536 research outputs found
Discovery of new Al-Cu-Fe minerals in the Khatyrka CV3 meteorite
Introduction: During a nanomineralogy investigation of the Khatyrka CV3 carbonaceous chondrite, we have identified two new alloy minerals (AlCu with a Pm-3m CsCl structure and Al_3Fe with a C2/m structure) and associated icosahedrite (quasicrystal Al_(63)Cu_(26)Fe_(11) with a five-fold symmetry) at micron scales in section 126A of USNM 7908. The section belongs to the larger Grain 126, which is one of the fragments recovered from an expedition to the Koryak Mountains in far eastern Russia in 2011 [1] as a result of a search for samples that would provide information on the origin of the quasicrystal mineral icosahedrite [2,3,4]. The recovered fragments have meteoritic (CV3-like) oxygen isotopic compositions and are identified collectively as coming from the Khatyrka meteorite [5], which formed 4.5 billion years ago during the earliest stages of the solar system. Khatyrka is unique, so far being the only meteorite to host metallic Al component
Collisions in outer space produced an icosahedral phase in the Khatyrka meteorite never observed previously in the laboratory
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Evidence of cross-cutting and redox reaction in Khatyrka meteorite reveals metallic-Al minerals formed in outer space
We report on a fragment of the quasicrystal-bearing CV3 carbonaceous chondrite Khatyrka recovered from fine-grained, clay-rich sediments in the Koryak Mountains, Chukotka (Russia). We show higher melting-point silicate glass cross-cutting lower melting-point Al-Cu-Fe alloys, as well as unambiguous evidence of a reduction-oxidation reaction history between Al-Cu-Fe alloys and silicate melt. The redox reactions involve reduction of FeO and SiO_2 to Fe and Fe-Si metal, and oxidation of metallic Al to Al_2O_3, occurring where silicate melt was in contact with Al-Cu-Fe alloys. In the reaction zone, there are metallic Fe and Fe-Si beads, aluminous spinel rinds on the Al-Cu-Fe alloys, and Al_2O_3 enrichment in the silicate melt surrounding the alloys. From this and other evidence, we demonstrate that Khatyrka must have experienced at least two distinct events: first, an event as early as 4.564 Ga in which the first Al-Cu-Fe alloys formed; and, second, a more recent impact-induced shock in space that led to transformations of and reactions between the alloys and the meteorite matrix. The new evidence firmly establishes that the Al-Cu-Fe alloys (including quasicrystals) formed in outer space in a complex, multi-stage process
Collisions in outer space produced an icosahedral phase in the Khatyrka meteorite never observed previously in the laboratory
We report the first occurrence of an icosahedral quasicrystal with composition Al_(62.0(8))Cu_(31.2(8))Fe_(6.8(4)), outside the measured equilibrium stability field at standard pressure of the previously reported Al-Cu-Fe quasicrystal (Al_xCu_yFe_z, with x between 61 and 64, y between 24 and 26, z between 12 and 13%). The new icosahedral mineral formed naturally and was discovered in the Khatyrka meteorite, a recently described CV3 carbonaceous chondrite that experienced shock metamorphism, local melting (with conditions exceeding 5 GPa and 1,200 °C in some locations), and rapid cooling, all of which likely resulted from impact-induced shock in space. This is the first example of a quasicrystal composition discovered in nature prior to being synthesized in the laboratory. The new composition was found in a grain that has a separate metal assemblage containing icosahedrite (Al_(63)Cu_(24)Fe_(13)), currently the only other known naturally occurring mineral with icosahedral symmetry (though the latter composition had already been observed in the laboratory prior to its discovery in nature). The chemistry of both the icosahedral phases was characterized by electron microprobe, and the rotational symmetry was confirmed by means of electron backscatter diffraction
Trajectory of Substance Use Disorders and Collegiate Recovery in Emerging Adults
Abstract
Collegiate Recovery Programs (CRPs) provide services to support emerging adults achieve academic success, while maintaining substance use disorder recovery. College and university campuses can often be considered abstinence-hostile environments, giving rise to the need of support services for students in recovery. A nationwide survey to understand the efficacy of services provided by CRPs was conducted to assess the demographics and academic profiles of students involved with CRPs. Co-occurring disorders including mental health issues, criminal histories, utilizations of recovery services and 12-step groups, and work histories of students were also assessed. CRPs can provide services and an environment to students that increase recovery capital domains. Recovery capital domains such as spirituality, health and wellness, academics, critical thinking and discernment, personal achievement, and service opportunities may be related to metrics of academic success such as grade point average. However, measuring success for those in substance use disorder recovery through academics metrics alone could present a barrier to improving recovery services. Assessing the effectiveness of CRP programs through the lens of recovery capital offers a strengths-based, wholistic approach to improving services for students in recovery. Future directions include administering comprehensive measurements for recovery success, in addition to academic metrics, for students that are members of CRP.
