Geochemical characteristics and implications of shale gas from the Longmaxi Formation, Sichuan Basin, China

AbstractGas geochemical analysis was conducted on the shale gas from the Longmaxi Formation in the Weiyuan-Changning areas, Sichuan Basin, China. Chemical composition was measured using an integrated method of gas chromatography combined with mass spectrometry. The results show that the Longmaxi shale gas, after hydraulic fracturing, is primarily dominated by methane (94.0%–98.6%) with low humidity (0.3%–0.6%) and minor non-hydrocarbon gasses which are primarily comprised of CO2, N2, as well as trace He. δ13CCO2 = −2.5‰−6.0‰3He/4He = 0.01–0.03Ra.The shale gas in the Weiyuan and Changning areas display carbon isotopes reversal pattern with a carbon number (δ13C1 > δ13C2) and distinct carbon isotopic composition. The shale gas from the Weiyuan pilot has heavier carbon isotopic compositions for methane (δ13C1: from −34.5‰ to −36.8‰), ethane (δ13C2: −37.6‰ to −41.9‰), and CO2 (δ13CCO2: −4.5‰ to −6.0‰) than those in the Changning pilot (δ13C1: −27.2‰ to −27.3‰, δ13C2: −33.7‰ to −34.1‰, δ13CCO2: −2.5‰ to −4.6‰). The Longmaxi shale was thermally high and the organic matter was in over mature stage with good sealing conditions. The shale gas, after hydraulic fracturing, could possibly originate from the thermal decomposition of kerogen and the secondary cracking of liquid hydrocarbons which caused the reversal pattern of carbon isotopes. Some CO2 could be derived from the decomposition of carbonate. The difference in carbon isotopes between the Weiyuan and Changning areas could be derived from the different mixing proportion of gas from the secondary cracking of liquid hydrocarbons caused by specific geological and geochemical conditions

Using an extended LMDI model to explore techno-economic drivers of energy-related industrial CO2 emission changes:A case study for Shanghai (China)

Although investment and R&D activities can exert significant effects on energy-related industrial CO2 emissions (EICE), related factors have not been fairly uncovered in the existing index decomposition studies. This paper extends the previous logarithmic mean Divisia index (LMDI) decomposition model by introducing three novel factors (R&D intensity, investment intensity, and R&D efficiency). The extended model not only considers the conventional drivers of EICE, but also reflects the microeconomic effects of investment and R&D behaviors on EICE. Furthermore, taking Shanghai as an example, which is the economic center and leading CO2 emitter in China, we use the extended model to decompose and explain EICE changes. Also, we incorporate renewable energy sources into the proposed model to carry out an alternative decomposition analysis at Shanghais entire industrial level. The results show that among conventional (macroeconomic) factors, expanding output scale is mainly responsible for the increase in EICE, and industrial structure adjustment is the most significant factor in mitigating EICE. Regardless of renewable energy sources, the emission-reduction effect of energy intensity focused on by the Chinese government is less than the expected due to the rebound effect, but the introduction of renewable energy sources intensifies its mitigating effect, partly resulting from the transmission from the abating effect of industrial structure adjustment. The effect of energy structure is the weakest. Although all the three novel factors exert significant effects on EICE, they are more sensitive to policy interventions than conventional factors. R&D intensity presents an obvious mitigating effect, while investment intensity and R&D efficiency display an overall promotion effect with some volatility. The introduction of renewable energy sources intensifies the promotion effect of R&D efficiency as a result of the "green paradox" effect. Finally, we propose that CO2 mitigation efforts should be made by considering both macroeconomic and microeconomic factors in order to achieve a desirable emission-reduction effect

Adjusting aggregation modes and photophysical and photovoltaic properties of diketopyrrolopyrrole-based small molecules by introducing B←N bonds

The packing mode of small-molecular semiconductors in thin films is an important factor that controls the performance of their optoelectronic devices. Designing and changing the packing mode by molecular engineering is challenging. Three structurally related diketopyrrolopyrrole (DPP)-based compounds were synthesized to study the effect of replacing C−C bonds by isoelectronic dipolar B←N bonds. By replacing one of the bridging C−C bonds on the peripheral fluorene units of the DPP molecules by a coordinative B←N bond and changing the B←N bond orientation, the optical absorption, fluorescence, and excited-state lifetime of the compounds can be tuned. The substitution alters the preferential aggregation of the molecules in the solid state from H-type (for C−C) to J-type (for B←N). Introducing B←N bonds thus provides a subtle way of controlling the packing mode. The photovoltaic properties of the compounds were evaluated in bulk heterojunctions with a fullerene acceptor and showed moderate performance as a consequence of suboptimal morphologies, bimolecular recombination, and triplet-state formation

