperatures. Here it
is shown that such a transition is eliminated if the zero-point energy of
transverse stripe fluctuations is sufficiently large in comparison to the CDW
coupling between stripes. As a consequence, there exist novel,
liquid-crystalline low-temperature phases -- an electron smectic, with
crystalline order in one direction, but liquid-like correlations in the other,
and an electron nematic with orientational order but no long-range positional
order. These phases, which constitute new states of matter, can be either high
temperature supeconductors or two-dimensional anisotropic ``metallic''
non-Fermi liquids. Evidence for the new phases may already have been obtained
by neutron scattering experiments in the cuprate superconductor,
La_{1.6-x}Nd_{0.4}Sr_xCuO_{4}.Comment: 5 pages in RevTex with two figures in ep
Engineered mussel bioglue as a functional osteoinductive binder for grafting of bone substitute particles to accelerate in vivo bone regeneration
Xenograft bone substitutes, such as deproteinized bovine bone mineral (DBBM), have been widely employed as osteoconductive structural materials for bone tissue engineering. However, the loss of xenograft bone substitute particles in defects has been a major limitation, along with a lack of osteoinductive function. Mussel adhesive protein (MAP), a remarkable and powerful adhesive biomaterial in nature, can attach to various substrates, even in wet environments. Its adhesive and water-resistant abilities are considered to be mainly derived from the reduced catechol form, 3,4-dihydroxyphenylalanine (DOPA), of its tyrosine residues. Here, we evaluated the use of DOPA-containing MAP as a functional binder biomaterial to effectively retain DBBM particles at the defect site during in vivo bone regeneration. We observed that DOPA-containing MAP was able to bind DBBM particles easily to make an aggregate, and grafted DBBM particles were not lost in a defect in the rat calvaria during the healing period. Importantly, grafting of a DOPA-containing MAP-bound DBBM aggregate resulted in remarkably accelerated in vivo bone regeneration and even bone remodeling. Interestingly, we found that the DOPA residues in the modified MAP had an osteoinductive ability based on clear observation of the in vivo maturation of new bones with a similar bone density to the normal bone and of the in vitro osteogenic differentiation of osteoblast cells. Collectively, DOPA-containing MAP is a promising functional binder biomaterial for xenograft bone substitute-assisted bone regeneration with enhanced osteoconductivity and acquired osteoinductivity. This mussel glue could also be successfully utilized as a potential biomaterial for general bone tissue engineering.open1145sciescopu
Ferroelectricity induced by interatomic magnetic exchange interaction
Multiferroics, where two or more ferroic order parameters coexist, is one of
the hottest fields in condensed matter physics and materials science[1-9].
However, the coexistence of magnetism and conventional ferroelectricity is
physically unfavoured[10]. Recently several remedies have been proposed, e.g.,
improper ferroelectricity induced by specific magnetic[6] or charge orders[2].
Guiding by these theories, currently most research is focused on frustrated
magnets, which usually have complicated magnetic structure and low magnetic
ordering temperature, consequently far from the practical application. Simple
collinear magnets, which can have high magnetic transition temperature, have
never been considered seriously as the candidates for multiferroics. Here, we
argue that actually simple interatomic magnetic exchange interaction already
contains a driving force for ferroelectricity, thus providing a new microscopic
mechanism for the coexistence and strong coupling between ferroelectricity and
magnetism. We demonstrate this mechanism by showing that even the simplest
antiferromagnetic (AFM) insulator MnO, can display a magnetically induced
ferroelectricity under a biaxial strain
Measuring every particle's size from three-dimensional imaging experiments
Often experimentalists study colloidal suspensions that are nominally
monodisperse. In reality these samples have a polydispersity of 4-10%. At the
level of an individual particle, the consequences of this polydispersity are
unknown as it is difficult to measure an individual particle size from
microscopy. We propose a general method to estimate individual particle radii
within a moderately concentrated colloidal suspension observed with confocal
microscopy. We confirm the validity of our method by numerical simulations of
four major systems: random close packing, colloidal gels, nominally
monodisperse dense samples, and nominally binary dense samples. We then apply
our method to experimental data, and demonstrate the utility of this method
with results from four case studies. In the first, we demonstrate that we can
recover the full particle size distribution {\it in situ}. In the second, we
show that accounting for particle size leads to more accurate structural
information in a random close packed sample. In the third, we show that crystal
nucleation occurs in locally monodisperse regions. In the fourth, we show that
particle mobility in a dense sample is correlated to the local volume fraction.Comment: 7 pages, 5 figure
Effective connectivity during working memory and resting states: A DCM study
