1,880 research outputs found
Dissociation of CH4 by electron impact: Production of metastable hydrogen and carbon fragments
Metastable fragments produced by electron impact excitation of CH4 have been investigated for incident electron energies from threshold to 300 eV. Only metastable hydrogen and carbon atoms were observed. Onset energies for the production of metastable hydrogen atoms were observed at electron impact energies of 22.0 + or - .5 eV, 25.5 + or - .6 eV, 36.7 + or - .6 eV and 66 + or - 3 eV, and at 26.6 + or - .6 eV for the production of metastable carbon atoms. Most of the fragments appear to have been formed in high-lying Rydberg states. The total metastable hydrogen cross section reaches a maximum value of approximately 1 X 10 to the minus 18th power sq cm at 100 eV. At the same energy, the metastable carbon cross section is 2 x 10 to the minus 19th power sq cm
Tape recorder failure investigation
Two end-item tape recorders lost 4:1 mode data recording mode capability at less than half of their 1 6,000-cycle, 4-year operating life. Subsequent life tests on two spare recorders also experienced 4:1 mode data loss at 8,000 and 11,700 cycles. Tear down inspection after completion of the life tests showed that the tape had worn through the alfesil record and reproduce heads. An investigation was initiated to understand the cause of excessive tape head wear and the reasons why the 4:1 mode data rate, low-speed mode is more damaging than the 1:1 mode data rate, high-speed recording mode. The objective was to establish how operating conditions (tape speed, humidity, temperature, stop/start cycles) affects head life with the goal of extending head life on the remaining in-service tape recorders. Another interest was to explain why an earlier vendor life test showed capability beyond 16,000 cycles
Incorporation of excluded volume correlations into Poisson-Boltzmann theory
We investigate the effect of excluded volume interactions on the electrolyte
distribution around a charged macroion. First, we introduce a criterion for
determining when hard-core effects should be taken into account beyond standard
mean field Poisson-Boltzmann (PB) theory. Next, we demonstrate that several
commonly proposed local density functional approaches for excluded volume
interactions cannot be used for this purpose. Instead, we employ a non-local
excess free energy by using a simple constant weight approach. We compare the
ion distribution and osmotic pressure predicted by this theory with Monte Carlo
simulations. They agree very well for weakly developed correlations and give
the correct layering effect for stronger ones. In all investigated cases our
simple weighted density theory yields more realistic results than the standard
PB approach, whereas all local density theories do not improve on the PB
density profiles but on the contrary, deviate even more from the simulation
results.Comment: 23 pages, 7 figures, 1 tabl
Fractionation effects in phase equilibria of polydisperse hard sphere colloids
The equilibrium phase behaviour of hard spheres with size polydispersity is
studied theoretically. We solve numerically the exact phase equilibrium
equations that result from accurate free energy expressions for the fluid and
solid phases, while accounting fully for size fractionation between coexisting
phases. Fluids up to the largest polydispersities that we can study (around
14%) can phase separate by splitting off a solid with a much narrower size
distribution. This shows that experimentally observed terminal polydispersities
above which phase separation no longer occurs must be due to non-equilibrium
effects. We find no evidence of re-entrant melting; instead, sufficiently
compressed solids phase separate into two or more solid phases. Under
appropriate conditions, coexistence of multiple solids with a fluid phase is
also predicted. The solids have smaller polydispersities than the parent phase
as expected, while the reverse is true for the fluid phase, which contains
predominantly smaller particles but also residual amounts of the larger ones.