Electrooxidation of Hydrogen on Ni-Organic Metal Complex Catalysts in Acidic Media for PEMFCs

Novel organic metal complexes with N2O2 coordination structure which showed high hydrogen oxidation reaction were synthesized. The catalytic activity was found to strongly depend on the heat-treatment temperature and the structural properties

Application of Metal Oxide Heterostructures in Arsenic Removal from Contaminated Water

<p> It has become one of the major environmental problems for people worldwide to be exposed to high arsenic concentrations through contaminated drinking water, and even the long-term intake of small doses of arsenic has a carcinogenic effect. As an efficient and economic approach for the purification of arsenic-containing water, the adsorbents in adsorption processes have been widely studied. Among a variety of adsorbents reported, the metal oxide heterostructures with high surface area and specific affinity for arsenic adsorption from aqueous systems have demonstrated a promising performance in practical applications. This review paper aims to summarize briefly the metal oxide heterostructures in arsenic removal from contaminated water, so as to provide efficient, economic, and robust solutions for water purification.</p

Application of “mosiac sign” on T2-WI in predicting the consistency of pituitary neuroendocrine tumors

PurposeTumor consistency is important for pituitary neuroendocrine tumors (PitNETs) resection to improve surgical outcomes. In this study, we evaluated the T2-WI of PitNETs and defined a specific T2-WI signaling manifestation, the “Mosaic sign,” to predict tumor consistency and resection of PitNETs.DesignA retrospective review of MRI and tumor histology of 137 consecutive patients who underwent endoscopic endonasal resection for PitNETs was performed.MethodsThe “Mosaic sign” was defined by the ratio of the tumor itself T2-WI signals, and characterized by multiple intratumor hyperintense dots. The degree of tumor resection was an assessment by postoperative MRI examination. The presence of the “Mosaic sign” was compared with patients' basic information, tumor consistency, tumor pathological staining, and surgical result. To determine whether the presence or absence of “Mosaic sign” could predict tumor consistency and guide surgical resection of tumors.ResultsStatistical analysis showed that the consistency of the tumor and the degree of resection were correlated with the “Mosaic sign”. In the 137 cases of T2-WI, 43 had “Mosaic sign”, 39 cases had soft tumor consistency, and 4 were classified as fibrous, of which 42 were completely resected and 1 was subtotal resected. Of the 94 patients without “Mosaic sign”, the consistency of tumor of 54 cases were classified as soft, the remaining 40 cases were fibrous, 80 cases were completely resected, and 14 cases were subtotal resected. Postoperative cerebrospinal fluid leakage occurred in 1 patient. The number of corticotroph adenomas in the group of “Mosaic sign” was higher, with the statistical difference between the two groups (P = 0.0343).ConclusionsThe presence of the “Mosaic sign” in T2-WI may provide preoperative information for pituitary adenomas consistency and effectively guide surgical approaches

Recurrent renal secondary hyperparathyroidism caused by supernumerary mediastinal parathyroid gland and parathyromatosis: A case report

BackgroundSurgical parathyroidectomy (PTX) is necessary for patients with severe and progressive secondary hyperparathyroidism (SHPT) refractory to medical treatment. Recurrence of SHPT after PTX is a serious clinical problem. Both supernumerary mediastinal parathyroid gland and parathyromatosis are the rare causes of recurrent renal SHPT. We report a rare case of recurrent renal SHPT due to supernumerary mediastinal parathyroid gland and parathyromatosis.Case presentationA 53-year-old man underwent total parathyroidectomy with autotransplantation due to the drug-refractory SHPT 17 years ago. In the last 11 months, the patient experienced symptoms including bone pain and skin itch, and the serum intact parathyroid hormone (iPTH) level elevated to 1,587 pg/ml. Ultrasound detected two hypoechoic lesions located at the dorsal area of right lobe of the thyroid gland, and both lesions presented as characteristics of hyperparathyroidism in contrast-enhanced ultrasound. 99mTc-MIBI/SPECT detected a nodule in the mediastinum. A reoperation involved a cervicotomy for excising parathyromatosis lesions and the surrounding tissue and a thoracoscopic surgery for resecting a mediastinal parathyroid gland. According to a histological examination, two lesions behind the right thyroid lobe and one lesion in the central region had been defined as parathyromatosis. A nodule in the mediastinum was consistent with hyperplastic parathyroid. The patient remained well for 10 months with alleviated symptoms and stabilized iPTH levels in the range of 123–201 pg/ml.ConclusionAlthough rare, recurrent SHPT may be caused by a coexistence of both supernumerary parathyroid glands and parathyromatosis, which should receive more attention. The combination of imaging modalities is important for reoperative locations of parathyroid lesions. To successfully treat parathyromatosis, all the lesions and the surrounding tissue must be excised. Thoracoscopic surgery is a reliable and safe approach for the resection of ectopic mediastinal parathyroid glands

