399 research outputs found
X-ray Absorption Near-Edge Structure calculations with pseudopotentials. Application to K-edge in diamond and alpha-quartz
We present a reciprocal-space pseudopotential scheme for calculating X-ray
absorption near-edge structure (XANES) spectra. The scheme incorporates a
recursive method to compute absorption cross section as a continued fraction.
The continued fraction formulation of absorption is advantageous in that it
permits the treatment of core-hole interaction through large supercells
(hundreds of atoms). The method is compared with recently developed
Bethe-Salpeter approach. The method is applied to the carbon K-edge in diamond
and to the silicon and oxygen K-edges in alpha-quartz for which polarized XANES
spectra were measured. Core-hole effects are investigated by varying the size
of the supercell, thus leading to information similar to that obtained from
cluster size analysis usually performed within multiple scattering
calculations.Comment: 11 pages, 4 figure
Study of ligand substituent effects on the rate and stereoselectivity of lactide polymerization using aluminum salen-type initiators.
A series of aluminum salen-type complexes [where salen is N,N′-bis(salicylaldimine)-1,2-ethylenediamine] bearing ligands that differ in their steric and electronic properties have been synthesized and investigated for the polymerization of rac-lactide. X-ray crystal structures on key precatalysts reveal metal coordination geometries intermediate between trigonal bipyramidal and square-based pyramidal. Both the phenoxy substituents and the backbone linker have a significant influence over the polymerization. Electron-withdrawing groups attached to the phenoxy donor generally gave an increased polymerization rate, whereas large ortho substituents generally slowed down the polymerization. The vast majority of the initiators afforded polylactide with an isotactic bias; only one exhibited a bias toward heteroselectivity. Isoselectivity generally increases with increased flexibility of the backbone linker, which is presumed to be better able to accommodate any potential steric clashes between the propagating polymer chain, the inserting monomer unit, and the substituents on the phenoxy donor
Annihilation of low energy antiprotons in silicon
The goal of the AEIS experiment at the Antiproton
Decelerator (AD) at CERN, is to measure directly the Earth's gravitational
acceleration on antimatter. To achieve this goal, the AEIS
collaboration will produce a pulsed, cold (100 mK) antihydrogen beam with a
velocity of a few 100 m/s and measure the magnitude of the vertical deflection
of the beam from a straight path. The final position of the falling
antihydrogen will be detected by a position sensitive detector. This detector
will consist of an active silicon part, where the annihilations take place,
followed by an emulsion part. Together, they allow to achieve 1 precision on
the measurement of with about 600 reconstructed and time tagged
annihilations.
We present here, to the best of our knowledge, the first direct measurement
of antiproton annihilation in a segmented silicon sensor, the first step
towards designing a position sensitive silicon detector for the
AEIS experiment. We also present a first comparison with
Monte Carlo simulations (GEANT4) for antiproton energies below 5 MeVComment: 21 pages in total, 29 figures, 3 table
Influence of the 6^1S_0-6^3P_1 Resonance on Continuous Lyman-alpha Generation in Mercury
Continuous coherent radiation in the vacuum-ultraviolet at 122 nm
(Lyman-alpha) can be generated using sum-frequency mixing of three fundamental
laser beams in mercury vapour. One of the fundamental beams is at 254 nm
wavelength, which is close to the 6^1S_0-6^3P_1 resonance in mercury.
Experiments have been performed to investigate the effect of this one-photon
resonance on phasematching, absorption and the nonlinear yield. The efficiency
of continuous Lyman-alpha generation has been improved by a factor of 4.5.Comment: 8 pages, 7 figure
Prospects for measuring the gravitational free-fall of antihydrogen with emulsion detectors
The main goal of the AEgIS experiment at CERN is to test the weak equivalence
principle for antimatter. AEgIS will measure the free-fall of an antihydrogen
beam traversing a moir\'e deflectometer. The goal is to determine the
gravitational acceleration g for antihydrogen with an initial relative accuracy
of 1% by using an emulsion detector combined with a silicon micro-strip
detector to measure the time of flight. Nuclear emulsions can measure the
annihilation vertex of antihydrogen atoms with a precision of about 1 - 2
microns r.m.s. We present here results for emulsion detectors operated in
vacuum using low energy antiprotons from the CERN antiproton decelerator. We
compare with Monte Carlo simulations, and discuss the impact on the AEgIS
project.Comment: 20 pages, 16 figures, 3 table
AEGIS at CERN: Measuring Antihydrogen Fall
The main goal of the AEGIS experiment at the CERN Antiproton Decelerator is
the test of fundamental laws such as the Weak Equivalence Principle (WEP) and
CPT symmetry. In the first phase of AEGIS, a beam of antihydrogen will be
formed whose fall in the gravitational field is measured in a Moire'
deflectometer; this will constitute the first test of the WEP with antimatter.Comment: Presented at the Fifth Meeting on CPT and Lorentz Symmetry,
Bloomington, Indiana, June 28-July 2, 201
Charge-radius change and nuclear moments in the heavy tin isotopes from laser spectroscopy: Charge radius of Sn
NESTER ACCLaser spectroscopy measurements have been carried out on the neutron-rich tin isotopes with the COMPLIS experimental setup. Using the optical transition, hyperfine spectra of Sn and were recorded for the first time. The nuclear moments and the mean square charge radius variation (\delta, the absolute charge radii of these isotopes were deduced in particular that of the doubly magic Sn nucleus. The comparison of the results with several mean-field-type calculations have shown that dynamical effects play an important role in the tin isotopes
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