310 research outputs found

    Topological quantum phase transition in an S=2 spin chain

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    We construct a model Hamiltonian for S = 2 spin chain, where a variable parameter α\alpha is introduced. The edge spin is S = 1 for α=0\alpha = 0, and S = 3/2 for α=1\alpha = 1. Due to the topological distinction of the edge states, these two phases must be separated by one or several topological quantum phase transitions. We investigate the nature of the quantum phase transition by DMRG calculation, and propose a phase diagram for this model.Comment: 5 pages, 4 figure

    Detection and localization of closely distributed damages via lamb wave sparse reconstruction

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    Ultrasonic Lamb wave is a promising tool for structural health monitoring and nondestructive evaluation of plate-like structures. Using an array with several piezoelectric discs for damage imaging (i.e. visual detection and localization) is of interest. Commonly used delay-and-sum method is limited for overlapped signals when several damages are closely distributed in the structure. To overcome this limitation, modal-based sparse reconstruction imaging method is applied for adjacent damages in this study. Firstly, Lamb wave dispersion curve is obtained by solving the Rayleigh-Lamb equations. Subsequently, propagation modal of the damage-reflected signal is constructed based on the solved dispersion curve. Finally, the modal is used for damage imaging via sparse reconstruction and basis pursuit de-noising. Experimental data measured in an aluminum plate is considered, and the result demonstrates that the sparse reconstruction imaging method is effective to detect and localize closely distributed damages in the presence of signal overlapping

    Fast Lithium Ion Diffusion in Brownmillerite LixSr2Co2O5\mathrm{Li}_{x}\mathrm{{Sr}_{2}{Co}_{2}{O}_{5}}

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    Ionic conductors have great potential for interesting tunable physical properties via ionic liquid gating and novel energy storage applications such as all-solid-state lithium batteries. In particular, low migration barriers and high hopping attempt frequency are the keys to achieve fast ion diffusion in solids. Taking advantage of the oxygen-vacancy channel in LixSr2Co2O5\mathrm{Li}_{x}\mathrm{{Sr}_{2}{Co}_{2}{O}_{5}}, we show that migration barriers of lithium ion are as small as 0.28~0.17eV depending on the lithium concentration rates. Our first-principles calculation also investigated hopping attempt frequency and concluded the room temperature ionic diffusivity and ion conductivity is high as 10−7∼10−6 cm2 s−1{10}^{-7}\sim{10}^{-6}~\mathrm{{cm}^{2}~s^{-1}} and 10−3∼10−2 S⋅cm−1{10}^{-3}\sim{10}^{-2}~\mathrm{S\cdot{cm}^{-1}} respectively, which outperform most of perovskite-type, garnet-type and sulfide Li-ion solid-state electrolytes. This work proves LixSr2Co2O5\mathrm{Li}_{x}\mathrm{{Sr}_{2}{Co}_{2}{O}_{5}} as a promising solid-state electrolyte.Comment: 6 pages, 7 figure

    Visualizing temperature-dependent phase stability in high entropy alloys

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    High entropy alloys (HEAs) contain near equimolar amounts of five or more elements and are a compelling space for materials design. In the design of HEAs, great emphasis is placed on identifying thermodynamic conditions for single-phase and multi-phase stability regions, but this process is hindered by the difficulty of navigating stability relationships in high-component spaces. Traditional phase diagrams use barycentric coordinates to represent composition axes, which require (N – 1) spatial dimensions to represent an N-component system, meaning that HEA systems with N \u3e 4 components cannot be readily visualized. Here, we propose forgoing barycentric composition axes in favor of two energy axes: a formation-energy axis and a ‘reaction energy’ axis. These Inverse Hull Webs offer an information-dense 2D representation that successfully captures complex phase stability relationships in N ≥ 5 component systems. We use our proposed diagrams to visualize the transition of HEA solid-solutions from high-temperature stability to metastability upon quenching, and identify important thermodynamic features that are correlated with the persistence or decomposition of metastable HEAs

