Lithiated cobaltates for lithium-ion batteries: Structure, morphology and electrochemistry of oxides grown by solid-state reaction, wet chemistry and film deposition

[Abstract] We present the structural (XRD and Raman) and electrochemical properties of various oxides of the cobaltate family (with the α-NaFeO2-type structure) grown by solid-state reaction, wet chemistry and film deposition techniques. It is shown that synthesis greatly affects the electrochemistry and cycle life characteristics of these layer structured cathode materials. HT-LiCoO2, LT-LiCoO2, doped LiCo1−yAlyO2 and LiCoO2 films are investigated

Structural and electrochemical properties of Li-Ni-Co oxides synthesized by wet chemistry via a succinic-acid-assisted technique

[Abstract] Lithiated metal oxides LiCo1−yNiyO2 were synthesized by a sol–gel method using succinic acid as chelating agent. Microcrystalline materials were formed by calcination in oxygen at 800°C. The physicochemical properties of the powders (crystallinity, lattice constants, size grain) has been investigated in the compositional range 0≤y≤1. Structural studies show that a layered single phase was obtained. The local cationic environment has been studied by Raman and FTIR spectroscopy. The changes in the vibrational spectra are well related to those observed by X-ray diffraction. It is shown that the lithium predominant layers are preserved in the entire range of substitution. Pelletized LiCo1−yNiyO2 powders (0.2≤y≤1.0) were tested in Li//LiCo1−yNiyO2 cells by galvanostatic titration. These cells have an initial capacity of 140 mAh/g in the voltage range 2.8–4.2 V and show attractive charge–discharge profiles upon cycling.Spanish and French Foreign Office; PAI Picasso 00717TCSpanish and French Foreign Office; HF1999-010

Estrategia de Comunicación Interna de la Empresa Nicaragüense de Acueductos y Alcantarillados (ENACAL) sede Masaya a partir de 2014

En este trabajo investigativo se analizó a través del diagnóstico comunicacional las debilidades y fortalezas de la Empresa Nicaragüense de Acueductos y Alcantarillados (ENACAL), con respecto a su comunicación interna definiendo algunas estrategias que ayuden a mejorar o reforzar los lazos comunicacionales entre los trabajadores y sus superiores.tre los criterios seleccionados para realizar la debida investigación se tomó en cuenta a los trabajadores y a la delegada de la empresa. Con el objetivo de identificar cuáles eran los problemas de comunicación que se estaban dando dentro del ente.Cabe mencionar que para el debido estudio de esta investigación, en el marco teórico se hizo uso de teoría que constata nuestros argumentos sobre la Comunicación, comunicación interna y las estrategias, las que ayudaran a un mayor flujo comunicacional dentro y fuera de la empresa. También se brinda información sobre los aspectos generales que tiene ENACAL con respecto a sus usuarios.En lo que respecta a su diseño metodológico, se especifica el tipo de investigación, el nivel de profundidad y al respecto al proceso de desarrollo del fenómeno es transversal porque es tomado en cuenta el tiempo estipulado para su aplicación en el 2014, seguido de los métodos y el procedimiento a seguir.Para realizar el procedimiento a la investigación se llevó a cabo observación directa a la institución, después se procedió a la implementación del grupo focal. Luego se aplicaron encuestas y entrevista, con el propósito de conocer la opinión de los trabajadores que están subordinados a los jefes de áreas y filiales, por otra parte conocer la posición oficial e institucional de la delegado Después de todo este procedimiento se pudo obtener dentro de las respuestas los principales problemas comunicacionales que se dan en la empresa tanto a lo interno como a lo externo, por lo que se plantea, la necesidad de crear para este ente, estrategias de comunicación que ayuden a su formación y mejoramiento comunicacional interno

Influence of aluminum doping on the properties of LiCoO2 and LiNi0.5Co0.5O2 oxides

We have prepared LiCo1−yAlyO2 and LiNi0.5−yAlyCo0.5O2 (0≤y≤0.3) powder samples by a low temperature sol–gel method using succinic acid as chelating agent. We have studied the details of their crystallographic and local structure by X-ray diffraction (XRD) and FTIR spectroscopy, respectively; we have analyzed their chemical composition by ICP and obtained information about the morphology of the polycrystalline particles by SEM. Also, we have studied the electrochemical performance of the as-prepared materials in the LiLiNi0.5−yAlyCo0.5O2 cells cycled in the potential range 2.5–4.2 V finding that the overall capacity of the oxides has been reduced due to the metal substitution. For example, at 4.2 V cut-off, the charge capacity of the LiLiNi0.35Al0.15Co0.5O2 cell is ca. 115 mA h/g. However, more stable charge–discharge cycling performances have been obtained as compared to those displayed by the native oxides. Finally, we have characterized the kinetics of Li-diffusion by the galvanostatic intermittent titration technique and, according to our results, Al substitution provides an increase in the chemical diffusion coefficients of Li ions in the LiNi0.5−yAlyCo0.5O2 matrix.Spanish and French Foreing Office; PAI Picasso 00717TCSpanish and French Foreing Office; HF 1999-010

LiCo1−yMyO2 positive electrodes for rechargeable lithium batteries: II. Nickel substituted materials grown by the citrate method

