Etapes estètiques /

Forma part del projecte: Biblioteca Digital d'Història de l'Art Hispànic (UAB)Localització de l'original: Universitat Autònoma de BarcelonaEstudi de temàtica artística editada per la Societat Catalana d'Edicions l'any 1916 i en dos volums. El primer es centra en la ciutat de París, i el segon presenta Barcelona i l'Exposició General de Belles Arts de 1894. Conté un retrat de l'autorEstudio de temática artística editada por la Societat Catalana d'Edicions en 1916 y en dos volúmenes. El primero se centra en la ciudad de París, y el segundo presenta Barcelona la Exposición General de Bellas Artes de 1894. Contiene un retrato del autorStudy on art edited in two volumes by Societat Catalana d'Edicions in 1916. The first one focuses on the city of Paris, and the second one presents Barcelona and the Exposició General de Belles Arts in 1894. It contains a portrait of the autho

Impact of HONO sources on the performance of mesoscale air quality models

Nitrous acid (HONO) photolysis constitutes a primary source of OH in the early morning, which leads to changes in model gas-phase and particulate matter concentrations. However, state-of-the-art models of chemical mechanisms share a common representation of gas-phase chemistry leading to HONO that fails in reproducing the observed profiles. Hence, there is a growing interest in improving the definition of additional HONO sources within air quality models, i.e. direct emissions or heterogeneous reactions. In order to test their feasibility under atmospheric conditions, the WRF-ARW/HERMES/CMAQ modeling system is applied with high horizontal resolution (4 4 km2) to Spain for November 24e27, 2008. HONO modeled sources include: (1) direct emissions from on-road transport; NO2 hydrolysis on aerosol and ground surfaces, the latter with (2) kinetics depending exclusively on available surfaces for reaction and (3) refined kinetics considering also relative humidity dependence; and (4) photoenhanced NO2 reduction on ground surfaces. The DOMINO measurement campaign performed in El Arenosillo (Southern Spain) provides valuable HONO observations. Modeled HONO results are consistently below observations, even when the most effective scenario is assessed, corresponding to contributions of direct emissions and NO2 hydrolysis with the simplest kinetics parameterization. With the additional sources of HONO, PM2.5 predictions can be up to 14% larger in urban areas. Quantified impacts on secondary pollutants have to be taken as a low threshold, due to the proven underestimation of HONO levels. It is fundamental to improve HONO sources definition within air quality models, both for the scientific community and decision makers.Peer ReviewedPostprint (published version

Epithelial cell shedding and barrier function: a matter of life and death at the small intestinal villus tip

The intestinal epithelium is a critical component of the gut barrier. Composed of a single layer of intestinal epithelial cells (IECs) held together by tight junctions, this delicate structure prevents the transfer of harmful microorganisms, antigens, and toxins from the gut lumen into the circulation. The equilibrium between the rate of apoptosis and shedding of senescent epithelial cells at the villus tip, and the generation of new cells in the crypt, is key to maintaining tissue homeostasis. However, in both localized and systemic inflammation, this balance may be disturbed as a result of pathological IEC shedding. Shedding of IECs from the epithelial monolayer may cause transient gaps or microerosions in the epithelial barrier, resulting in increased intestinal permeability. Although pathological IEC shedding has been observed in mouse models of inflammation and human intestinal conditions such as inflammatory bowel disease, understanding of the underlying mechanisms remains limited. This process may also be an important contributor to systemic and intestinal inflammatory diseases and gut barrier dysfunction in domestic animal species. This review aims to summarize current knowledge about intestinal epithelial cell shedding, its significance in gut barrier dysfunction and host-microbial interactions, and where research in this field is directed

FIB/FESEM experimental and analytical assessment of R-curve behavior of WC-Co cemented carbides

