Carbon Dioxide Reduction Systems

The Methoxy system for regenerating oxygen from carbon dioxide was studied. Experiments indicate that the reaction between carbon dioxide and hydrogen can be carried out with ease in an efficient manner and with excellent heat conservation. A small reactor capable of handling the C02 expired by three men has been built and operated. The decomposition of methane by therma1,arc and catalytic processes was studied. Both the arc and catalytic processes gave encouraging results with over 90 percent of the methane being decomposed to carbon and hydrogen in some of the catalytic processes. Control of the carbon deposition in both the catalytic and arc processes is of great importance to prevent catalyst deactivation and short circuiting of electrical equipment. Sensitive analytical techniques have been developed for all of the components present in the reactor effluent streams

Wave-number-explicit bounds in time-harmonic scattering

In this paper we consider the problem of scattering of time-harmonic acoustic waves by a bounded sound soft obstacle in two and three dimensions, studying dependence on the wave number in two classical formulations of this problem. The first is the standard variational/weak formulation in the part of the exterior domain contained in a large sphere, with an exact Dirichletto-Neumann map applied on the boundary. The second formulation is as a second kind boundary integral equation in which the solution is sought as a combined single- and double-layer potential. For the variational formulation we obtain, in the case when the obstacle is starlike, explicit upper and lower bounds which show that the inf-sup constant decreases like k −1 as the wave number k increases. We also give an example where the obstacle is not starlike and the inf-sup constant decreases at least as fast as k −2. For the boundary integral equation formulation, if the boundary is also Lipschitz and piecewise smooth, we show that the norm of the inverse boundary integral operator is bounded independently of k if the coupling parameter is chosen correctly. The methods we use also lead to explicit bounds on the solution of the scattering problem in the energy norm when the obstacle is starlike in which the dependence of the norm of the solution on the wave number and on the geometry are made explicit

Design study and evaluation of a hypergolic engine for a space power system, phase 2 Final report, 1 Jul. 1964 - 10 Feb. 1966

Design feasibility of hypergolic engine for space power syste

Vertical variation in diffusion coefficient within sediments

River ecosystems can be strongly in uenced by contaminants in the water column, in the pore water and attached to sediment particles. Current models [TGD, 2003] predict exposure to sediments based on equilibrium partitioning between dissolved and suspended-particle-sorbed phase in the water column despite numerous studies showing significant direct mass transfer across the sediment water interface. When exchange across the interface (hyporheic exchange) is included in modelling the diffusion coefficient is assumed to be constant with depth. The overall aims of this research were to quantify the vertical variation in diffusion coefficient below the sediment water interface and asses the use of a modified EROSIMESS-System (erosimeter) in the study of hyporheic exchange. The modified erosimeter and novel fibre optic uorometers measuring in-bed concentrations Rhodamine WT were employed in an experimental investigation. Five different diameter glass sphere beds (0.15 to 5.0mm) and five bed shear velocities (0.01 to 0.04m/s) allowed the vertical variation in diffusion coefficient to be quantified to a depth of 0.134m below the sediment water interface. The vertical variation in diffusion coefficient can be described using an exponential function that was found to be consistent for all the parameter combinations tested. This function, combined with the scaling relationship proposed by O'Connor and Harvey [2008] allows a prediction of the diffusion coefficient below the sediment water interface based on bed shear velocity, roughness height and permeability. 1D numerical diffusion model simulations using the exponential function compare favourably with the experimental data

Experimental study of the runup of tsunami waves on a smooth sloping beach

A series of large-scale laboratory flume experiments are performed using a pneumatic long-wave generator to simulate tsunami-length trough-led waves. The periods generated are from approximately 6.5 – 37, 40, 72 and 230 s. The runup of these waves is measured on a 1:20 sloping beach. Preliminary results from these tests are presented. The reflections of long waves is discussed. Runup of the 230 s waves is found to be lower than the waves with periods of less than 72 s and previously published data in the literature. Plots of various wave parameters against runup show the strongest positive correlations to be with the crest amplitude and the total potential energy for all wave periods presented. The shorter period data shows a reasonably good fit to available runup relationships, with the longer 40, 72 and 230 s waves showing a poorer fit, suggesting another relationship. Outlines of extensive further work is also given