[Abstract] The layered LiCo1−yNiyO2 microcrystalline powders were synthesized by a sol–gel method using citric acid as a chelating agent in the range 0.2 ≤ y ≤ 0.8. Submicron-sized particles of the precursor were obtained at temperature below 400 °C and microcrystalline powders were grown by thermal treatment at 700 °C for 5 h in air. The carboxylic-based acid functioned such as a fuel, decomposed the homogeneous precipitate of metal complexes at low temperature, and yielded the free impurity LiCo1−yNiyO2 single-phases suitable for electrochemical applications. The synthesized products were characterized by structural, spectroscopic and thermal analyses. FT-IR measurements provide information on the growth process and the final local environment in the cationic sublattice of LiCo1−yNiyO2 solid solution. The electrochemical performance of the synthesized products in rechargeable Li cells was evaluated using non-aqueous solution 1 M LiPF6 in EC-DMC as electrolyte. The electrochemical features of a series of LiCo1−yNiyO2 compounds (0.2 ≤ y ≤ 1.0) are discussed in relation with their synthesis procedure and substitutive amount. The substitution of Ni3+ for Co3+ in LiCo1−yNiyO2 for y = 0.75 shows improvement of the specific capacity at ca. 187 mAh/g upon 32 cycles

Charge ordering and dielectric properties in the near half-doped Pr0.79Na0.21MnO3 perovskite

[Abstract] The Pr0.79Na0.21MnO3 perovskite has been prepared in polycrystalline form by a ceramic method. We have carried out its structural characterization by synchrotron X-ray powder diffraction (SXRPD) at room temperature and at 150 K (T<TCO). In the charge ordering (CO) state, the SXRPD data can be refined both on the basis of the site-centred model and the bond-centred model proposed for half-doped manganites, without a clear advantage of one model over the other. From the dielectric point of view, at the CO temperature this manganite shows a maximum in the dielectric constant whose origin is intrinsic, and cannot be attributed to the presence of extrinsic factors. We relate this dielectric behaviour to the formation of polar entities at the temperature of charge condensation, due to an asymmetric charge distribution intermediate between site-centred and bond-centred type.Xunta de Galicia; PGIDIT06PXB103298PRMinisterio de Educación y Ciencia; Project FEDER MAT 2004-0513

Studies on the power factor of (Ba,Sr)Co2+xRu4−xO11 compounds

[Abstract] We have prepared polycrystalline single-phase ACo2+xRu4−xO11 (A = Sr, Ba; 0 ≤ x ≤ 0.5) using the ceramic method and we have studied their structure, electrical resistivity and Seebeck coefficient, in order to estimate their power factor (P.F.). These layered compounds show values of electrical resistivity of the order of 10−5 Ωm and their Seebeck coefficients are positive and range from 1 μV K−1 (T = 100 K) to 20 μV K−1 (T = 450 K). The maximum power factor at room temperature is displayed by BaCo2Ru4O11 (P.F.: 0.20 μW K−2 cm−1), value that is comparable to that shown by compounds such as SrRuO3 and Sr6Co5O15.Ministerio de Ciencia e Innovación; Project FEDER MAT 2007-6669

Magnetic and electronic properties of lithium cobalt oxide substituted by nickel

[Abstract] We measured susceptibility, electron-spin resonance, magnetization and electrical conductivity of LiCo1−yNiyO2 powders synthesized by wet-chemistry method using succinic acid as chelating agent. We found unusual properties in the nickel-rich LiCo0.2Ni0.8O2, which shows several resonance lines as a function of the temperature in the range 3.5–300 K. The signal at low magnetic field is attributed to the magnetic domains in the nanostructured sample. The two other lines correspond to the typical ferromagnetic signal observed in powdered compounds. In the temperature range 120–300 K, the unique ESR line centered at 315 mT is the paramagnetic signal with a gyromagnetic factor g=2.12, which is in good agreement with the presence of a high concentration of Ni3+ (3d7) ions. In the nickel-rich oxide, LiNi0.8Co0.2O2, the magnetic data are qualitatively well-described by the model proposed by Drillon and Panissod for a 3D ferromagnetic order.Spanish and French Foreign Office; HF 1999-0101Spanish and French Foreign Office; PAI Picasso 00717T

IR characterization of Ln2−xSrxCoO4 (x≥1; Ln=La, Nd) oxides

[Abstract] We have recorded the FTIR spectra of powder samples of Ln2−xSrxCoO4 (Ln=La, Nd) at room temperature. We have identified the infrared active modes (3A2u+4Eu), and analyzed how they change as a function of Ln and the Sr doping. We correlate the obtained results with structural data obtained from powder X-ray diffraction studies and with the electronic properties displayed by these samples

Apparent colossal dielectric constants in nanoporous Metal Organic Frameworks

[Abstract] In this work, we show that the hybrid material Co2(1,4-bdc)2(dabco)•[4DMF•1H2O], shows an apparent colossal dielectric constant at room temperature (r5000 at 300 K for =100 Hz). Nevertheless, such response does not imply colossal polarizability processes, as its dielectric constant is not purely intrinsic, but is greatly enhanced by the activation of extrinsic dielectric effects close to room temperature associated to the diffusion of numerous guest molecules through the channels. If such extrinsic contributions are eliminated or reduced, the values of the dielectric constant turn to be much smaller, as observed in the closely related Co2(1,4-bdc-NH2)2(dabco)•[7/2DMF•1H2O], Co2(1,4-ndc)2(dabco) •[3DMF•2H2O] and Ni2(1,4-bdc)2(dabco)•[3DMF•1/2H2O] compounds. Therefore, we warn about the imperious necessity of distinguishing between intrinsic and extrinsic effects in electrically inhomogenous MOF materials that display a certain conductivity in order to adequately interpret their dielectric behaviorMinisterio de Economía y Competitividad; MAT2010-21342-C02-01Xunta de Galicia; PGIDIT10PXB103272P