Although the relationship between resting-state functional connectivity and task-related activity has been addressed, the relationship between task and resting-state directed or effective connectivity – and its behavioral concomitants – remains elusive. We evaluated effective connectivity under an N-back working memory task in 24 participants using stochastic dynamic causal modelling (DCM) of 7 T fMRI data. We repeated the analysis using resting-state data, from the same subjects, to model connectivity among the same brain regions engaged by the N-back task. This allowed us to: (i) examine the relationship between intrinsic (task-independent) effective connectivity during resting (Arest) and task states (Atask), (ii) cluster phenotypes of task-related changes in effective connectivity (Btask) across participants, (iii) identify edges (Btask) showing high inter-individual effective connectivity differences and (iv) associate reaction times with the similarity between Btaskand Arestin these edges. We found a strong correlation between Arestand Ataskover subjects but a marked difference between Btaskand Arest. We further observed a strong clustering of individuals in terms of Btask, which was not apparent in Arest. The task-related effective connectivity Btaskvaried highly in the edges from the parietal to the frontal lobes across individuals, so the three groups were clustered mainly by the effective connectivity within these networks. The similarity between Btaskand Arestat the edges from the parietal to the frontal lobes was positively correlated with 2-back reaction times. This result implies that a greater change in context-sensitive coupling – from resting-state connectivity – is associated with faster reaction times. In summary, task-dependent connectivity endows resting-state connectivity with a context sensitivity, which predicts the speed of information processing during the N-back task
Thermoelectric properties of Cu-dispersed bi0.5sb1.5te3
A novel and simple approach was used to disperse Cu nanoparticles uniformly in the Bi0.5Sb1.5Te3 matrix, and the thermoelectric properties were evaluated for the Cu-dispersed Bi0.5Sb1.5Te3. Polycrystalline Bi0.5Sb1.5Te3 powder prepared by encapsulated melting and grinding was dry-mixed with Cu(OAc)2 powder. After Cu(OAc)2 decomposition, the Cu-dispersed Bi0.5Sb1.5Te3 was hot-pressed. Cu nanoparticles were well-dispersed in the Bi0.5Sb1.5Te3 matrix and acted as effective phonon scattering centers. The electrical conductivity increased systematically with increasing level of Cu nanoparticle dispersion. All specimens had a positive Seebeck coefficient, which confirmed that the electrical charge was transported mainly by holes. The thermoelectric figure of merit was enhanced remarkably over a wide temperature range of 323-523 K
Probing the Interplay between Quantum Charge Fluctuations and Magnetic Ordering in LuFe2O4
Ferroelectric and ferromagnetic materials possess spontaneous electric and
magnetic order, respectively, which can be switched by the corresponding
applied electric and magnetic fields. Multiferroics combine these properties in
a single material, providing an avenue for controlling electric polarization
with a magnetic field and magnetism with an electric field. These materials
have been intensively studied in recent years, both for their fundamental
scientific interest as well as their potential applications in a broad range of
magnetoelectric devices [1, 2, 3, 4]. However, the microscopic origins of
magnetism and ferroelectricity are quite different, and the mechanisms
producing strong coupling between them are not always well understood. Hence,
gaining a deeper understanding of magnetoelectric coupling in these materials
is the key to their rational design. Here, we use ultrafast optical
spectroscopy to show that quantum charge fluctuations can govern the interplay
between electric polarization and magnetic ordering in the charge-ordered
multiferroic LuFe2O4
Magnetic field-temperature phase diagram of multiferroic (NH4)2FeCl5??H2O
Owing to their overall low energy scales, flexible molecular architectures, and ease of chemical substitution, molecule-based multiferroics are extraordinarily responsive to external stimuli and exhibit remarkably rich phase diagrams. Even so, the stability and microscopic properties of various magnetic states in close proximity to quantum critical points are highly under-explored in these materials. Inspired by these opportunities, we combined pulsed-field magnetization, first-principles calculations, and numerical simulations to reveal the magnetic field???temperature (B???T) phase diagram of multiferroic (NH4)2FeCl5???H2O. In this system, a network of intermolecular hydrogen and halogen bonds creates a competing set of exchange interactions that generates additional structure in the phase diagram???both in the vicinity of the spin flop and near the 30 T transition to the fully saturated state. Consequently, the phase diagrams of (NH4)2FeCl5???H2O and its deuterated analog are much more complex than those of other molecule-based multiferroics. The entire series of coupled electric and magnetic transitions can be accessed with a powered magnet, opening the door to exploration and control of properties in this and related materials
One-dimensional nature of the magnetic fluctuations in YBaCuO
There is increasing evidence that inhomogeneous distributions of charge and
spin--so-called "striped phases"--play an important role in determining the
properties of the high-temperature superconductors. For example, recent
neutron-scattering measurements on the YBaCuO family of
materials show both spin and charge fluctuations that are consistent with the
striped-phase picture. But the fluctuations associated with a striped phase are
expected to be one-dimensional, whereas the magnetic fluctuations observed to
date appear to display two-dimensional symmetry. We show here that this
apparent two-dimensionality results from measurements on twinned crystals, and
that similar measurements on substantially detwinned crystals of
YBaCuO reveal the one-dimensional character of the magnetic
fluctuations, thus greatly strengthening the striped-phase interpretation.
Moreover, our results also suggest that superconductivity originates in charge
stripes that extend along the b crystal axis, where the superfluid density is
found to be substantially larger than for the a direction.Comment: 3 pages, PDF onl
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