Large-Scale Experiments On Tsunami Inundation And Overtopping Forces At Vertical Sea Walls

Tsunami are very long gravity waves that may cause significant damage to coastal sea walls. The majority of relevant design codes and research papers that describe methods for predicting tsunami loads on coastal walls consider the scenario of transitory force from a bore-led wave. This does not relate to tsunami that do not form bore waves. Bore fronts generally cause short term spikes in force, which may have little effect on the vulnerability of massive structures. Post disaster accounts suggest that most coastal walls show damage that implies failure modes that occur over moderate to long durations. Therefore it is likely that the bore front assumption gives an overly conservative prediction of maximum force, and may not capture the full timescale of tsunami loading. This paper uses a pneumatic tsunami generation facility to determine the force loading on two vertical coastal sea walls during tsunami inundation. Two sea-wall models, 0.15 and 0.25 m high, with crown widths of 0.1 m (7.5 and 12.5 m at a nominal prototype scale of 1:50) are tested. It is shown that bore fronts only occur for short period waves over the bathymetry tested. Bore fronts cause a very short period spike in force, which is followed by a transitory force approximated by the hydrostatic pressure equation. The loading of tsunami length waves of periods $\geq$ 40 s (280 s prototype at 1:50 scale), which do not break is not greater than 1.2 times the hydrostatic force. Overtopping volume is positively correlated to the time duration of positive upstream head over the crest, rather than its maximum value. Overtopping causes a small increase in the horizontal load due to the addition of a drag and momentum load. The magnitude and time of these effects are small and short-lived in comparison to the hydrostatic load. The results compare well with available equations based on hydrostatic force and the engineer may apply a desired multiplying coefficient of a factor of at least 1.2 to account for any added pressure and momentum, and the factor of safety intended

Empirical fragility curves: The effect of uncertainty in ground motion intensity

Empirical fragility curves derived from large post-disaster databases with data aggregated at municipality-level, commonly make the assumption that the ground motion intensity level is known and is determined at the centroid of each municipality from a ground motion prediction equation. A flexible Bayesian framework is applied here to the 1980 Irpinia database to explore whether more complex statistical models that account for sources of uncertainty in the intensity can significantly change the shape of the fragility curves. Through this framework the effect of explicitly modelling the uncertainty in the intensity, the spatial correlation of its intra-event component and the uncertainty due to the scatter of the buildings in the municipality are investigated. The analyses showed that the results did not change substantively with increased model complexity or the choice of prior. Nonetheless, informed decisions should be based on the defensible modelling of the significant variability in the data between municipalities

Io's radar properties

Arecibo 13 cm wavelength radar observations during 1987-90 have yielded echoes from Io on each of 11 dates. Whereas Voyager imaged parts of the satellite at resolutions of several km and various visible/infrared measurements have probed the surfaces's microscale properties, the radar data yield new information about the nature of the surface at cm to km scales. Our observations provide fairly thorough coverage and reveal significant heterogeneity in Io's radar properties. A figure is given showing sums of echo spectra from 11 dates

Vertical variation of mixing within porous sediment beds below turbulent flows

River ecosystems are influenced by contaminants in the water column, in the pore water and adsorbed to sediment particles. When exchange across the sediment-water interface (hyporheic exchange) is included in modelling, the mixing coefficient is often assumed to be constant with depth below the interface. Novel fibre-optic fluorometers have been developed and combined with a modified EROSIMESS system to quantify the vertical variation in mixing coefficient with depth below the sediment-water interface. The study considered a range of particle diameters and bed shear velocities, with the permeability Péclet number, image between 1,000 and 77,000 and the shear Reynolds number, image between 5 and 600. Different parameterisation of both an interface exchange coefficient and a spatially variable in-sediment mixing coefficient are explored. The variation of in-sediment mixing is described by an exponential function applicable over the full range of parameter combinations tested. The empirical relationship enables estimates of the depth to which concentrations of pollutants will penetrate into the bed sediment, allowing the region where exchange will occur faster than molecular diffusion to be determined