Sensitivity of Intrinsic Permeability to Electrokinetic Coupling in Shaly and Clayey Porous Media

Classical Darcy's law assumes that the intrinsic permeability of porous media is only dependent on the micro-geometrical and structural properties of the inner geometry of the medium. There are, however, numerous experimental evidences that intrinsic permeability of shaly and clayey porous material is a function of the fluid phase used in the experiments. Several pore-scale processes have been proposed to explain the observed behavior. In this study, we conduct a detailed investigation of one such mechanism, namely the electrokinetic coupling. We have developed a numerical model to simulate this process at the pore-scale, incorporating a refined model of the electrical double layer. The model is used to conduct a detailed sensitivity analysis to elucidate the relative importance of several chemical-physical parameters on the intensity of the electrokinetic coupling. We found that permeability reduction due to this mechanism is likely to occur only if the effective pore-radius is smaller than 10−6m. We also observed that electrokinetic coupling is strongly sensitive to electrophoretic mobility, which is normally reduced in clays compared to free-water conditions. Based on these findings, we set up a suite of stochastic pore-network simulations to quantify the extent of permeability reduction. We found that only if the effective pore-radius is ranging from 5× 10−7m to 5× 10−8, electrokinetic coupling can be responsible for a 5-20% reduction of the intrinsic permeability, and, therefore, this mechanism has a minor impact on situations of practical environmental or mining interes

Small Local Earthquake Detection Using Low‐Cost MEMS Accelerometers: Examples in Northern and Central Italy

Abstract This study evaluates the seismicity detection efficiency of a new low-cost triaxial accelerometer prototype based on microelectromechanical systems (MEMS) technology. Networks of MEMS sensors were installed in telecommunication infrastructures to build two small arrays in northern and central Italy. The sensor prototypes recorded major earthquakes as well as nine small seismic events with 2.0<ML<3.0. Where possible, MEMS were compared to the closest high-quality seismic stations belonging to the national accelerometric network. The comparison, in terms of peak ground accelerations and spectral responses, confirms that the signals are in good agreement. The tested inexpensive MEMS sensors were able to detect small local events with epicentral distances as large as 50 km and provided an efficient characterization of the main motion parameters. This confirms that the proposed accelerometer prototypes are promising tools to integrate into traditional networks for local seismicity monitoring

Shear wave profiles from surface wave inversion: the impact of uncertainty on seismic site response analysis

Inversion is a critical step in all geophysical techniques, and is generally fraught with ill-posedness. In the case of seismic surface wave studies, the inverse problem can lead to different equivalent subsoil models and consequently to different local seismic response analyses. This can have a large impact on an earthquake engineering design. In this paper, we discuss the consequences of non-uniqueness of surface wave inversion on seismic responses, with both numerical and experimental data. Our goal is to evaluate the consequences on common seismic response analysis in the case of different impedance contrast conditions. We verify the implications of inversion uncertainty, and consequently of data information content, on realistic local site responses. A stochastic process is used to generate a set of 1D shear wave velocity profiles from several specific subsurface models. All these profiles are characterized as being equivalent, i.e. their responses, in terms of a dispersion curve, are compatible with the uncertainty in the same surface wave data. The generated 1D shear velocity models are then subjected to a conventional one-dimensional seismic ground response analysis using a realistic input motion. While recent analyses claim that the consequences of surface wave inversion uncertainties are very limited, our test points out that a relationship exists between inversion confidence and seismic responses in different subsoils. In the case of regular and relatively smooth increase of shear wave velocities with depth, as is usual in sedimentary plains, our results show that the choice of a specific model among equivalent solutions strongly influences the seismic response. On the other hand, when the shallow subsoil is characterized by a strong impedance contrast (thus revealing a characteristic soil resonance period), as is common in the presence of a shallow bedrock, equivalent solutions provide practically the same seismic amplification, especially in the frequency range of engineering interest

Tackling Lateral Variability Using Surface Waves: A Tomography-Like Approach

Lateral velocity variations in the near-surface reflect the presence of buried geological or anthropic structures, and their identification is of interest for many fields of application. Surface wave tomography (SWT) is a powerful technique for detecting both smooth and sharp lateral velocity variations at very different scales. A surface-wave inversion scheme derived from SWT is here applied to a 2-D active seismic dataset to characterize the shape of an urban waste deposit in an old landfill, located 15 km South of Vienna (Austria). First, the tomography-derived inverse problem for the 2-D case is defined: under the assumption of straight rays at the surface connecting sources and receivers, the forward problem for one frequency reduces to a linear relationship between observed phase differences at adjacent receivers and wavenumbers (from which phase velocities are straightforwardly derived). A norm damping regularization constraint is applied to ensure a smooth solution in space: the choice of the damping parameter is made through a minimization process, by which only phase variations of the order of the average wavelength are modelled. The inverse problem is solved for each frequency with a weighted least-squares approach, to take into account the data error variances. An independent multi-offset phase analysis (MOPA) is performed using the same dataset, for comparison: pseudo-sections from the tomography-derived linear inversion and MOPA are very consistent, with the former giving a more continuous result both in space and frequency and less artefacts. Local dispersion curves are finally depth inverted and a quasi-2-D shear wave velocity section is retrieved: we identify a well-defined low velocity zone and interpret it as the urban waste deposit body. Results are consistent with both electrical and electromagnetic measurements acquired on the same line

