MULTICULTURAL MENTOR TEXTS IN 2ND GRADE WRITER’S WORKSHOP

The purpose of this study is to investigate the effects of the utilization of relevant multicultural mentor texts during writer’s workshop instruction in the second-grade classroom. The specific aim is to understand how students relate these diverse texts to their development of literacy skills. This study is grounded in the theoretical frameworks of culturally relevant education and reader response theory. Upon data triangulation analysis, the following themes were identified: 1. Multicultural Literature Promoted Engagement with Literacy, 2. Multicultural Mentor Texts as a Guide for Writing, and 3. Writing as a Social Practice within the Writer’s Workshop Model. Implications regarding the significance of multicultural literature and best practices for elementary writing instruction are also discussed. Ultimately, the research suggests that students benefit from literacy instruction that incorporates multicultural literature and offers opportunities for socialization during writing instruction

Whitney coverings and the tent spaces T1,q(γ)T^{1,q}(\gamma) for the Gaussian measure

We introduce a technique for handling Whitney decompositions in Gaussian harmonic analysis and apply it to the study of Gaussian analogues of the classical tent spaces $T^{1,q}$ of Coifman, Meyer and Stein.Comment: 13 pages, 1 figure. Revised version incorporating referee's comments. To appear in Arkiv for Matemati

Proof of the thermodynamical stability of the E' center in SiO2

The E' center is a paradigmatic radiation-induced defect in SiO2 whose peculiar EPR and hyperfine activity has been known since over 40 years. This center has been traditionally identified with a distorted, positively-charged oxygen vacancy V_O+. However, no direct proof of the stability of this defect has ever been provided, so that its identification is still strongly incomplete. Here we prove directly that distorted V_O+ is metastable and that it satisfies the key requirements for its identification as E', such as thermal and optical response, and activation-deactivation mechanisms.Comment: RevTeX 4 pages, 2 figure

Photoluminescence characterization of aged and regenerated mesoporous silica

n/

Supporting Smart Home Scenarios Using OWL and SWRL Rules

Despite the pervasiveness of IoT domotic devices in the home automation landscape, their potential is still quite under-exploited due to the high heterogeneity and the scarce expressivity of the most commonly adopted scenario programming paradigms. The aim of this study is to show that Semantic Web technologies constitute a viable solution to tackle not only the interoperability issues, but also the overall programming complexity of modern IoT home automation scenarios. For this purpose, we developed a knowledge-based home automation system in which scenarios are the result of logical inferences over the IoT sensors data combined with formalised knowledge. In particular, we describe how the SWRL language can be employed to overcome the limitations of the well-known trigger-action paradigm. Through various experiments in three distinct scenarios, we demonstrated the feasibility of the proposed approach and its applicability in a standardised and validated context such as SARE

The art of rhinoplasty: researching technical and cultural foundations of western world rhinosurgery, from the middle ages to the renaissance

The analysis of the written sources allowed to follow the gradual development of every new technique in the field of rhinoplasty but also to understand the value of this surgery in those ancient times, highlighting a deep connection between traumatologic surgery of the nose and the development of modern ‘‘aesthetic and reconstructive’’ Rhinosurgery. Specifically, we analyzed the techniques described by less known surgeons to emphasize their cultural and surgical value. As a matter of fact, the descriptions offered by these authors clearly show the importance of rhinoplasty as a cardinal and autonomous practice since Antiquity, also clarifying the persistence and development of specific techniques for this surgical practice in the History of medicine. In the manuscript, the contributions of the Italian surgeons, such as Brancas and Vianeos families, are highlighted, demonstrating their influence on the progress of this surgical specialty in the Early Modern Age. Finally, we deepen the description of Gaspare Tagliacozzi’s work, pointing out the topics and controversial debates arising from his techniques and innovations in ‘‘rhinosurgery’’ and also in the field of tissue transplantation, laying the foundations of modern Plastic Surgery. Level of Evidence V This journal requires that authors assign a level of evidence to each article. For a full description of these Evidence-Based Medicine Ratings, please refer to Table of Contents or online Instructions to Authors www.springer.com/00266

Photobioreactors as a Dynamic Shading System Conceived for an Outdoor Workspace of the State Library of Queensland in Brisbane: Study of Daylighting Performances

