Un modèle débit-durée-fréquence pour caractériser le régime d'étiage d'un bassin versant

La méthodologie débit-durée-fréquence (QdF), appliquée ces dernières années aux étiages, a permis de définir quatre modèles types recouvrant l'ensemble des rivières étudiées. L'identification de la typologie du site étudié et l'estimation de deux descripteurs hydrologiques locaux suffisent au modèle, dit de référence, pour en déduire les courbes QdF (1j ≤ d ≤ 30j) en débit moyen minimum sur l'année (VCNd) ou débit seuil minimum annuel (QCNd) non dépassé sur ces mêmes durées. S'il est relativement aisé de définir les descripteurs hydrologiques, il est plus difficile d'identifier, sans observation de débit, le modèle à prendre en compte. En reconsidérant avec plus de rationalité la démarche d'identification des typologies, et en particulier les distributions multidurées relatives à chaque bassin, il est apparu possible d'évoluer vers un modèle unique pouvant être calé en chaque site observé. Ce nouveau concept de modélisation repose sur la propriété d'affinité des distributions, relatives aux échantillons de valeurs de durées d. Par souci de continuité avec l'approche QdF à référence typologique, la loi statistique log-normale à deux paramètres a été choisie. Le modèle, dont la conceptualisation est indépendante de la loi statistique choisie, aura dans le cas de la loi log-normale trois paramètres à ajuster sur les VCNd échantillonnés. Trente six sous bassins du bassin hydrographique de la Moselle ont été étudiés. Le modèle développé pour les débit moyens VCNd peut être appliqué aux débits seuils QCNd en conservant le même jeu de paramètres, grâce à une relation observée entre débits moyens et débits seuils. Cette nouvelle modélisation rationalise l'approche antérieure basée sur la typologie d'écoulement de basses eaux des bassins versants.The flow-duration-frequency (QdF) concept, as applied in recent years to low flows, has made it possible to establish four reference models (GALEA et al., 1999a), corresponding to four typologies. The hydrological variables concerned are the minimum mean discharge of the year defined for various continuous durations d (1day ≤ d ≤ 30day), called VCNd, and the annual minimum threshold discharge not exceeded over these same durations, called QCNd, according to OBERLIN (1992). These QdF models allow a description of the temporal variability of low flows observed for a river basin, from a statistical point of view. The typology of the basin and two local hydrological descriptors have to be known. For ungauged basins, these two descriptors (GALEA et al., 1999b) are well estimated by various methods, such as multivariate analysis relating to the physiographic characteristics of the basin. Nevertheless, the choice of the reference model still remains contentious.By reconsidering in a more rational manner the step of identification of typologies, and in particular the discharge distributions (for durations d) relating to each basin, it appeared interesting to establish a local model. This new model has a simpler formulation, thanks to a scale invariance assumption. This research (CHAPUT, 1999) was undertaken on 36 sub-basins of the Mosel basin. In order to ensure continuity with the earlier QdF models described above, the two-parameter log-normal law was chosen and adjusted on the distribution of mean discharges. The scale invariance assumption is deduced from the observed parallelism of distributions related to different durations, when discharges are represented in a logarithm scale. This observation means that all of the distributions can be translated to a common point, in order to obtain one "consolidated" distribution, independent on the considered duration. This parallelism has been observed on many basins, and seems to be a realistic assumption. Furthermore, these observations have been made on samples, and do not depend on the choice of statistical law. The methodology described in this paper makes it possible to adjust the local QdF model on sampled discharges. Only three parameters have to be determined: sc, the "consolidated" standard deviation, ∆e the low flow characteristic duration and VCN(2,1), which represents the quantile of the one-day distribution, with the two-year return period (F=0.5).This model is also useful for the determination of threshold discharges (QCNd). An observed property gives a relation between the VCN and QCN quantiles, for a fixed return period, considering different durations d: VCN quantiles can been deduced from QCN quantiles by integrating them, according to d. Consequently, the analytical formulation of the VCN model can be derived according to d, in order to obtain a QCN model. This model has the same three parameters sc, ∆e and VCN(2,1) described above. The comparison between QCN quantiles adjusted on samples and QCN quantiles deduced from the VCN model by derivation shows good results.As a conclusion, this new modelling approach unifies the typological approach for both mean discharges and threshold discharges. It is based on a local adjustment and avoids having to choose between one of the four former reference models. This local model opens up perspectives for a regional model, as it has been done for floods, for example by the Group of Research in Statistical Hydrology (1996). This will make it possible to estimate the low flow regime on an ungauged basin

