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Multi-Biomarker Analysis for Identifying Organic Matter Sources in Small Mountainous River Watersheds: A Case Study of the Yuba River Watershed
Organic matter in soils and sediments derives from a mixture of biological origins, often making it difficult to determine inputs from individual sources. Complicating the determination of source inputs to soil and sedimentary organic matter (OM) is the fact that physical and microbial processes have likely modified the initial composition of these sources. This study focused on identifying the composition of watershed-derived OM to better understand inputs to inland waters and improve our ability to resolve between terrigenous and aquatic sources in downstream systems, such as estuaries and coasts. We surveyed OM sources from the Yuba River watershed in northern California to identify specific biomarkers that represent aquatic and terrigenous OM sources. Multiple classes of organic proxiesâincluding sterols, fatty acids (FA), lignin phenols and stable carbon and nitrogen isotope values (ÎŽ 13C, ÎŽ15N)âwere measured in soils, vegetation, charcoal, and freshwater plankton to characterize representative source endmembers. Sterolsâ including 27-nor-24-cholesta-5,22-dien-3ÎČ-ol, cholesta-5,22-dien-3ÎČ-ol, 24-methylcholesta-5,22-dien-3ÎČ-ol and cholesta-5-en-3ÎČ-ol, and positive ÎŽ 15N valuesâwere associated with aquatic OM (plankton, suspended particulate OM), whereas lignin phenols, long chain FA, and diacids characterized terrigenous sources (soils, charcoal, vegetation). Trends in organic carbon and biomarker signatures in soil samples showed a response to environmental disturbance (i.e., mining, agriculture) through an inverse relationship between OM content and land use. Results from this study demonstrate the utility of multi-biomarker studies for distinguishing between OM from different sources and land uses, offering new insights for biogeochemical studies in aquatic systems
Photon Self-Induced Spin to Orbital Conversion in TGG crystal at high laser power
In this paper, we present experimental evidence of a newly discovered
third-order nonlinear optical process Self-Induced Spin-to-Orbital Conversion
(SISTOC) of the photon angular momentum. This effect is the physical mechanism
at the origin of the depolarization of very intense laser beams propagating in
isotropic materials. The SISTOC process, like self-focusing, is triggered by
laser heating leading to a radial temperature gradient in the medium. In this
work we tested the occurrence of SISTOC in a terbium gallium garnet (TGG) rod
for an impinging laser power of about 100~W. To study the SISTOC process we
used different techniques: polarization analysis, interferometry and tomography
of the photon orbital angular momentum. Our results confirm, in particular,
that the apparent depolarization of the beam is due to the occurrence of
maximal entanglement between the spin and orbital angular momentum of the
photons undergoing the SISTOC process. This explanation of the true nature of
the depolarization mechanism could be of some help in finding novel methods to
reduce or to compensate for this usually unwanted depolarization effect in all
cases where very high laser power and good beam quality are required.Comment: 6 pages, 10 figures, submitte
Matter-wave laser Interferometric Gravitation Antenna (MIGA): New perspectives for fundamental physics and geosciences
The MIGA project aims at demonstrating precision measurements of gravity with
cold atom sensors in a large scale instrument and at studying the associated
applications in geosciences and fundamental physics. The first stage of the
project (2013-2018) will consist in building a 300-meter long optical cavity to
interrogate atom interferometers and will be based at the low noise underground
laboratory LSBB in Rustrel, France. The second stage of the project (2018-2023)
will be dedicated to science runs and data analyses in order to probe the
spatio-temporal structure of the local gravity field of the LSBB region, a site
of high hydrological interest. MIGA will also assess future potential
applications of atom interferometry to gravitational wave detection in the
frequency band Hz hardly covered by future long baseline optical
interferometers. This paper presents the main objectives of the project, the
status of the construction of the instrument and the motivation for the
applications of MIGA in geosciences. Important results on new atom
interferometry techniques developed at SYRTE in the context of MIGA and paving
