5,614 research outputs found
Sorption vacuum trap Patent
Describing sorption vacuum trap having housing with group of reentrant wall portions projecting into internal gas-pervious container filled with gas and vapor sorbent materia
Novel solid-state emissive polymers and polymeric blends from a T-Shaped benzodifuran scaffold: A comparative study
Two novel polyimines were synthesized from a benzodifuran based diamino monomer and two dialdehydes bearing bulky groups and a flexible spacer. The polymers display tuned luminescence performance according to the presence of half-salen groups. The effect of the intramolecular bond on the emission properties were examined. Two model compounds, replicating the same emissive Schiff base cores, were synthetized. From the models, dye-doped blends in the fluorophore/matrix ratio, resembling the polymers, were produced. Amorphous thin films of the covalent polymers and the polymeric blends were obtained by spin-coating technique. The Photoluminescent (PL) response of the different macromolecular systems were qualitatively and quantitatively examined and compared
Noise-enhanced classical and quantum capacities in communication networks
The unavoidable presence of noise is thought to be one of the major problems
to solve in order to pave the way for implementing quantum information
technologies in realistic physical platforms. However, here we show a clear
example in which noise, in terms of dephasing, may enhance the capability of
transmitting not only classical but also quantum information, encoded in
quantum systems, through communication networks. In particular, we find
analytically and numerically the quantum and classical capacities for a large
family of quantum channels and show that these information transmission rates
can be strongly enhanced by introducing dephasing noise in the complex network
dynamics.Comment: 4 pages, 4 figures; See Video Abstract at
http://www.quantiki.org/video_abstracts/1003587
A novel DR/NIR T-shaped aiegen: Synthesis and x-ray crystal structure study
We developed a new benzodifuran derivative as the condensation product between 2,6-diamino-4-(4-nitrophenyl)benzo[1,2-b:4,5-b’]difuran-3,7-dicarboxylate and 3-hydroxy-2-naphthaldehyde. The intramolecular hydrogen-bond interactions in the terminal half-salen moieties produce a sterically encumbered highly conjugated main plane and a D-A-D (donor-acceptor-donor) T-shaped structure. The novel AIEgen (aggregation-induced enhanced emission generator) fulfils the requirement of RIR (restriction of intramolecular rotation) molecules. DR/NIR (deep red/near infrared) emission was recorded in solution and in the solid state, with a noteworthy photoluminescence quantum yield recorded on the neat crystals which undergo some mechanochromism. The crystal structure study of the probe from data collected at a synchrotron X-ray source shows a main aromatic plane π-stacked in a columnar arrangement
Simulation of noise-assisted transport via optical cavity networks
Recently, the presence of noise has been found to play a key role in
assisting the transport of energy and information in complex quantum networks
and even in biomolecular systems. Here we propose an experimentally realizable
optical network scheme for the demonstration of the basic mechanisms underlying
noise-assisted transport. The proposed system consists of a network of coupled
quantum optical cavities, injected with a single photon, whose transmission
efficiency can be measured. Introducing dephasing in the photon path this
system exhibits a characteristic enhancement of the transport efficiency that
can be observed with presently available technology.Comment: 8 pages, 7 figures. New version with more detail
Analysis of debris from Spacelab Space Life Sciences-1
Airborne microbiological and particulate contamination generated aboard Spacelab modules is a potential safety hazard. In order to shed light on the characteristics of these contaminants, microbial and chemical/particulate analyses were performed on debris vacuumed from cabin and avionics air filters in the Space Life Sciences-1 (SLS-1) module of the Space Transportation System 40 (STS-40) mission 1 month after landing. The debris was sorted into categories (e.g., metal, nonmetal, hair/fur, synthetic fibers, food particles, insect fragments, etc.). Elemental analysis of particles was done by energy dispersive analysis of x rays (metals) and Fourier transform infrared spectroscopy (nonmetals). Scanning electron micrographs were done of most particles. Microbiological samples were grown on R2A culture medium and identified. Clothing fibers dominated the debris by volume. Other particles, all attributed to the crew, resulted from abrasions and impacts during missions operations (e.g., paint chips, plastic, electronic scraps and clothing fibers). All bacterial species identified are commonly found in the atmosphere or on the human body. Bacillus sp. was the most frequently seen bacterium. One of the bacterial species, Enterobacter agglomerans, could cause illness in crew members with depressed immune systems
Cyclic Fluctuations, Climatic Changes and Role of Noise in Planktonic Foraminifera in the Mediterranean Sea
The study of Planktonic Foraminifera abundances permits to obtain climatic
curves on the basis of percentage ratio between tropical and temperate/polar
forms. Climatic changes were controlled by several phenomena as: (i)
Milankovitch's cycles, produced by variations of astronomical parameters such
as precession, obliquity and eccentricity; (ii) continental geodynamic
evolution and orogenic belt; (iii) variations of atmospheric and oceanic
currents; (iv) volcanic eruptions; (v) meteor impacts. But while astronomical
parameters have a quasi-regular periodicity, the other phenomena can be
considered as "noise signal" in natural systems. The interplay between cyclical
astronomical variations, the "noise signal" and the intrinsic nonlinearity of
the ecologic system produces strong glacial or interglacial period according to
the stochastic resonance phenomenon.Comment: 6 pages, 4 figure
In search of a new language. Italian labour law scholarship in the face of European integration
Jean Monnet Working Paper
Realistic and verifiable coherent control of excitonic states in a light harvesting complex
We explore the feasibility of coherent control of excitonic dynamics in light
harvesting complexes, analyzing the limits imposed by the open nature of these
quantum systems. We establish feasible targets for phase and phase/amplitude
control of the electronically excited state populations in the
Fenna-Mathews-Olson (FMO) complex and analyze the robustness of this control
with respect to orientational and energetic disorder, as well as decoherence
arising from coupling to the protein environment. We further present two
possible routes to verification of the control target, with simulations for the
FMO complex showing that steering of the excited state is experimentally
verifiable either by extending excitonic coherence or by producing novel states
in a pump-probe setup. Our results provide a first step toward coherent control
of these complex biological quantum systems in an ultrafast spectroscopy setup.Comment: 12 pages, 8 figure
Gaining insight into exclusive and common transcriptomic features linked with biotic stress responses in Malus
Identifying key information in transcriptomic data is very important, especially when the “omic” study deals with plant responses to stresses in field conditions where a high number of variables and disturbing factors may affect the analysis. In this meta-analysis we collected 12 transcriptomic works in Malus in order to identify which key genes, proteins, gene categories are involved in general plant pathological conditions and those features linked with exclusive biotic stress responses. Those genes that are only related with molecular responses to pathogen attacks and those linked with other plant physiological processes were identified. A pipeline composed by pathway and gene set enrichment analysis, protein-protein interaction networks and gene visualization tools was employed. A total of 13,230 genes of the 12 studies were analyzed with functional data mining tools: 5,215 were upregulated, 8,015 were downregulated. Gene set enrichment analysis pointed out that photosynthesis was inhibited by Erwinia amylovora and fungal pathogens. Different hormonal crosstalk was linked with responses to different pathogens. Gibberellin-related pathways, ABA-related were mostly repressed by fungal pathogens. Relating to transcription factors, genes encoding MYBs and WRKY2 were downregulated by fungal pathogens and 12 WRKYs were commonly regulated by different biotic stresses The protein-protein interaction analysis discovered the presence of several proteins affected by more than one biotic stress including a WRKY40 and some highly interactive proteins such as heat shock proteins. This study represents a first preliminary curated meta-analysis of apple transcriptomic responses to biotic stresses
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