Keywords: Substance Use Recovery; Emerging Adults; Collegiate Recovery Program
Observation of oscillatory relaxation in the Sn-terminated surface of epitaxial rock-salt SnSe topological crystalline insulator
Topological crystalline insulators have been recently predicted and observed
in rock-salt structure SnSe thin films. Previous studies have
suggested that the Se-terminated surface of this thin film with hydrogen
passivation, has a reduced surface energy and is thus a preferred
configuration. In this paper, synchrotron-based angle-resolved photoemission
spectroscopy, along with density functional theory calculations, are used to
demonstrate conclusively that a rock-salt SnSe thin film
epitaxially-grown on \ce{Bi2Se3} has a stable Sn-terminated surface. These
observations are supported by low energy electron diffraction (LEED)
intensity-voltage measurements and dynamical LEED calculations, which further
show that the Sn-terminated SnSe thin film has undergone a surface
structural relaxation of the interlayer spacing between the Sn and Se atomic
planes. In sharp contrast to the Se-terminated counterpart, the observed Dirac
surface state in the Sn-terminated SnSe thin film is shown to yield a
high Fermi velocity, m/s, which suggests a potential mechanism
of engineering the Dirac surface state of topological materials by tuning the
surface configuration.Comment: 12 pages, 13 figures, supplementary materials include
Shock synthesis of quasicrystals with implications for their origin in asteroid collisions
We designed a plate impact shock recovery experiment to simulate the starting materials and shock conditions associated with the only known natural quasicrystals, in the Khatyrka meteorite. At the boundaries among CuAl_5, (Mg_(0.75)Fe^(2+)_(0.25))_2SiO_4 olivine, and the stainless steel chamber walls, the recovered specimen contains numerous micron-scale grains of a quasicrystalline phase displaying face-centered icosahedral symmetry and low phason strain. The compositional range of the icosahedral phase is Al_(68–73)Fe_(11–16)Cu_(10–12)Cr_(1–4)Ni_(1–2) and extends toward higher Al/(Cu+Fe) and Fe/Cu ratios than those reported for natural icosahedrite or for any previously known synthetic quasicrystal in the Al-Cu-Fe system. The shock-induced synthesis demonstrated in this experiment reinforces the evidence that natural quasicrystals formed during a shock event but leaves open the question of whether this synthesis pathway is attributable to the expanded thermodynamic stability range of the quasicrystalline phase at high pressure, to a favorable kinetic pathway that exists under shock conditions, or to both thermodynamic and kinetic factors
A Monte Carlo based phase space model for quality assurance of intensity modulated radiotherapy incorporating leaf specific characteristics
Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/134797/1/mp3409.pd
Root exudates of the hyperaccumulator Thlaspi caerulescens do not enhance metal mobilization
To examine whether root exudates of the Zn/Cd hyperaccumulator Thlaspi caerulescens play a role in metal hyperaccumulation, we compared the metal mobilization capacity of root exudates collected from two ecotypes of T. caerulescens, and from the nonaccumulators wheat (Triticum aestivum) and canola (Brassica napus). Plants were grown hydroponically and three treatments (control, -Fe and -Zn) were later imposed for 2 wk before collection of root exudates. On a basis of root d. wt, the total soluble organic C in the root exudates of T. caerulescens was similar to that of wheat, and significantly higher than that of canola. In all treatment, the root exudates of T. caerulescens and canola mobilized little Cu and Zn from Cu- or Zn-loaded resins, and little Zn, Cd, Cu or Fe from a contaminated calcareous soil. By contrast, the root exudates of wheat generally mobilized more metals from both resin and soil. In particular, the -Fe treatment, and to a lesser extent the -Zn treatment, elicited large increases in the metal mobilization capacity of the root exudates from wheat. We conclude that root exudates from T. caerulescens do not significantly enhance mobilization of Zn and Cd, and therefore are not involved in Zn and Cd hyperaccumulation. (C) New Phytologist (2001)
Immediate breast reconstruction with a saline implant and AlloDerm, following removal of a Phyllodes tumor
<p>Abstract</p> <p>Background</p> <p>Phyllodes tumors are uncommon tumors of the breast that exhibit aggressive growth. While surgical management of the tumor has been reported, a single surgical approach with immediate breast reconstruction using AlloDerm has not been reported.</p> <p>Case presentation</p> <p>A 22-year-old woman presented with a 4 cm mass in the left breast upon initial examination. Although the initial needle biopsy report indicated a fibroadenoma, the final pathologic report revealed a 6.5 cm × 6.4 cm × 6.4 cm benign phyllodes tumor <it>ex vivo</it>. Treatment was a simple nipple-sparing mastectomy coupled with immediate breast reconstruction. After the mastectomy, a subpectoral pocket was created for a saline implant and AlloDerm was stitched to the pectoralis and serratus muscle in the lower-pole of the breast.</p> <p>Conclusions</p> <p>Saline implant with AlloDerm can be used for immediate breast reconstruction post-mastectomy for treatment of a phyllodes tumor.</p
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