A Photochemical Organocatalytic Strategy for the α-Alkylation of Ketones by using Radicals

Reported herein is a visible-light-mediated radical approach to the α-alkylation of ketones. This method exploits the ability of a nucleophilic organocatalyst to generate radicals upon SN2-based activation of alkyl halides and blue light irradiation. The resulting open-shell intermediates are then intercepted by weakly nucleophilic silyl enol ethers, which would be unable to directly attack the alkyl halides through a traditional two-electron path. The mild reaction conditions allowed functionalization of the α position of ketones with functional groups that are not compatible with classical anionic strategies. In addition, the redox-neutral nature of this process makes it compatible with a cinchona-based primary amine catalyst, which was used to develop a rare example of enantioselective organocatalytic radical α-alkylation of ketones

Seasonal and spatial variations in the ocean-coupled ambient wavefield of the Ross Ice Shelf

© The Author(s), 2019. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Baker, M. G., Aster, R. C., Anthony, R. E., Chaput, J., Wiens, D. A., Nyblade, A., Bromirski, P. D., Gerstoft, P., & Stephen, R. A. Seasonal and spatial variations in the ocean-coupled ambient wavefield of the Ross Ice Shelf. Journal of Glaciology, 65(254), (2019): 912-925, doi:10.1017/jog.2019.64.The Ross Ice Shelf (RIS) is host to a broadband, multimode seismic wavefield that is excited in response to atmospheric, oceanic and solid Earth source processes. A 34-station broadband seismographic network installed on the RIS from late 2014 through early 2017 produced continuous vibrational observations of Earth's largest ice shelf at both floating and grounded locations. We characterize temporal and spatial variations in broadband ambient wavefield power, with a focus on period bands associated with primary (10–20 s) and secondary (5–10 s) microseism signals, and an oceanic source process near the ice front (0.4–4.0 s). Horizontal component signals on floating stations overwhelmingly reflect oceanic excitations year-round due to near-complete isolation from solid Earth shear waves. The spectrum at all periods is shown to be strongly modulated by the concentration of sea ice near the ice shelf front. Contiguous and extensive sea ice damps ocean wave coupling sufficiently so that wintertime background levels can approach or surpass those of land-sited stations in Antarctica.This research was supported by NSF grants PLR-1142518, 1141916, 1142126, 1246151 and 1246416. JC was additionally supported by Yates funds in the Colorado State University Department of Mathematics. PDB also received support from the California Department of Parks and Recreation, Division of Boating and Waterways under contract 11-106-107. We thank Reinhard Flick and Patrick Shore for their support during field work, Tom Bolmer in locating stations and preparing maps, and the US Antarctic Program for logistical support. The seismic instruments were provided by the Incorporated Research Institutions for Seismology (IRIS) through the PASSCAL Instrument Center at New Mexico Tech. Data collected are available through the IRIS Data Management Center under RIS and DRIS network code XH. The PSD-PDFs presented in this study were processed with the IRIS Noise Tool Kit (Bahavar and others, 2013). The facilities of the IRIS Consortium are supported by the National Science Foundation under Cooperative Agreement EAR-1261681 and the DOE National Nuclear Security Administration. The authors appreciate the support of the University of Wisconsin-Madison Automatic Weather Station Program for the data set, data display and information; funded under NSF grant number ANT-1543305. The Ross Ice Shelf profiles were generated using the Antarctic Mapping Tools (Greene and others, 2017). Regional maps were generated with the Generic Mapping Tools (Wessel and Smith, 1998). Topography and bathymetry data for all maps in this study were sourced from the National Geophysical Data Center ETOPO1 Global Relief Model (doi:10.7289/V5C8276M). We thank two anonymous reviewers for suggestions on the scope and organization of this paper

