Reactions forming C(0,+)n=2,10, Cn=2,4H(0,+) and C3H(0,+) in the gas phase: semi empirical branching ratios

The aim of this paper is to provide a new set of branching ratios for interstellar and planetary chemical networks based on a semi empirical model. We applied, instead of zero order theory (i.e. only the most exoergic decaying channel is considered), a statistical microcanonical model based on the construction of breakdown curves and using experimental high velocity collision branching ratios for their parametriza- tion. We applied the model to ion-molecule, neutral-neutral, and ion-pair reactions implemented in the few popular databases for astrochemistry such as KIDA, OSU and UMIST. We studied the reactions of carbon and hydrocarbon species with electrons, He+, H+, CH+, CH, C, and C+ leading to intermediate complexes of the type Cn=2,10, Cn=2,4 H, C3 H2, C+n=2,10, Cn=2,4 H+, or C3 H+2 . Comparison of predictions with measurements supports the validity of the model. Huge deviations with respect to database values are often obtained. Effects of the new branching ratios in time dependant chemistry for dark clouds and for photodissociation region chemistry with conditions similar to those found in the Horsehead Nebula are discussed

Study of Civil Markets for Heavy-Lift Airships

The civil markets for heavy lift airships (HLAs) were defined by first identifying areas of most likely application. The operational suitability of HLAs for the applications identified were then assessed. The operating economics of HLAs were established and the market size for HLA services estimated by comparing HLA operating and economic characteristics with those of competing modes. The sensitivities of the market size to HLA characteristics were evaluated and the number and sizes of the vehicles required to service the more promising markets were defined. Important characteristics for future HLAs are discussed that were derived from the study of each application, including operational requirements, features enhancing profitability, military compatibility, improved design requirements, approach to entry into service, and institutional implications for design and operation

A Baseline Investigation into the Population Structure of White Seabass, Atractoscion nobilis, in California and Mexican Waters Using Microsatellite DNA Analysis

The white seabass, Atractoscion nobilis, is a commercially important member of the Sciaenidae that has experienced historic exploitation by fisheries off the coast of southern California. For the present study, we sought to determine the levels of contemporary population connectivity among localities distributed throughout the species’ range using nuclear microsatellite markers. Data from the present study have revealed three distinct genetic units of white seabass: one in the north including the Southern California Bight to Ensenada, another in the south including Punta Abreojos, and the last from within the Gulf of California

Charge-Transfer Excitations in the Model Superconductor HgBa2_2CuO4+δ_{\bf 4+\delta}

We report a Cu $K$-edge resonant inelastic x-ray scattering (RIXS) study of charge-transfer excitations in the 2-8 eV range in the structurally simple compound HgBa$_2$CuO$_{4+\delta}$ at optimal doping ($T_{\rm c} = 96.5$ K). The spectra exhibit a significant dependence on the incident photon energy which we carefully utilize to resolve a multiplet of weakly-dispersive ($< 0.5$ eV) electron-hole excitations, including a mode at 2 eV. The observation of this 2 eV excitation suggests the existence of a charge-transfer pseudogap deep in the superconducting phase. Quite generally, our data demonstrate the importance of exploring the incident photon energy dependence of the RIXS cross section.Comment: 5 pages, 3 figure

Unraveling the Nature of Charge Excitations in La2_2CuO4_4 with Momentum-Resolved Cu KK-edge Resonant Inelastic X-ray Scattering

Results of model calculations using exact diagonalization reveal the orbital character of states associated with different Raman loss peaks in Cu $K$-edge resonant inelastic X-ray scattering (RIXS) from La$_{2}$CuO$_{4}$. The model includes electronic orbitals necessary to highlight non-local Zhang-Rice singlet, charge transfer and $d$-$d$ excitations, as well as states with apical oxygen 2$p_z$ character. The dispersion of these excitations is discussed with prospects for resonant final state wave-function mapping. A good agreement with experiments emphasizes the substantial multi-orbital character of RIXS profiles in the energy transfer range 1-6 eV.Comment: Original: 4.5 pages. Replaced: 4 pages and 4 figures with updated content and reference

Implications for Metallographic Cooling Rates, Derived from Fine-Scale Analytical Traverses Across Kamacite, Taenite, and Tetrataenite in the Butler Iron Meteorite

