100 research outputs found
Dynamical Image Charge Effect in Molecular Tunnel Junctions: Beyond Energy Level Alignment
When an electron tunnels between two metal contacts it temporarily induces an
image charge (IC) in the electrodes which acts back on the tunneling electron.
It is usually assumed that the IC forms instantaneously such that a static
model for the image potential applies. Here we investigate how the finite IC
formation time affects charge transport through a molecule suspended between
two electrodes. For a single level model, an analytical treatment shows that
the conductance is suppressed by a factor (compared to the static IC
approximation) where is the quasiparticle renormalization factor. We show
that can be expressed either in terms of the plasma frequency of the
electrode or as the overlap between the ground states of the electrode with and
without an electron on the molecule. First-principles GW calculations for
benzene-diamine connected to gold electrodes show that the dynamical
corrections can reduce the conductance by more than a factor of two.Comment: 5 pages, 3 figure
Molecular Realization of a Quantum NAND Tree
The negative-AND (NAND) gate is universal for classical computation making it
an important target for development. A seminal quantum computing algorithm by
Farhi, Goldstone and Gutmann has demonstrated its realization by means of
quantum scattering yielding a quantum algorithm that evaluates the output
faster than any classical algorithm. Here, we derive the NAND outputs
analytically from scattering theory using a tight-binding (TB) model and show
the restrictions on the TB parameters in order to still maintain the NAND gate
function. We map the quantum NAND tree onto a conjugated molecular system, and
compare the NAND output with non-equilibrium Green's function (NEGF) transport
calculations using density functional theory (DFT) and TB Hamiltonians for the
electronic structure. Further, we extend our molecular platform to show other
classical gates that can be realized for quantum computing by scattering on
graphs.Comment: 17 pages, 6 figures, 1 tabl
Finite Bias Calculations to Model Interface Dipoles in Electrochemical Cells at the Atomic Scale
The structure of an electrochemical interface is not determined by any external electrostatic field, but rather by external chemical potentials. This paper demonstrates that the electric double layer should be understood fundamentally as an internal electric field set up by the atomic structure to satisfy the thermodynamic constraints imposed by the environment. This is captured by the generalized computational hydrogen electrode model, which enables us to make efficient first-principles calculations of atomic scale properties of the electrochemical interface
Phosphomolybdic acid-responsive Pickering emulsions stabilized by ionic liquid functionalized Janus nanosheets
<p><b>A</b> Representative photomicrographs of Caspase-3 immunofluorescence staining (400Ă). <b>B</b> Quantification of Caspase-3 fluorescence intensity in different groups. <b>C</b> Representative Western blot band of Caspase-3 activation in the ischemic cortex at 24 h after reperfusion. <b>D</b> Effect of LBP (40 mg/kg) on the Caspase-3 activation in MCAO mice cortex at 24 h after reperfusion. Data are expressed as mean±SEM (nâ=â6). <sup>##</sup>P<0.01 vs. sham-operated group; **P<0.01 vs. vehicle group.</p
Decadal soil carbon accumulation across Tibetan permafrost regions
Acknowledgements We thank the members of Peking University Sampling Teams (2001â2004) and IBCAS Sampling Teams (2013â2014) for assistance in field data collection. We also thank the Forestry Bureau of Qinghai Province and the Forestry Bureau of Tibet Autonomous Region for their permission and assistance during the sampling process. This study was financially supported by the National Natural Science Foundation of China (31670482 and 31322011), National Basic Research Program of China on Global Change (2014CB954001 and 2015CB954201), Chinese Academy of Sciences-Peking University Pioneer Cooperation Team, and the Thousand Young Talents Program.Peer reviewedPostprintPostprin
Single-Molecule Electrochemical Transistor Utilizing a Nickel-Pyridyl Spinterface
Using a scanning tunnelling microscope
break-junction technique,
we produce 4,4âČ-bipyridine (44BP) single-molecule junctions
with Ni and Au contacts. Electrochemical control is used to prevent
Ni oxidation and to modulate the conductance of the devices via nonredox
gatingîžthe first time this has been shown using non-Au contacts.
Remarkably the conductance and gain of the resulting Ni-44BP-Ni electrochemical
transistors is significantly higher than analogous Au-based devices.
Ab-initio calculations reveal that this behavior arises because charge
transport is mediated by spin-polarized Ni <i>d</i>-electrons,
which hybridize strongly with molecular orbitals to form a âspinterfaceâ.
Our results highlight the important role of the contact material for
single-molecule devices and show that it can be varied to provide
control of charge and spin transport
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