Polymer electrolyte membranes and process for the production thereof

The process for the production of a polymer electrolyte membrane, comprises the successive steps of: preparing a mixed solution of a Room Temperature Ionic Liquid (RTIL), at least one alkaline metal salt and a photosensitive hydrogen abstracting component at a temperature in the range 20 to 70 °C, wherein the RTIL is a compound consisting of at least one organic cation and at least one organic or inorganic anion; adding to the solution a polymeric material at a temperature in the range of 20-70 °C; blending the solution added with the polymeric material at a temperature in the range of 70-140 °C to get a uniform mixture; pressing the mixture between two sheets at a temperature in the range of 60 - 150 °C and a pressure in the range of 20 - 80 bar, so that a film is formed; and exposing the film to UV light, so that the polymeric material of the film is cross-linked and the polymer electrolyte membrane is obtained

NMR Self Diffusion and Relaxation Time Measurements for Poly (vinylidene fluoride) (PVDF) Based Polymer Gel Electrolytes Containing LiBF4 and Propylene Carbonate

Polymer gel electrolytes (PGEs) have been prepared using lithium tetrafluoroborate (LiBF4), propylene carbonate (PC) and poly (vinylidene fluoride) (PVDF). Self diffusion coefficients have been measured using pulse field gradient nuclear magnetic resonance (PFG-NMR) for the lithium cation, BF4 anion and solvent molecules using 7Li, 19F and 1H nuclei, respectively. It was found that lithium ion diffusion was slow compared to the much larger fluorinated BF4 anion, which is attributed to a large solvation shell around the lithium ions. The 7Li and 1H diffusion measurements also exhibited two unique environments for the diffusive species. The measurement of NMR transverse relaxation times has confirmed the presence of lithium ions in multiple phases as shown by the diffusion measurements