On the temporal stability of the coda of ambient noise correlations

We analyze the sensitivity of cross correlations to the anisotropy of the incident field in the context of seismic ambient noise monitoring of small velocity changes. Numerical simulations of elastic waves are performed in a 2D scattering plate with a focus on the comparative character of the direct and coda waves in the cross-correlation. We show that coda waves reconstructed from cross-correlations are far more robust than direct waves in the presence of azimuthal anisotropy of the incident field. We observe similar behavior with real data recorded on Erebus volcano, where a database of impulsive icequakes is used to simulate an anisotropic source field. We propose a simplified approach to evaluate the sensitivity of scattered waves to the anisotropy of the incoming noise field. We rely on previous results obtained for direct waves and on intrinsic properties of scattered waves to predict the errors produced by strong source anisotropy with numerical experiments. These results also yield realistic values for monitoring the accuracy to be expected with real data at crustal scales. Our analysis shows that high-precision noise-based monitoring could be performed with coda waves in the correlation functions, even in the presence of variations in the azimuthal distribution of the ambient noise field

Non-monotonic field-dependence of the ZFC magnetization peak in some systems of magnetic nanoparticles

We have performed magnetic measurements on a diluted system of gamma-Fe2O3 nanoparticles (~7nm), and on a ferritin sample. In both cases, the ZFC-peak presents a non-monotonic field dependence, as has already been reported in some experiments,and discussed as a possible evidence of resonant tunneling. Within simple assumptions, we derive expressions for the magnetization obtained in the usual ZFC, FC, TRM procedures. We point out that the ZFC-peak position is extremely sensitive to the width of the particle size distribution, and give some numerical estimates of this effect. We propose to combine the FC magnetization with a modified TRM measurement, a procedure which allows a more direct access to the barrier distribution in a field. The typical barrier values which are obtained with this method show a monotonic decrease for increasing fields, as expected from the simple effect of anisotropy barrier lowering, in contrast with the ZFC results. From our measurements on gamma-Fe2O3 particles, we show that the width of the effective barrier distribution is slightly increasing with the field, an effect which is sufficient for causing the observed initial increase of the ZFC-peak temperatures.Comment: LaTeX file 19 pages, 9 postscript figures. To appear in Phys. Rev. B (tentative schedule: Dec.97

Lorenz function of Bi2_{2}Te3_{3}/Sb2_{2}Te3_{3} superlattices

Combining first principles density functional theory and semi-classical Boltzmann transport, the anisotropic Lorenz function was studied for thermoelectric Bi$_{2}$Te$_{3}$/Sb$_{2}$Te$_{3}$ superlattices and their bulk constituents. It was found that already for the bulk materials Bi$_{2}$Te$_{3}$ and Sb$_{2}$Te$_{3}$, the Lorenz function is not a pellucid function on charge carrier concentration and temperature. For electron-doped Bi$_{2}$Te$_{3}$/Sb$_{2}$Te$_{3}$ superlattices large oscillatory deviations for the Lorenz function from the metallic limit were found even at high charge carrier concentrations. The latter can be referred to quantum well effects, which occur at distinct superlattice periods