In the field of responsive shading systems, the use of photobioreactors (PBRs) containing microalgae seems to be a promising technology. Within this framework, this paper presents a case study where a PBR was specifically conceived as a shading system for an external workspace located on an open terrace of the State Library of Queensland (SLQ) in Brisbane. The proposed shading system makes use of PBRs as translucent screening elements, capable of regulating natural light to provide adequate visual comfort for a multi-purpose workspace, despite exposure of the site to direct sunlight and fluctuating weather conditions. The microalgae (Scenedesmus Obliquus) cultivated within the shading elements contribute to improving the environment by bio-sequestrating CO2 and producing oxygen. They are also a valuable raw material containing bioactive compounds with various applications including nutraceutical products, livestock feed, and biofuel synthesis. In addition, their green pigmentation is visually engaging and allows for the filtration of solar radiation. The paper focuses on analyzing the daylight performance in the outdoor workplace under the PBR shade. The biomass density of the PBR is adjustable across a wide range of light transmittances (10%-80%) to counter the highly variable outdoor conditions. For different Tv values, illuminance values were calculated using the simulation tool DIVA-for-Rhino and then analyzed as both point-in-time illuminance in June, September and December, and through climate-based daylight metrics such as the Daylight Autonomy and the Useful Daylight Illuminance. As a further step, the daylighting performances were compared to two other climates (Turin, Italy, and Dubai, United Arab Emirates), to verify which setting of the PBR may be suitable for different boundary conditions, thus making the system more widely applicable. The results in Brisbane showed that for clear sky conditions, higher levels of biomass saturation are needed (Tv < 20%) to remain in the 300-3000 lx 'optimal' illuminance comfort range, with lower concentrations (Tv < 30%) to remain within the 300-6000 lx 'acceptable' illuminance comfort range. Differently, in overcast sky conditions, the optimal range of illuminance is easily obtained with reduced levels of biomass saturation (Tv < 80%)

Formation of citrazinic acid ions and their contribution to optical and magnetic features of carbon nanodots: A combined experimental and computational approach

The molecular model is one of the most appealing to explain the peculiar optical properties of Carbon nanodots (CNDs) and was proven to be successful for the bottom up synthesis, where a few molecules were recognized. Among the others, citrazinic acid is relevant for the synthesis of citric acid-based CNDs. Here we report a combined experimental and computational approach to discuss the formation of different protonated and deprotonated species of citrazinic acid and their contribution to vibrational and magnetic spectra. By computing the free energy formation in water solution, we selected the most favoured species and we retrieved their presence in the experimental surface enhanced Raman spectra. As well, the chemical shifts are discussed in terms of tautomers and rotamers of most favoured species. The expected formation of protonated and de-protonated citrazinic acid ions under extreme pH conditions was proven by evaluating specific interactions with H2 SO4 and NaOH molecules. The reported results confirm that the presence of citrazinic acid and its ionic forms should be considered in the interpretation of the spectroscopic features of CNDs

Integrating sol-gel and carbon dots chemistry for the fabrication of fluorescent hybrid organic-inorganic films

Highly fluorescent blue and green-emitting carbon dots have been designed to be integrated into sol-gel processing of hybrid organic-inorganic materials through surface modification with an organosilane, 3-(aminopropyl)triethoxysilane (APTES). The carbon dots have been synthesised using citric acid and urea as precursors; the intense fluorescence exhibited by the nanoparticles, among the highest reported in the scientific literature, has been stabilised against quenching by APTES. When the modification is carried out in an aqueous solution, it leads to the formation of silica around the C-dots and an increase of luminescence, but also to the formation of large clusters which do not allow the deposition of optically transparent films. On the contrary, when the C-dots are modified in ethanol, the APTES improves the stability in the precursor sol even if any passivating thin silica shell does not form. Hybrid films containing APTES-functionalized C-dots are transparent with no traces of C-dots aggregation and show an intense luminescence in the blue and green range

Outcomes in Hybrid Breast Reconstruction: A Systematic Review

Background and Objectives: Lipofilling is a commonly performed procedure worldwide for breast augmentation and correction of breast contour deformities. In breast reconstruction, fat grafting has been used as a single reconstructive technique, as well as in combination with other procedures. The aim of the present study is to systematically review available studies in the literature describing the combination of implant-based breast reconstruction and fat grafting, focusing on safety, complications rate, surgical sessions needed to reach a satisfying reconstruction, and patient-reported outcomes. Materials and Methods: We adhered to the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) throughout the whole review protocol. A systematic review of the literature up to April 2022 was performed using Medline, Embase, and Cochrane Library databases. Only studies dealing with implant-based breast reconstruction combined with fat grafting were included. Results: We screened 292 articles by title and abstract. Only 48 articles were assessed for full-text eligibility, and among those, 12 studies were eventually selected. We included a total of 753 breast reconstructions in 585 patients undergoing mastectomy or demolitive breast surgeries other than mastectomy (quadrantectomy, segmentectomy, or lumpectomy) due to breast cancer or genetic predisposition to breast cancer. Overall, the number of complications was 60 (7.9%). The mean volume of fat grafting per breast per session ranged from 59 to 313 mL. The mean number of lipofilling sessions per breast ranged from 1.3 to 3.2. Conclusions: Hybrid breast reconstruction shows similar short-term complications to standard implant-based reconstruction but with the potential to significantly decrease the risk of long-term complications. Moreover, patient satisfaction was achieved with a reasonably low number of lipofilling sessions (1.7 on average)