Kinetic approach to the cluster liquid-gas transition

The liquid-gas transition in free atomic clusters is investigated theoretically based on simple unimolecular rate theories and assuming sequential evaporations. A kinetic Monte Carlo scheme is used to compute the time-dependent properties of clusters undergoing multiple dissociations, and two possible definitions of the boiling point are proposed, relying on the cluster or gas temperature. This numerical approach is supported by molecular dynamics simulations of clusters made of sodium atoms or C60 molecules, as well as simplified rate equation

Exact time-reversal focusing of acoustic and quantum excitations in open cavities: The perfect inverse filter

The time-reversal mirror (TRM) prescribes the reverse playback of a signal to focalize an acoustic excitation as a Loschmidt echo. In the quantum domain, the perfect inverse filter (PIF) processes this signal to ensure an exact reversion provided that the excitation originated outside the cavity delimited by the transducers. We show that PIF takes a simple form when the initial excitation is created inside this cavity. This also applies to the acoustical case, where it corrects the TRM and improves the design of an acoustic bazooka. We solve an open chaotic cavity modeling a quantum bazooka and a simple model for a Helmholtz resonator, showing that the PIF becomes decisive to compensate the group velocities involved in a highly localized excitation and to achieve subwavelength resolution.Comment: 6 pages, 2 figure

Tuning laser-induced bandgaps in graphene

Could a laser field lead to the much sought-after tunable bandgaps in graphene? By using Floquet theory combined with Green's functions techniques, we predict that a laser field in the mid-infrared range can produce observable bandgaps in the electronic structure of graphene. Furthermore, we show how they can be tuned by using the laser polarization. Our results could serve as a guidance to design opto-electronic nano-devices.Comment: 4 pages, 3 figures, to appear in Applied Physics Letter

Non-perturbative laser effects on the electrical properties of graphene nanoribbons

The use of Floquet theory combined with a realistic description of the electronic structure of illuminated graphene and graphene nanoribbons is developed to assess the emergence of non-adiabatic and non-perturbative effects on the electronic properties. Here, we introduce an efficient computational scheme and illustrate its use by applying it to graphene nanoribbons in the presence of both linear and circular polarization. The interplay between confinement due to the finite sample size and laser-induced transitions is shown to lead to sharp features on the average conductance and density of states. Particular emphasis is given to the emergence of the bulk limit response.Comment: 14 pages, 8 figures, to appear in J. Phys.: Condens. Matter, special issue on "Ultrafast and nonlinear optics in carbon nanomaterials

Laser-induced effects on the electronic features of graphene nanoribbons

We study the interplay between lateral confinement and photon-induced processes on the electronic properties of illuminated graphene nanoribbons. We find that by tuning the device setup (edges geometries, ribbon width and polarization direction), a laser with frequency {\Omega} may either not affect the electronic structure, or induce bandgaps or depletions at \hbar {\Omega}/2, and/or at other energies not commensurate with half the photon energy. Similar features are also observed in the dc conductance, suggesting the use of the polarization direction to switch on and off the graphene device. Our results could guide the design of novel types of optoelectronic nano-devices.Comment: 4 pages, 3 figure

