Nankai Trough, Japan Trench and Kuril Trench: geochemistry of fluids sampled by submersible <i>Nautile</i>

Deep-water samples collected during the Kaiko project are often associated with biological communities located on geological structures favorable to fluid venting. The evidence of fluid venting are the temperature anomalies, the decrease in sulfate concentrations, the content in methane and the lowC1(C2 +C3) ratio of light hydrocarbons. Because of large dilution by ambiant seawater during sampling it is difficult to compute the composition of the advected end-member pore fluid. Part of this fluid should originate in the “petroleum window”, i.e. at temperature about 60°C. Modeling the upward flow of water, taking into account the anomalies of temperature measured on the seafloor and the geochemical anomalies, leads to non-steady-state advection of the pore fluid. The occurrence of a deep component in the fluid has implications for the geological and tectonic models of the subduction zones off Japan

Non-transform offsets along the Mid-Atlantic Ridge south of the Azores (38N-34N): ultramafic exposures and hosting of hydrothermal vents

Ten contiguous non-transform offsets (NTOs) along the Mid-Atlantic Ridge (MAR) south of the Azores (between 38°N and 35°40?N) have been studied in detail using swath bathymetric, acoustic backscatter and deep-tow high-resolution sidescan sonar (TOBI) data. In contrast with discontinuities studied elsewhere at slow-spreading ridges, these left-lateral NTOs are consistently broader and larger, with complex structural fabrics accommodating the offset. They are characterized by a range of elevated and faulted massifs detached from their segment flanks, with an irregular acoustic backscatter pattern. Some of these massifs have been explored and sampled recently during dive cruises revealing that they are composed of upper mantle peridotites and lower crustal rocks, and sometimes associated with high-temperature hydrothermal venting. Water column surveys adjacent to these massifs show high CH4 and low TDM (total dissolvable manganese) concentrations, possibly resulting from the process of serpentinization of ultramafic rocks. The correlation between the shallow dome-like shaped massifs and the high concentrations of CH4 (associated with low levels of Mn) is of particular interest to predict the outcrop of ultramafic rocks within the NTOs where no geological data are available. The exposure of the ultramafic massifs within the NTOs is favored by low magmatic supply and low-angle detachment faulting occurring at segment ends. The pervasive fracturing and faulting at these discontinuities favor circulation of hydrothermal fluids and occurrence of high-temperature vent sites

New insight into the contributions of thermogenic processes and biogenic sources to the generation of organic compounds in hydrothermal fluids

International audienc

Helium isotopic composition of hydrothermal fluids from the Manus back-arc Basin, Papua New Guinea

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Geochemistry of high H2 and CH4 vent fluids issuing from ultramafic rocks at the Rainbow hydrothermal field (36°14′N, MAR)

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Deepwater mantle 3 He plumes over the northern Mid-Atlantic Ridge (36°N-40°N) and the Azores Platform

International audienceAs part of a multidisciplinary project aimed at studying mid-ocean ridge processes near the Azores, fifty water column profiles were analyzed for 3 He/ 4 He ratios in dissolved helium (a well-known hydrothermal tracer) from 36°N to 40°N along the Mid-Atlantic Ridge (MAR) and over the Azores Plateau. As expected, large d 3 He anomalies could be observed over the Rainbow, Lucky Strike, and Menez Gwen hydrothermal sites. The main finding of the present study is the discovery of a large hydrothermal 3 He plume north of the Açor Fracture Zone (north AFZ site), with a CH 4 / 3 He ratio indicative of a basaltichosted hydrothermal system. Clear 3 He and CH 4 anomalies, likely corresponding to unknown venting sites too, were also detected in the Amar Minor segment and south of the Kurchatov Fracture Zone. Evidence for substantial mantle helium degassing was also observed in the deep nodal basins along the Terceira Rift. On the basis of 3 He plumes over the total length of the surveyed segments, the distribution of hydrothermal sites corresponds to a site frequency of 1.3 ± 0.2 site/100 km, in good agreement with the global vent field statistics of Baker and German (2004). For the Rainbow, Lucky Strike, and Menez Gwen sites, the application of a plume model based on the conservation of mass, heat, and momentum shows that the heat output computed by the model is only an estimation of the heat released by the focused part of the flow imputable to one single vent. Applied to the north AFZ venting site for which the height of the plume is not known precisely, the model does not allow us to discriminate between a Menez Gwen/Rainbow type of venting or a more focused vent complex such as the one observed at the TAG site (26°N)

Hydrocarbons and oxidized organic compounds in hydrothermal fluids from Rainbow and Lost City ultramafic-hosted vents

The first building blocks of life could be produced in ultramafic-hosted hydrothermal systems considering the large amounts of hydrogen and methane generated by serpentinisation and Fischer–Tropsch-Type synthesis, respectively, in those systems. The purpose of this study was to detect and characterise organic molecules in hydrothermal fluids from ultramafic-hosted hydrothermal systems in the Mid-Atlantic Ridge (MAR) region. During the EXOMAR cruise 2005, fluids from the Rainbow (36°14′N) and the Lost City (30°N) hydrothermal fields were collected and treated by Stir Bar Sorptive Extraction (SBSE) and Solid Phase Extraction (SPE). The extracts were analysed by Thermal Desorption–Gas Chromatography–Mass Spectrometry (TD–GC–MS) and GC–MS, respectively. Compared to nearby deep seawater, hydrothermal fluids were clearly enriched in organic compounds, with a more diverse spectrum of molecules. We observed a very similar range of organic compounds in fluids from both sites, with a dominance of aliphatic hydrocarbons (C9–C14), aromatic compounds (C6–C16) and carboxylic acids (C8–C18). The occurrence of these compounds is supported by other field studies on serpentinites and sulfide deposits. Literature on thermodynamic data and experimental work has suggested the possible abiogenic origin of hydrocarbons and organic acids. In addition, it has been shown elsewhere that catalytic reactions producing hydrocarbons likely occur at both Lost City and Rainbow hydrothermal fields as suggested by the evolution of δ13C with increasing C number for methane, ethane, propane and butane. In order to investigate the origin of the organic molecules in the fluids, compound-specific carbon isotope ratio measurements were performed on n-alkanes and carboxylic acids, for which the δ13C values were in the range of − 46 to − 20‰ (vs. V-PDB). These preliminary data did not allow conclusive support or rejection of an abiogenic origin of the compounds. Indeed, predicting δ13C signatures in hydrothermal systems is likely to be complicated, due to differences in source δ13C signatures (i.e., of the C building blocks), and a variety of, mostly unknown, fractionation steps which may occur along the synthesis pathways. In addition, even though a fraction of the compounds detected in the fluids is likely abiotically produced, a dominance of biogenic sources and/or processes might hide their characteristic signature.