the way to precision gravity measurements are also reported.Comment: Proceedings of the 50th Rencontres de Moriond "100 years after GR",
La Thuile (Italy), 21-28 March 2015 - 10 pages, 5 figures, 23 references
version2: added references, corrected typo
Performance of a thermally deformable mirror for correction of low-order aberrations in laser beams
The thermally deformable mirror is a device aiming at correcting beam-wavefront distortions for applications where classical mechanical methods are precluded by noise considerations, as in advanced gravitational wave interferometric detectors. This moderately low-cost technology can be easily implemented and controlled thanks to the good reproducibility of the actuation. By using a flexible printed circuit board technology, we demonstrate experimentally that a device of 61 actuators in thermal contact with the back surface of a high-reflective mirror is able to correct the low-order aberrations of a laser beam at 1064 nm and could be used to optimize the mode matching into Fabry-Perot cavities
Use of ESI-FTICR-MS to Characterize Dissolved Organic Matter in Headwater Streams Draining Forest-Dominated and Pasture-Dominated Watersheds
Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS) has proven to be a powerful technique revealing complexity and diversity of natural DOM molecules, but its application to DOM analysis in grazing-impacted agricultural systems remains scarce. In the present study, we presented a case study of using ESI-FTICR-MS in analyzing DOM from four headwater streams draining forest-or pasture-dominated watersheds in Virginia, USA. In all samples, most formulas were CHO compounds (71.8-87.9%), with other molecular series (CHOS, CHON, CHONS, and CHOP (N, S)) accounting for only minor fractions. All samples were dominated by molecules falling in the lignin-like region (H/C = 0.7-1.5, O/C = 0.1-0.67), suggesting the predominance of allochthonous, terrestrial plant-derived DOM. Relative to the two pasture streams, DOM formulas in the two forest streams were more similar, based on Jaccard similarity coefficients and nonmetric multidimensional scaling calculated from Bray-Curtis distance. Formulas from the pasture streams were characterized by lower proportions of aromatic formulas and lower unsaturation, suggesting that the allochthonous versus autochthonous contributions of organic matter to streams were modified by pasture land use. The number of condensed aromatic structures (CAS) was higher for the forest streams, which is possibly due to the controlled burning in the forest-dominated watersheds and suggests that black carbon was mobilized from soils to streams. During 15-day biodegradation experiments, DOM from the two pasture streams was altered to a greater extent than DOM from the forest streams, with formulas with H/C and O/C ranges similar to protein (H/C = 1.5-2.2, O/C = 0.3-0.67), lipid (H/C = 1.5-2.0, O/C = 0-0.3), and unsaturated hydrocarbon (H/C = 0.7-1.5, O/C = 0-0.1) being the most bioreactive groups. Aromatic compound formulas including CAS were preferentially removed during combined light+bacterial incubations, supporting the contention that black carbon is labile to light alterations. Collectively, our data demonstrate that head-water DOM composition contains integrative information on watershed sources and processes, and the application of ESI-FTICR-MS technique offers additional insights into compound composition and reactivity unrevealed by fluorescence and stable carbon isotopic measurements
Low noise amplication of an optically carried microwave signal: application to atom interferometry
In this paper, we report a new scheme to amplify a microwave signal carried
on a laser light at =852nm. The amplification is done via a
semiconductor tapered amplifier and this scheme is used to drive stimulated
Raman transitions in an atom interferometer. Sideband generation in the
amplifier, due to self-phase and amplitude modulation, is investigated and
characterized. We also demonstrate that the amplifier does not induce any
significant phase-noise on the beating signal. Finally, the degradation of the
performances of the interferometer due to the amplification process is shown to
be negligible
Carbon Budget of Tidal Wetlands, Estuaries, and Shelf Waters of Eastern North America