The properties of the coexisting phases are studied in detail; mean diameter,
polydispersity and volume fraction of the phases all reveal marked
fractionation. We also propose a method for constructing quantities that
optimally distinguish between the coexisting phases, using Principal Component
Analysis in the space of density distributions. We conclude by comparing our
predictions to perturbative theories for near-monodisperse systems and to Monte
Carlo simulations at imposed chemical potential distribution, and find
excellent agreement.Comment: 21 pages, 23 figures, 2 table
Concept for a Large Scalable Space Telescope: In-Space Assembly
We present a conceptual design for a scalable (10-50 meter segmented filled-aperture) space observatory operating at UV-optical-near infrared wavelengths. This telescope is designed for assembly in space by robots, astronauts or a combination of the two, as envisioned in NASA s Vision for Space Exploration. Our operations concept for this-space telescope provides for assembly and check-out in an Earth Moon L2 (EML2) orbit, and transport to a Sun-Earth L2 (SEL2) orbit for science operations and routine servicing, with return to EML2 for major servicing. We have developed and analyzed initial designs for the optical, structural, thermal and attitude control systems for a 30-m aperture space telescope. We further describe how the separate components are packaged for launch by heavy lift vehicle(s) and the approach for the robot assembly of the telescope from these components
A cluster theory for a Janus fluid
Recent Monte Carlo simulations on the Kern and Frenkel model of a Janus fluid
have revealed that in the vapour phase there is the formation of preferred
clusters made up of a well-defined number of particles: the micelles and the
vesicles. A cluster theory is developed to approximate the exact clustering
properties stemming from the simulations. It is shown that the theory is able
to reproduce the micellisation phenomenon.Comment: 27 pages, 8 figures, 6 table
Validation of a New Predictive Risk Model: Measuring the Impact of the Major Modifiable Risks of Death for Patients and Populations
Background: Modifiable risks account for a large fraction of disease and death, but clinicians and patients lack tools to identify high risk populations or compare the possible benefit of different interventions.
Methods: We used data on the distribution of exposure to 12 major behavioral and biometric risk factors inthe US population, mortality rates by cause, and estimates of the proportional hazards of risk factor exposure from published systematic reviews to develop a risk prediction model that estimates an adult\u27s 10 year mortality risk compared to a population with optimum risk factors. We compared predicted risk to observed mortality in 8,241 respondents in NHANES 1988-1994 and NHANES 1999-2004 with linked mortality data up to the end of 2006
Parity forbidden excitations of Sr2CuO2Cl2 revealed by optical third-harmonic spectroscopy
We present the first study of nonlinear optical third harmonic generation in
the strongly correlated charge-transfer insulator Sr2CuO2Cl2. For fundamental
excitation in the near-infrared, the THG spectrum reveals a strongly resonant
response for photon energies near 0.7 eV. Polarization analysis reveals this
novel resonance to be only partially accounted for by three-photon excitation
to the optical charge-transfer exciton, and indicates that an even-parity
excitation at 2 eV, with a_1g symmetry, participates in the third harmonic
susceptibility.Comment: Requires RevTeX v4.0beta
Transport Coefficients for Granular Media from Molecular Dynamics Simulations
Under many conditions, macroscopic grains flow like a fluid; kinetic theory
pred icts continuum equations of motion for this granular fluid. In order to
test the theory, we perform event driven molecular simulations of a
two-dimensional gas of inelastic hard disks, driven by contact with a heat
bath. Even for strong dissipation, high densities, and small numbers of
particles, we find that continuum theory describes the system well. With a bath
that heats the gas homogeneously, strong velocity correlations produce a
slightly smaller energy loss due to inelastic collisions than that predicted by
kinetic theory. With an inhomogeneous heat bath, thermal or velocity gradients
are induced. Determination of the resulting fluxes allows calculation of the
thermal conductivity and shear viscosity, which are compared to the predictions
of granular kinetic theory, and which can be used in continuum modeling of
granular flows. The shear viscosity is close to the prediction of kinetic
theory, while the thermal conductivity can be overestimated by a factor of 2;
in each case, transport is lowered with increasing inelasticity.Comment: 14 pages, 17 figures, 39 references, submitted to PRE feb 199
New avenue to the Parton Distribution Functions: Self-Organizing Maps
Neural network algorithms have been recently applied to construct Parton
Distribution Function (PDF) parametrizations which provide an alternative to
standard global fitting procedures. We propose a technique based on an
interactive neural network algorithm using Self-Organizing Maps (SOMs). SOMs
are a class of clustering algorithms based on competitive learning among
spatially-ordered neurons. Our SOMs are trained on selections of stochastically
generated PDF samples. The selection criterion for every optimization iteration
is based on the features of the clustered PDFs. Our main goal is to provide a
fitting procedure that, at variance with the standard neural network
approaches, allows for an increased control of the systematic bias by enabling
user interaction in the various stages of the process.Comment: 34 pages, 17 figures, minor revisions, 2 figures update
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