38,554 research outputs found

    The Geometry of Niggli Reduction I: The Boundary Polytopes of the Niggli Cone

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    Correct identification of the Bravais lattice of a crystal is an important step in structure solution. Niggli reduction is a commonly used technique. We investigate the boundary polytopes of the Niggli-reduced cone in the six-dimensional space G6 by algebraic analysis and organized random probing of regions near 1- through 8-fold boundary polytope intersections. We limit consideration of boundary polytopes to those avoiding the mathematically interesting but crystallographically impossible cases of 0 length cell edges. Combinations of boundary polytopes without a valid intersection in the closure of the Niggli cone or with an intersection that would force a cell edge to 0 or without neighboring probe points are eliminated. 216 boundary polytopes are found: 15 5-D boundary polytopes of the full G6 Niggli cone, 53 4-D boundary polytopes resulting from intersections of pairs of the 15 5-D boundary polytopes, 79 3-D boundary polytopes resulting from 2-fold, 3-fold and 4-fold intersections of the 15 5-D boundary polytopes, 55 2-D boundary polytopes resulting from 2-fold, 3-fold, 4-fold and higher intersections of the 15 5-D boundary polytopes, 14 1-D boundary polytopes resulting from 3-fold and higher intersections of the 15 5-D boundary polytopes. All primitive lattice types can be represented as combinations of the 15 5-D boundary polytopes. All non-primitive lattice types can be represented as combinations of the 15 5-D boundary polytopes and of the 7 special-position subspaces of the 5-D boundary polytopes. This study provides a new, simpler and arguably more intuitive basis set for the classification of lattice characters and helps to illuminate some of the complexities in Bravais lattice identification. The classification is intended to help in organizing database searches and in understanding which lattice symmetries are "close" to a given experimentally determined cell

    Outport adaptations: Social indicators through Newfoundland\u27s Cod crisis

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    The 1992 moratorium on fishing for Northern Cod marked a symbolic end to the way of life that had sustained Newfoundland\u27s out ports for hundreds of years. It also marked the completion of an ecological regime shift, from an ocean ecosystem dominated by cod and other predatory ground fish, to one in which such fish are comparatively scarce, and lower-trophic-level invertebrates more common. We examine patterns of change seen in large-scale social indicators, which reflect the smaller-scale adaptations of individuals and communities during this ecological shift. Trends in population, migration, age, unemployment and dependency suggest declining conditions in rural Newfoundland over the years of fisheries troubles. The 1992 crisis accelerated previous trends, but did not produce great discontinuities. Some trends date instead to the late-1980s resource-depletion phase that ended the glory years of Newfoundland\u27s ground fish boom. Government interventions meant to soften the economic impact of the 1992 crisis also blunted its social impacts, effectively postponing or distributing these over a number of subsequent years. Out port society is adapting to shifts in the regulatory and global-market environment, as well as changing marine ecology. Adaptive strategies include new investments in invertebrate fisheries, changes in education and migration, and continuing reliance on the informal economy

    The Geometry of Niggli Reduction II: BGAOL -- Embedding Niggli Reduction

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    Niggli reduction can be viewed as a series of operations in a six-dimensional space derived from the metric tensor. An implicit embedding of the space of Niggli-reduced cells in a higher dimensional space to facilitate calculation of distances between cells is described. This distance metric is used to create a program, BGAOL, for Bravais lattice determination. Results from BGAOL are compared to the results from other metric-based Bravais lattice determination algorithms

    Orbiting multi-beam microwave radiometer for soil moisture remote sensing

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    The effects of soil moisture and other factors on soil surface emissivity are reviewed and design concepts for a multibeam microwave radiometer with a 15 m antenna are described. Characteristic antenna gain and radiation patterns are shown and losses due to reflector roughness are estimated

    Characteristics of a variable spaced planar thermionic converter with a tungsten emitter and a niobium collector

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    Current-voltage characteristics of variable spaced thermionic converter with tungsten emitter and niobium collecto

    Contrasting the beam interaction characteristics of selected lasers with a partially stabilised zirconia (PSZ) bio-ceramic

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    Differences in the beam interaction characteristics of a CO2 laser, a Nd:YAG laser, a high power diode laser (HPDL) and an excimer laser with a partially stabilised zirconia (PSZ) bio-ceramic have been studied. A derivative of Beer-Lambert’s law was applied and the laser beam absorption lengths of the four lasers were calculated as 33.55 x 10-3 cm for the CO2 laser, 18.22 x 10-3 cm for the Nd:YAG laser, 17.17 x 10-3 cm for the HPDL and 8.41 x 10-6 cm for the excimer laser. It was determined graphically that the fluence threshold values at which significant material removal was effected by the CO2 laser, the Nd:YAG laser, the HPDL and the excimer laser were 52 J/cm2, 97 J/cm2, 115 J/cm2 and 0.48 J/cm2 respectively. The thermal loading value for the CO2 laser, the Nd:YAG laser, the HPDL and the excimer laser were calculated as being 1.55 kJ/cm3, 5.32 kJ/cm3, 6.69 kJ/cm3 and 57.04 kJ/cm3 respectively
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