A Train-on-Target Strategy for Multilingual Spoken Language Understanding

[EN] There are two main strategies to adapt a Spoken Language Understanding system to deal with languages different from the original (source) language: test-on-source and train-on-target. In the train-ontarget approach, a new understanding model is trained in the target language, which is the language in which the test utterances are pronounced. To do this, a segmented and semantically labeled training set for each new language is needed. In this work, we use several general-purpose translators to obtain the translation of the training set and we apply an alignment process to automatically segment the training sentences. We have applied this train-on-target approach to estimate the understanding module of a Spoken Dialog System for the DIHANA task, which consists of an information system about train timetables and fares in Spanish. We present an evaluation of our train-on-target multilingual approach for two target languages, French and EnglishThis work has been partially funded by the project ASLP-MULAN: Audio, Speech and Language Processing for Multimedia Analytics (MEC TIN2014-54288-C4-3-R).García-Granada, F.; Segarra Soriano, E.; Millán, C.; Sanchís Arnal, E.; Hurtado Oliver, LF. (2016). A Train-on-Target Strategy for Multilingual Spoken Language Understanding. Lecture Notes in Computer Science. 10077:224-233. https://doi.org/10.1007/978-3-319-49169-1_22S22423310077Benedí, J.M., Lleida, E., Varona, A., Castro, M.J., Galiano, I., Justo, R., López de Letona, I., Miguel, A.: Design and acquisition of a telephone spontaneous speech dialogue corpus in Spanish: DIHANA. In: LREC 2006, pp. 1636–1639 (2006)Calvo, M., Hurtado, L.-F., García, F., Sanchís, E.: A Multilingual SLU system based on semantic decoding of graphs of words. In: Torre Toledano, D., Ortega Giménez, A., Teixeira, A., González Rodríguez, J., Hernández Gómez, L., San Segundo Hernández, R., Ramos Castro, D. (eds.) IberSPEECH 2012. CCIS, vol. 328, pp. 158–167. Springer, Heidelberg (2012). doi: 10.1007/978-3-642-35292-8_17Calvo, M., Hurtado, L.F., Garca, F., Sanchis, E., Segarra, E.: Multilingual spoken language understanding using graphs and multiple translations. Comput. Speech Lang. 38, 86–103 (2016)Dinarelli, M., Moschitti, A., Riccardi, G.: Concept segmentation and labeling for conversational speech. In: Interspeech, Brighton, UK (2009)Esteve, Y., Raymond, C., Bechet, F., Mori, R.D.: Conceptual decoding for spoken dialog systems. In: Proceedings of EuroSpeech 2003, pp. 617–620 (2003)García, F., Hurtado, L., Segarra, E., Sanchis, E., Riccardi, G.: Combining multiple translation systems for spoken language understanding portability. In: Proceedings of IEEE Workshop on Spoken Language Technology (SLT), pp. 282–289 (2012)Hahn, S., Dinarelli, M., Raymond, C., Lefèvre, F., Lehnen, P., De Mori, R., Moschitti, A., Ney, H., Riccardi, G.: Comparing stochastic approaches to spoken language understanding in multiple languages. IEEE Trans. Audio Speech Lang. Process. 6(99), 1569–1583 (2010)He, Y., Young, S.: A data-driven spoken language understanding system. In: Proceedings of ASRU 2003, pp. 583–588 (2003)Hurtado, L., Segarra, E., García, F., Sanchis, E.: Language understanding using n-multigram models. In: Vicedo, J.L., Martínez-Barco, P., Muńoz, R., Saiz Noeda, M. (eds.) EsTAL 2004. LNCS (LNAI), vol. 3230, pp. 207–219. Springer, Heidelberg (2004). doi: 10.1007/978-3-540-30228-5_19Jabaian, B., Besacier, L., Lefèvre, F.: Comparison and combination of lightly supervised approaches for language portability of a spoken language understanding system. IEEE Trans. Audio Speech Lang. Process. 21(3), 636–648 (2013)Koehn, P., et al.: Moses: open source toolkit for statistical machine translation. In: Proceedings of ACL Demonstration Session, pp. 177–180 (2007)Lafferty, J., McCallum, A., Pereira, F.: Conditional random fields: probabilistic models for segmenting and labeling sequence data. In: International Conference on Machine Learning, pp. 282–289. Citeseer (2001)Lefèvre, F.: Dynamic Bayesian networks and discriminative classifiers for multi-stage semantic interpretation. In: IEEE International Conference on Acoustics, Speech and Signal Processing, ICASSP 2007, vol. 4, pp. 13–16. IEEE (2007)Ortega, L., Galiano, I., Hurtado, L.F., Sanchis, E., Segarra, E.: A statistical segment-based approach for spoken language understanding. In: Proceedings of InterSpeech 2010, Makuhari, Chiba, Japan, pp. 1836–1839 (2010)Segarra, E., Sanchis, E., Galiano, M., García, F., Hurtado, L.: Extracting semantic information through automatic learning techniques. IJPRAI 16(3), 301–307 (2002)Servan, C., Camelin, N., Raymond, C., Bchet, F., Mori, R.D.: On the use of machine translation for spoken language understanding portability. In: Proceedings of ICASSP 2010, pp. 5330–5333 (2010)Tür, G., Mori, R.D.: Spoken Language Understanding: Systems for Extracting Semantic Information from Speech, 1st edn. Wiley, Hoboken (2011

Ultrafast Molecular Transport on Carbon Surfaces: The Diffusion of Ammonia on Graphite

We present a combined experimental and theoretical study of the self-diffusion of ammonia on exfoliated graphite. Using neutron time-of-flight spectroscopy we are able to resolve the ultrafast diffusion process of adsorbed ammonia, NH$_3$, on graphite. Together with van der Waals corrected density functional theory calculations we show that the diffusion of NH$_3$ follows a hopping motion on a weakly corrugated potential energy surface with an activation energy of about 4 meV which is particularly low for this type of diffusive motion. The hopping motion includes further a significant number of long jumps and the diffusion constant of ammonia adsorbed on graphite is determined with D=3.9 \cdot 10^{-8}~\mbox{m}^2 /\mbox{s} at 94 K

Floquet interface states in illuminated three-dimensional topological insulators

Recent experiments showed that the surface of a three dimensional topological insulator develops gaps in the Floquet-Bloch band spectrum when illuminated with a circularly polarized laser. These Floquet-Bloch bands are characterized by non-trivial Chern numbers which only depend on the helicity of the polarization of the radiation field. Here we propose a setup consisting of a pair of counter-rotating lasers, and show that one-dimensional chiral states emerge at the interface between the two lasers. These interface states turn out to be spin-polarized and may trigger interesting applications in the field of optoelectronics and spintronics.Comment: 5 pages with 3 figures + supplemental materia