    Effect of processing conditions on the structure, electrical and mechanical properties of melt mixed high density polyethylene/multi-walled CNT composites in compression molding

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    Abstract Processing conditions can significantly influence the structure and properties of polymer nanocomposites. In the present study, melt mixed high density polyethylene (HDPE)/multi-walled carbon nanotube (MWCNT) nanocomposites were prepared via twin-screw extrusion and then compression molded (CM). The effect of heating temperature, pressing time and cooling rate on the structure, electrical and mechanical properties of the CM nanocomposites was systematically investigated. Volume resistivity tests indicate that the nanocomposite with 2 wt.-% MWCNTs, which is in the region of the electrical percolation threshold, is very sensitive to the CM parameters such that heating temperature &gt; pressing time &gt; cooling rate. Generally, the resistivity of nanocomposites decreases with increasing heating temperature and pressing time. Interestingly, the electrical resistivity of the rapidly cooled nanocomposite with 2 wt.-% MWCNTs is about 2 orders lower than that of the slowly cooled nanocomposite which is attributed to the lower crystallinity and smaller crystallites presenting less of an obstacle to the formation of conductive pathways. The tensile properties of the nanocomposite with 2 wt.-% MWCNTs are also influenced by the compression molding parameters to some extent, while those of the nanocomposites with higher MWCNT loading are insensitive to the changes in processing conditions. The modulus of the nanocomposites increases by about 25 to 50 % and 110 to 130 %, respectively, with the incorporation of 2 and 4 wt.-% MWCNTs, which agrees well with the theoretical values predicted from Halpin-Tsai and Mori-Tanaka models. This work has important implications for both process control and the tailoring of electrical and mechanical properties in the commercial manufacture of conductive HDPE/MWCNT nanocomposites.</jats:p

    Protograph-Based Raptor-Like Codes

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    Theoretical analysis has long indicated that feedback improves the error exponent but not the capacity of pointto- point memoryless channels. The analytic and empirical results indicate that at short blocklength regime, practical rate-compatible punctured convolutional (RCPC) codes achieve low latency with the use of noiseless feedback. In 3GPP, standard rate-compatible turbo codes (RCPT) did not outperform the convolutional codes in the short blocklength regime. The reason is the convolutional codes for low number of states can be decoded optimally using Viterbi decoder. Despite excellent performance of convolutional codes at very short blocklengths, the strength of convolutional codes does not scale with the blocklength for a fixed number of states in its trellis

    Proteomic analyses reveal distinct chromatin-associated and soluble transcription factor complexes.

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    The current knowledge on how transcription factors (TFs), the ultimate targets and executors of cellular signalling pathways, are regulated by protein-protein interactions remains limited. Here, we performed proteomics analyses of soluble and chromatin-associated complexes of 56 TFs, including the targets of many signalling pathways involved in development and cancer, and 37 members of the Forkhead box (FOX) TF family. Using tandem affinity purification followed by mass spectrometry (TAP/MS), we performed 214 purifications and identified 2,156 high-confident protein-protein interactions. We found that most TFs form very distinct protein complexes on and off chromatin. Using this data set, we categorized the transcription-related or unrelated regulators for general or specific TFs. Our study offers a valuable resource of protein-protein interaction networks for a large number of TFs and underscores the general principle that TFs form distinct location-specific protein complexes that are associated with the different regulation and diverse functions of these TFs

    A Phase Change Memory Chip Based on TiSbTe Alloy in 40-nm Standard CMOS Technology

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    In this letter, a phase change random access memory (PCRAM) chip based on Ti0.4Sb2Te3 alloy material was fabricated in a 40-nm 4-metal level complementary metal-oxide semiconductor (CMOS) technology. The phase change resistor was then integrated after CMOS logic fabrication. The PCRAM was successfully embedded without changing any logic device and process, in which 1.1 V negative-channel metal-oxide semiconductor device was used as the memory cell selector. The currents and the time of SET and RESET operations were found to be 0.2 and 0.5 mA, 100 and 10 ns, respectively. The high speed performance of this chip may highlight the design advantages in many embedded applications
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