Exceptional fracture toughness levels exhibited by WC-Co cemented carbides (hardmetals) are due mainly to toughening derived from plastic stretching of crack-bridging ductile enclaves. This takes place due to the development of a multiligament zone at the wake of cracks growing in a stable manner. As a result, hardmetals exhibit crack growth resistance (R-curve) behavior. In this work, the toughening mechanics and mechanisms of these materials are investigated by combining experimental and analytical approaches. Focused Ion Beam technique (FIB) and Field-Emission Scanning Electron Microscopy ( FESEM) are implemented to obtain serial sectioning and imaging of crack-microstructure interaction in cracks arrested after stable extension under monotonic loading. The micrographs obtained provide experimental proof of the developing multiligament zone, including failure micromechanisms within individual bridging ligaments. Analytical assessment of the multiligament zone is then conducted on the basis of experimental information attained from FIB/FESEM images, and a model for the description of R-curve behavior of hardmetals is proposed. It was found that, due to the large stresses supported by the highly constrained and strongly bonded bridging ligaments, WC-Co cemented carbides exhibit quite steep but short R-curve behavior. Relevant strength and reliability attributes exhibited by hardmetals may then be rationalized on the basis of such toughening scenario.Ministerio de España de Economía y Competitividad (Grant MAT2012-34602)Industry-University program between Sandvik Hyperion and Universitat Politècnica de Cataluny

Sheet failure prediction during forming of advanced high strength steels

The automotive industry has increased significantly the use of advanced high strength steels (AHSS) in many structural components of vehicles, with the aim to reduce weight and also increase safety. The high resistance of these steels is accompanied by a decrease in formability, which makes simulation a requirement to adequately foresee the formability of a stretch formed component. For sheet metal forming, the conventional diagram based in strains, Forming Limit Diagrams (FLD), is often used as a failure criterion, but this approach is not effective when working with AHSS, due to the bigger effect produced by changes on strain paths than conventional steels. This work proposes the use a Forming Limit Stress Diagram (FLSD) based on the main stresses acting on the material. These FLSD has been obtained by the simulation of stretching test. To improve the results, the tensile test curve has been extended by using an optical measuring system and a subsequent adjustment of the stress-strain curve for the material. Finally, simulations and real parts behavior have been compared and the failure predictions models have been discussed.Postprint (published version

Near real time evaluation of the spanish air quality forecast system: CALIOPE

The WRF-ARW/HERMES-EMEP/CMAQ/BSC-DREAM8b modelling system provides high resolution air quality predictions for 48h in Europe –EU12- (12x12 km2, 1h), the Iberian Peninsula and Balearic Islands –IP4- (4x4 km2, 1h) and Canary Islands –CAN2- (2x2 km2, 1h) since July 2007, under the framework of the CALIOPE project (Baldasano et al., 2008; http://www.bsc.es/caliope/). A near real time evaluation system has been developed and it is on-line and in operation since January, 2009. Non validated near real time air quality data from more than 400 surface stations are compared to ground-concentration predictions in Spain. Seven ozonosondes are used to test the performance of the model in reproducing O3 vertical structures in Europe, Spain and Canary Islands. Additionally, OMI images are used to qualitatively assess the vertical column densities of NO2 predicted for Europe.Postprint (published version

Igκ allelic inclusion is a consequence of receptor editing

The discovery of lymphocytes bearing two light chains in mice carrying self-reactive antibody transgenes has challenged the “one lymphocyte–one antibody” rule. However, the extent and nature of allelically included cells in normal mice is unknown. We show that 10% of mature B cells coexpress both Igκ alleles. These cells are not the result of failure in allelic exclusion per se, but arise through receptor editing. We find that under physiological conditions, editing occurs both by deletion and by inclusion with equal probability. In addition, we demonstrate that B lymphocytes carrying two B-cell receptors are recruited to germinal center reactions, and thus fully participate in humoral immune responses. Our data measure the scope of allelic inclusion and provide a mechanism whereby autoreactive B cells might “escape” central tolerance