The "M-shaped" Ni concentrations across Widmanstatten patterns in iron meteorites, mesosiderites, and ordinary chondrites are commonly used to calculate cooling rates. As Ni-poor kamacite exolves from Ni-rich taenite, Ni concentrations build up at the kamacite-taenite interface because of the sluggish diffusivity of Ni. Quantitative knowledge of experimentally-determined Ni diffusivities, coupled with the shape of the M-profile, have been used to allow calculation of cooling rates that pertained at low temperatures, less than or equal to 500 C. However, determining Ni metallographic cooling rates are challenging, due to the sluggish diffusivity of Ni at low temperatures. There are three potential difficulties in using Ni cooling rates at low temperatures: (i) Ni diffusivities are typically extrapolated from higher-temperature measurements; (ii) Phase changes occur at low temperatures that may be difficult to take into account; and (iii) It appears that Ge in kamacite and taenite has continued to equilibrate (or attempted to equilibrate) at temperatures below those that formed the M-shaped Ni profile. Combining Ni measurements with those of other elements has the potential to provide a way to confirm or challenge Ni-determined cooling rates, as well as provide insight into the partitioning behaviors of elements during the cooling of iron meteorites. Despite these benefits, studies that examine elemental profiles of Ni along with other elements in iron meteorites are limited, often due to the low concentration levels of the other elements and associated analytical challenges. The Butler iron meteorite provides a good opportunity to conduct a multi-element analytical study, due to the higher concentration levels of key elements in addition to Fe and Ni. In this work, we perform combined analysis for six elements in the Butler iron to determine the relative behaviors of these elements during the evolution of iron meteorites, with implications for metallographic cooling rates

Nuclear break-up of 11Be

The break-up of 11Be was studied at 41AMeV using a secondary beam of 11Be from the GANIL facility on a 48Ti target by measuring correlations between the 10Be core, the emitted neutrons and gamma rays. The nuclear break-up leading to the emission of a neutron at large angle in the laboratory frame is identified with the towing mode through its characteristic n-fragment correlation. The experimental spectra are compared with a model where the time dependent Schrodinger equation (TDSE) is solved for the neutron initially in the 11 Be. A good agreement is found between experiment and theory for the shapes of neutron experimental energies and angular distributions. The spectroscopic factor of the 2s orbital is tentatively extracted to be 0.46+-0.15. The neutron emission from the 1p and 1d orbitals is also studied

Fragmentation of small carbon clusters, a review

An overview of the works devoted to fragmentation of small carbon clusters is given in a first part. Fragmentation of swift neutral and (multi) charged carbon clusters studied with the AGAT spectrometer is presented and discussed in a second part

Charge and current-sensitive preamplifiers for pulse shape discrimination techniques with silicon detectors

New charge and current-sensitive preamplifiers coupled to silicon detectors and devoted to studies in nuclear structure and dynamics have been developed and tested. For the first time shapes of current pulses from light charged particles and carbon ions are presented. Capabilities for pulse shape discrimination techniques are demonstrated.Comment: 14 pages, 12 figures, to be published in Nucl. Inst. Meth.

Fast-neutron induced background in LaBr3:Ce detectors

The response of a scintillation detector with a cylindrical 1.5-inch LaBr3:Ce crystal to incident neutrons has been measured in the energy range En = 2-12 MeV. Neutrons were produced by proton irradiation of a Li target at Ep = 5-14.6 MeV with pulsed proton beams. Using the time-of-flight information between target and detector, energy spectra of the LaBr3:Ce detector resulting from fast neutron interactions have been obtained at 4 different neutron energies. Neutron-induced gamma rays emitted by the LaBr3:Ce crystal were also measured in a nearby Ge detector at the lowest proton beam energy. In addition, we obtained data for neutron irradiation of a large-volume high-purity Ge detector and of a NE-213 liquid scintillator detector, both serving as monitor detectors in the experiment. Monte-Carlo type simulations for neutron interactions in the liquid scintillator, the Ge and LaBr3:Ce crystals have been performed and compared with measured data. Good agreement being obtained with the data, we present the results of simulations to predict the response of LaBr3:Ce detectors for a range of crystal sizes to neutron irradiation in the energy range En = 0.5-10 MeVComment: 28 pages, 10 figures, 4 Table