Original Article Benefit of a 360-degree horizontal turn following premedication with simethicone on image quality during gastroendoscopy: a randomized controlled trial

Abstract: Objectives: To investigate whether a 360-degree horizontal turn after oral premedication with simethicone improves the mucosal visibility during gastroendoscopic examination, and to determine the proper time to turn over the patient. Methods: This study involved 993 patients scheduled for gastroendoscopy. Just before gastroendoscopy，after oral premedication with simethicone, patients were randomly assigned to three groups：in Group A, patients waited for 20 min before gastroendoscopy; in Group B, patients were separately waited for 5/10/15/20 min and were then turned 360 degrees just before gastroendoscopy; in Group C, patients were immediately turned 360 degrees and then separately waited for 5/10/15/20 min before examination. The sum of the gastric mucosal visibility scores (MVS) was calculated after the examination. The MVS and proportion of images with higher visibility scores for the mucosal surface. Lower scores indicate better visibility of the mucosal surface. Results: In Groups B and Groups C, when waiting time more than 10 min had lower mean total MVS than Group A. The MVS of four subgroups of Group B were not different from those of Group C. Conclusion: Oral premedication with simethicone and immediately make a body posture change (turning over 360 degrees) then waiting for 10min can increase the image quality during gastroendoscopy and effectively decrease the premedication time

Electron Acceptors With a Truxene Core and Perylene Diimide Branches for Organic Solar Cells: The Effect of Ring-Fusion

In this work, a star-shaped planar acceptor named FTr-3PDI was synthesized via ring-fusion between truxene core and three bay-linked perylene diimide (PDI) branches. Compared to the unfused non-planar acceptor Tr-3PDI, FTr-3PDI exhibits better structural rigidity and planarity, as well as more effective conjugation between truxene core and PDI branches. As a result, FTr-3PDI shows up-shifted energy levels, enhanced light absorption coefficient, increased electron mobility, and more favorable phase separation morphology in bulk-heterojunction (BHJ) blend films as compared to Tr-3PDI. Consequently, FTr-3PDI afforded higher power conversion efficiency (PCE) in BHJ solar cells when blended with a polymer donor PTB7-Th. This work demonstrates that ring-fusion is a promising molecular design strategy to combine the merits of truxene and PDI for non-fullerene acceptors used in organic solar cells

A Higher Correlation of HCV Core Antigen with CD4+ T Cell Counts Compared with HCV RNA in HCV/HIV-1 Coinfected Patients

Development of HCV infection is typically followed by chronic hepatitis C (CHC) in most patients, while spontaneous HCV viral clearance (SVC) occurs in only a minority of subjects. Compared with the widespread application of HCV RNA testing by quantitative RT-PCR technique, HCV core antigen detection may be an alternative indicator in the diagnosis of hepatitis C virus infections and in monitoring the status of infectious individuals. However, the correlation and differences between these two indicators in HCV infection need more investigation, especially in patients coinfected by HIV-1. In this study, a total of 354 anti-HCV and/or anti-HIV serum positive residents from a village of central China were enrolled. Besides HCV-related hepatopathic variables including clinical status, ALT, AST, anti-HCV Abs, as well as the altered CD4+/CD8+ T cell counts, HCV core antigen and HCV viral load were also measured. The concentration of serum HCV core antigen was highly correlated with level of HCV RNA in CHC patients with or without HIV-1 coinfection. Of note, HCV core antigen concentration was negatively correlated with CD4+ T cell count, while no correlation was found between HCV RNA level and CD4+ T cell count. Our findings suggested that quantitative detection of plasma HCV core antigen may be an alternative indicator of HCV RNA qPCR assay when evaluating the association between HCV replication and host immune status in HCV/HIV-1 coinfected patients