Carbon cycling in the coastal zone affects global carbon budgets and is critical for understanding the urgent issues of hypoxia, acidification, and tidal wetland loss. However, there are no regional carbon budgets spanning the three main ecosystems in coastal waters: tidal wetlands, estuaries, and shelf waters. Here we construct such a budget for eastern North America using historical data, empirical models, remote sensing algorithms, and processâbased models. Considering the net fluxes of total carbon at the domain boundaries, 59 ± 12% (± 2 standard errors) of the carbon entering is from rivers and 41 ± 12% is from the atmosphere, while 80 ± 9% of the carbon leaving is exported to the open ocean and 20 ± 9% is buried. Net lateral carbon transfers between the three main ecosystem types are comparable to fluxes at the domain boundaries. Each ecosystem type contributes substantially to exchange with the atmosphere, with CO2 uptake split evenly between tidal wetlands and shelf waters, and estuarine CO2 outgassing offsetting half of the uptake. Similarly, burial is about equal in tidal wetlands and shelf waters, while estuaries play a smaller but still substantial role. The importance of tidal wetlands and estuaries in the overall budget is remarkable given that they, respectively, make up only 2.4 and 8.9% of the study domain area. This study shows that coastal carbon budgets should explicitly include tidal wetlands, estuaries, shelf waters, and the linkages between them; ignoring any of them may produce a biased picture of coastal carbon cycling
Effluent Organic Nitrogen (EON): Bioavailability and Photochemical and Salinity-Mediated Release
The goal of this study was to investigate three potential ways that the soluble organic nitrogen (N) fraction of wastewater treatment plant (WWTP) effluents, termed effluent organic N (EON), could contribute to coastal eutrophication - direct biological removal, photochemical release of labile compounds, and salinity-mediated release of ammonium (NH4+). Effluents from two WWTPs were used in the experiments. For the bioassays, EON was added to water from four salinities (âŒ0 to 30) collected from the James River (VA) in August 2008, and then concentrations of N and phosphorus compounds were measured periodically over 48 h. Bioassay results, based on changes in DON concentrations, indicate that some fraction of the EON was removed and that the degree of EON removal varied between effluents and with salinity. Further, we caution that bioassay results should be interpreted within a broad context of detailed information on chemical characterization. EON from both WWTPs was also photoreactive, with labile NH4+ and dissolved primary amines released during exposure to sunlight. We also present the first data that demonstrate that when EON is exposed to higher salinities, increasing amounts of NH4+ are released, further facilitating EON use as effluent transits from freshwater through estuaries to the coast
Sorption of colored vs. noncolored organic matter by tidal marsh soils
Tidal marshes are significant sources of colored (or chromophoric) dissolved organic carbon (CDOC) to adjacent waters and, as a result, contribute substantially to their optical complexity and ultimately affect their water quality. Despite this, our mechanistic understanding of the processes that regulate the exchange and transformation of CDOC at the tidal marshâestuarine interface remains limited. We hypothesized that tidal marsh soils regulate this exchange and transformation subject to soil mineralogy and salinity environment. To test this hypothesis, we generated initial mass sorption isotherms of CDOC and noncolored dissolved organic carbon (NCDOC) using anaerobic batch incubations of Great Dismal Swamp DOC with four tidal wetland soils, representing a range of organic carbon content (1.77â±â0.12â% to 36.2â±â2.2â%) and across four salinity treatments (0, 10, 20, and 35). CDOC sorption followed Langmuir isotherms that were similar in shape to those of total DOC, but with greater maximum sorption capacity and lower binding affinity. Like isotherms of total DOC, CDOC maximum sorption capacity increased and binding affinity decreased with greater salinity. Initial natively adsorbed colored organic carbon was low and increased with soil organic content. In contrast, NCDOC desorbed under all conditions with desorption increasing linearly with initial CDOC concentration. This suggests that for our test solutions CDOC displaced NCDOC on tidal marsh soils. Parallel factor analysis of 3-D excitation emission matrices and specific ultraviolet absorbance measurements suggested that CDOC sorption was driven primarily by the exchange of highly aromatic humic-like CDOC. Taken together, these results suggest that tidal marsh soils regulate export and composition of CDOC depending on the complex interplay between soil mineralogy, water salinity, and CDOC vs. NCDOC composition.</p
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