The Kibble-Zurek Problem: Universality and the Scaling Limit

Near a critical point, the equilibrium relaxation time of a system diverges and any change of control/thermodynamic parameters leads to non-equilibrium behavior. The Kibble-Zurek problem is to determine the dynamical evolution of the system parametrically close to its critical point when the change is parametrically slow. The non-equilibrium behavior in this limit is controlled entirely by the critical point and the details of the trajectory of the system in parameter space (the protocol) close to the critical point. Together, they define a universality class consisting of critical exponents-discussed in the seminal work by Kibble and Zurek-and scaling functions for physical quantities, which have not been discussed hitherto. In this article, we give an extended and pedagogical discussion of the universal content in the Kibble-Zurek problem. We formally define a scaling limit for physical quantities near classical and quantum transitions for different sets of protocols. We report computations of a few scaling functions in model Gaussian and large-N problems and prove their universality with respect to protocol choice. We also introduce a new protocol in which the critical point is approached asymptotically at late times with the system marginally out of equilibrium, wherein logarithmic violations to scaling and anomalous dimensions occur even in the simple Gaussian problem.Comment: 19 pages,10 figure

Oxidation of Glycine by Alkaline Hexacyanoferrate(III) - A Curious Dependence on Initial Concentration of the Oxidant

1112-111

Boxicity of graphs on surfaces

The boxicity of a graph $G=(V,E)$ is the least integer $k$ for which there exist $k$ interval graphs $G_i=(V,E_i)$, $1 \le i \le k$, such that $E=E_1 \cap ... \cap E_k$. Scheinerman proved in 1984 that outerplanar graphs have boxicity at most two and Thomassen proved in 1986 that planar graphs have boxicity at most three. In this note we prove that the boxicity of toroidal graphs is at most 7, and that the boxicity of graphs embeddable in a surface $\Sigma$ of genus $g$ is at most $5g+3$. This result yields improved bounds on the dimension of the adjacency poset of graphs on surfaces.Comment: 9 pages, 2 figure

Landowner Characteristics Associated with Receiving Information About Invasive Plants and Implications for Outreach Providers

Based on a survey of woodland owners in West Virginia, we examined the possibility of differences in the characteristics of those who had and had not received information about local invasive plants and implications for outreach providers. Findings suggest that landowners who farmed on their property, held recreation objectives, and lived in the local area were significantly more likely than their counterparts to have received information. A majority of landowners with these characteristics, however, had not heard or read such information. Implications for expanding awareness through both traditional and non-traditional information channels are presented

Passively Administered Pooled Human Immunoglobulins Exert IL-10 Dependent Anti-Inflammatory Effects that Protect against Fatal HSV Encephalitis

HSV-1 is the leading cause of sporadic encephalitis in humans. HSV infection of susceptible 129S6 mice results in fatal encephalitis (HSE) caused by massive inflammatory brainstem lesions comprising monocytes and neutrophils. During infection with pathogenic microorganisms or autoimmune disease, IgGs induce proinflammatory responses and recruit innate effector cells. In contrast, high dose intravenous immunoglobulins (IVIG) are an effective treatment for various autoimmune and inflammatory diseases because of potent anti-inflammatory effects stemming in part from sialylated IgGs (sIgG) present at 1–3% in IVIG. We investigated the ability of IVIG to prevent fatal HSE when given 24 h post infection. We discovered a novel anti-inflammatory pathway mediated by low-dose IVIG that protected 129S6 mice from fatal HSE by modulating CNS inflammation independently of HSV specific antibodies or sIgG. IVIG suppressed CNS infiltration by pathogenic CD11b+ Ly6Chigh monocytes and inhibited their spontaneous degranulation in vitro. FcγRIIb expression was required for IVIG mediated suppression of CNS infiltration by CD45+ Ly6Clow monocytes but not for inhibiting development of Ly6Chigh monocytes. IVIG increased accumulation of T cells in the CNS, and the non-sIgG fraction induced a dramatic expansion of FoxP3+ CD4+ T regulatory cells (Tregs) and FoxP3− ICOS+ CD4+ T cells in peripheral lymphoid organs. Tregs purified from HSV infected IVIG treated, but not control, mice protected adoptively transferred mice from fatal HSE. IL-10, produced by the ICOS+ CD4+ T cells that accumulated in the CNS of IVIG treated, but not control mice, was essential for induction of protective anti-inflammatory responses. Our results significantly enhance understanding of IVIG's anti-inflammatory and immunomodulatory capabilities by revealing a novel sIgG independent anti-inflammatory pathway responsible for induction of regulatory T cells that secrete the immunosuppressive cytokine IL-10 and further reveal the therapeutic potential of IVIG for treating viral induced inflammatory diseases