Characterization of Dismissed Landfills Via Geophysical Techniques

In the context of waste landfill management, geophysical methods are a powerful tool for evaluating their impact on public health and environment. Noninvasive and cost-effective geophysical techniques rapidly investigate large areas with no impact on the system. This is essential for the characterization of the waste body and the evaluation of the liner integrity at the bottom of the landfill and leakage localization. Three case studies are described with the purpose of highlighting the potentiality of such techniques in landfill studies. The case studies show different site conditions (capped landfills, controlled closed systems, and unconfined systems) that limit the applicability of any other kind of investigation and, at the same time, highlight the versatility of the geophysical techniques to adapt to several field situations. Electrical and electromagnetic techniques proved to be the most efficient geophysical techniques for providing useful information to develop an accurate site conceptual model

Frequency-Domain Electromagnetic Mapping of an Abandoned Waste Disposal Site: A Case in Sardinia (Italy)

For decades, bad practices inmunicipal and industrial wastemanagement have had negative environmental impacts, generating high health risks for people and the environment. The use of badly designed, not engineered, and not well-operated landfills has, around the world, produced a large number of potentially contaminated sites, for which there are urgent needs to assess the actual risk and to proceed, in case, with reclamation activities. One of these sites, an abandoned waste disposal site located near a Site of Community Importance on the central-eastern coast of Sardinia (Italy), is the subject of the case history described in this work. As a part of a multi-method geophysical characterisation, a frequency-domain electromagnetic (FDEM) mapping survey was carried out with the specific aim of detecting the presence of buried materials (waste) and of delineating the lateral extent of the landfill by identifying the electrical conductivity anomalies produced, for the most part, by the conductive waste fill. Using an EM31 device in the vertical-dipole configuration, at a height of 0.9 m above the ground, both quadrature and in-phase electromagnetic responses were collected over a 7-hectare area with elevation varying between 6 m and 2.8 m above sea level. After removing the measurements identified as data coming from any recognisable surface man-made features within the survey area or near its perimeter, the filtered quadrature response (expressed as apparent conductivity) ranged from 5.5 mS/m to about 188.6 mS/m. All values are beyond the low induction number (LIN) condition and valid for the classical EM31 mapping, thus requiring advanced data processing. To obtain undistorted, meaningful, and interpretable high-resolution maps, measured data have been processed to correct the bias, introduced by the nonlinearity of the device, as a function of height above ground and the topography. The comparative analysis of the apparent conductivity map, obtained by the properly processed EM31 data and some aerial photos that clearly documented the site history, has allowed unequivocal delineation of the landfill extent, in good agreement with the results obtained with other geophysical methods (not described in this paper) and with the ground truthing data provided by three boreholes, which were core-drilled at the end of the study at three locations selected on the basis of the apparent conductivity map

Reply to comment on 'Shear wave profile from surface wave inversion: the impact of uncertainty on seismic site response analysis'

Socco et al (2012 J. Geophys. Eng. 9 241) comment on our study about the effect of non-uniqueness of surface wave solutions on seismic site response analysis. In particular, they refer to the approach we adopted for the selection of equivalent shear wave velocity profiles and argue that it leads to overestimation of the uncertainty due to the inherent ill-posedness of the problem. Moreover, for one of the synthetic cases of our original paper, they calculate a different set of equivalent velocity profiles, retrieving the corresponding amplification spectra. From these results, Socco et al claim that their general conclusion that the impact of solution non-uniqueness on seismic response simulations is negligible. In this reply we demonstrate that (a) the uncertainty bounds used by Socco et al in their prediction analysis, as a consequence of their surface wave inversion procedure, are unreasonably narrow; (b) consequently, their shaking predictions appear to suffer no impact from their underestimated uncertainty; and (c) their presented case shows an amplification spectrum that is only the result of assuming the existence of a bedrock at 150 m that causes resonance of the overlying layer—practically independent of the details of the S-wave velocity distribution

A field-scale remediation of residual light non-aqueous phase liquid (LNAPL): chemical enhancers for pump and treat

The remediation of petroleum-contaminated soil and groundwater is a challenging task. The petroleum hydrocarbons have a long persistence in both the vadose zone and in the aquifer and potentially represent secondary and residual sources of contamination. This is particularly evident in the presence of residual free-phase. Pump-and-treat is the most common hydrocarbon decontamination strategy. Besides, it acts primarily on the water dissolved phase and reduces concentrations of contaminants to an asymptotic trend. This study presents a case of enhanced light non-aqueous phase liquid (LNAPL) remediation monitored using noninvasive techniques. A pilot-scale field experiment was conducted through the injection of reagents into the subsoil to stimulate the desorption and the oxidation of residual hydrocarbons. Geophysical and groundwater monitoring during pilot testing controlled the effectiveness of the intervention, both in terms of product diffusion capacity and in terms of effective reduction of pollutant concentrations. In particular, non-invasive monitoring of the reagent migration and its capability to reach the target areas is a major add-on to the remediation technique. Most of the organic contaminants were decomposed, mobilized, and subsequently removed using physical recovery techniques. A considerable mass of contaminant was recovered resulting in the reduction of concentrations in the intervention areas