Droit de la construction : de la jurisprudence à la pratique notariale

"Parce que le contentieux de la construction concerne les notaires à bien des égards, cette nouvelle chronique, rédigée par des universitaires et des praticiens, a pour objectif premier de brosser un panorama des décisions importantes rendues au cours de l\u27année 2012 en la matière. Les signataires de ces lignes ont ensuite cherché, dans le cadre de cette collaboration entre chercheurs et notaires, à enrichir leurs commentaires de conseils pratiques. Ainsi, au cours de l\u27année écoulée, la Cour de cassation s\u27est prononcée sur des questions générales d\u27organisation de l\u27immeuble, précisant la liberté de choix entre le statut de la copropriété et la division en volumes ou revenant sur les règles applicables aux travaux réalisés sur un mur mitoyen. Des précisions ont également été apportées sur le champ d\u27application de la responsabilité décennale des constructeurs, puisqu\u27il a été rappelé que le vendeur même non professionnel d\u27un immeuble rénové peut, à certaines conditions, engager sa responsabilité décennale, de même que cette cause de responsabilité est également susceptible de s\u27appliquer lorsque les dommages affectant un immeuble neuf causent des préjudices à des tiers ou se matérialisent par un simple risque d\u27écroulement, sans que la catastrophe ne soit encore survenue. Un arrêt important précise en outre, dans le domaine des assurances, la distinction entre la faute lourde, couverte, et celle intentionnelle, dont l\u27assureur ne répondra pas. On relèvera finalement trois décisions importantes en matière de vente d\u27immeubles à construire. Deux concernent la rédaction des actes, quant à la distinction entre les notions d\u27achèvement et de livraison d\u27une part, puis relativement aux clauses d\u27allongement de délai de livraison pour intempéries, d\u27autre part. Le dernier revient sur la question importante la rénovation en précisant l\u27étendue de la responsabilité du notaire dans le choix entre le modèle de la vente en l\u27état futur d\u27achèvement et celui de la vente d\u27immeuble à rénover." Gwenaëlle Durand-Pasquie

Small Angle Scattering by Fractal Aggregates: A Numerical Investigation of the Crossover Between the Fractal Regime and the Porod Regime

Fractal aggregates are built on a computer using off-lattice cluster-cluster aggregation models. The aggregates are made of spherical particles of different sizes distributed according to a Gaussian-like distribution characterised by a mean $a_0$ and a standard deviation $\sigma$. The wave vector dependent scattered intensity $I(q)$ is computed in order to study the influence of the particle polydispersity on the crossover between the fractal regime and the Porod regime. It is shown that, given $a_0$, the location $q_c$ of the crossover decreases as $\sigma$ increases. The dependence of $q_c$ on $\sigma$ can be understood from the evolution of the shape of the center-to-center interparticle-distance distribution function.Comment: RevTex, 4 pages + 6 postscript figures, compressed using "uufiles", published in Phys. Rev. B 50, 1305 (1994

Energy Spectra, Altitude Profiles and Charge Ratios of Atmospheric Muons

We present a new measurement of air shower muons made during atmospheric ascent of the High Energy Antimatter Telescope balloon experiment. The muon charge ratio mu+ / mu- is presented as a function of atmospheric depth in the momentum interval 0.3-0.9 GeV/c. The differential mu- momentum spectra are presented between 0.3 and about 50 GeV/c at atmospheric depths between 13 and 960 g/cm^2. We compare our measurements with other recent data and with Monte Carlo calculations of the same type as those used in predicting atmospheric neutrino fluxes. We find that our measured mu- fluxes are smaller than the predictions by as much as 70% at shallow atmospheric depths, by about 20% at the depth of shower maximum, and are in good agreement with the predictions at greater depths. We explore the consequences of this on the question of atmospheric neutrino production.Comment: 11 pages, 8 figures, to appear in Phys. Rev. D (2000

The Energy Spectra and Relative Abundances of Electrons and Positrons in the Galactic Cosmic Radiation

Observations of cosmic-ray electrons and positrons have been made with a new balloon-borne detector, HEAT (the "High-Energy Antimatter Telescope"), first flown in 1994 May from Fort Sumner, NM. We describe the instrumental approach and the data analysis procedures, and we present results from this flight. The measurement has provided a new determination of the individual energy spectra of electrons and positrons from 5 GeV to about 50 GeV, and of the combined "all-electron" intensity (e+ + e-) up to about 100 GeV. The single power-law spectral indices for electrons and positrons are alpha = 3.09 +/- 0.08 and 3.3 +/- 0.2, respectively. We find that a contribution from primary sources to the positron intensity in this energy region, if it exists, must be quite small.Comment: latex2e file, 30 pages, 15 figures, aas2pp4.sty and epsf.tex needed. To appear in May 10, 1998 issue of Ap.