Electrooxidation of nitrite ions on gold/polyaniline/carbon paste electrode

Nitrite ions can penetrate from fertilizers into underground water and consequently contaminate the water and food sources. A facile two-step electrochemical method was used to fabricate gold/polyaniline/carbon paste electrode (Au/PAni/CPE) for nitrite sensing. The Au/PAni/CPE was visualized and characterized by scanning electron microscopy, energy-dispersed X-ray spectroscopy, X-ray diffraction and electrochemical methods. The electrocatalytic activity of bare CPE, PAni/CPE and Au/PAni/CPE toward the electrooxidation of nitrite was examined and compared via cyclic voltammetry. To obtain the optimal condition for fabrication of the electrode, the number of cycles in cyclic voltammetry for synthesis of polyaniline and the deposition time in potentiostatic deposition of gold were optimized with respect to the electrooxidation of nitrite. In a phosphate buffer solution (PBS, pH 7.0), the peak current was linear to the concentration of nitrite in the range from 3.8×10-5 M to 1.0×10-3 M with a detection limit of 2.5×10-5 M. The interference effect on the nitrite detection was also studied. The proposed method was also employed for the determination of nitrite in rain and lake water samples

Meteorite impact craters as hotspots for mineral resources and energy fuels: A global review

The ever-increasing recovery rate of natural resources from terrestrial impact craters over the last few decades across the globe offers new avenues for further exploration of mineral and hydrocarbon resources in such settings. As of today, 60 of the 208 terrestrial craters have been identified to host diverse resources such as hydrocarbons, metals and construction materials. The potential of craters as plausible resource contributors to the energy sector is therefore, worthy of consideration, as 42 (70%) of the 60 craters host energy resources such as oil, gas, coal, uranium, mercury, critical and major minerals as well as hydropower resources. Among others, 19 craters are of well-developed hydrocarbon reserves. Mineral deposits associated with craters are also classified similar to other mineral resources such as progenetic, syngenetic and epigenetic sources. Of these, the progenetic and syngenetic mineralization are confined to the early and late excavation stage of impact crater evolution, respectively, whereas epigenetic deposits are formed during and after the modification stage of crater formation. Thus, progenetic and syngenetic mineral deposits (like Fe, Ni, Pb, Zn and Cu) associated with craters are formed as a direct result of the impact event, whereas epigenetic deposits (e.g. hydrocarbon) are hosted by the impact structure and result from post-impact processes. In the progenetic and syngenetic deposits, the shock-wave induced fracturing and melting aid the formation of deposits, whereas in the epigenetic deposits, the highly fractured lithostratigraphic units of higher porosity and permeability, like the central elevated area (CEA) or the rim, act as traps. In this review, we provide a holistic view of the mineral and energy resources associated with impact craters, and use some of the remote sensing techniques to identify the mineral deposits as supplemented by a schematic model of the types of deposits formed during cratering process

Usporedna analiza sekvenci dijagnostičkih PCR umnožaka virusa ovčjih boginja iz indijske ovce

Field samples were identified by agar gel precipitation and polymerase chain reaction (PCR) as positive for sheeppox virus. Envelope protein gene PCR amplicons (192 bp) of Indian sheeppox viruses isolated in 1997 and 2003 were sequenced to analyse nucleotide divergence. Analysis revealed that 2003 isolates possessed 100% nucleotide identity to each other, but only 95% nucleotide and amino acid were identity to an isolate from 1997. These Indian isolates were unique from other capripox virus sequences in that they contained a single codon insertion. Consistent with previous findings, the results indicate that recent sheepox virus isolates in India are more similar to previously described sheepox virus than to goatpox viruses from India and elsewhere.Virus ovčjih boginja dokazan je u terenskim uzorcima imunodifuzijom u gelu i lančanom reakcijom polimeraze (PCR). PCR umnošci gena za protein ovojnice (192 pb) indijskih izolata virusa ovčjih boginja izdvojenih tijekom 1997. i 2003. razlikovali su se po nukleotidnom slijedu. Izolati iz 2003. međusobno su bili identični u 100% nukleotida, dok je izolat iz 1997. bio njima podudaran samo u 95% nukleotida i aminokiselina. Ti indijski izolati bili su jedinstveni u odnosu na druge viruse boginja koza po jednom ugrađenom kodonu. U skladu s prijašnjim istraživanjima, nalazi ukazuju da su nedavni izolati virusa ovčjih boginja u Indiji sličniji ranije opisanim virusima ovčjih boginja nego virusima kozjih boginja iz Indije i drugdje