41 research outputs found

    Introducing Dynamic Nonlinear Soil-Foundation-Structure Interaction Effects in Displacement-Based Seismic Design

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    An iterative linear-equivalent procedure to take into account nonlinear soilstructure interaction effects in the displacement-based seismic design is presented for the case of shallow foundations. The procedure is based on the use of empirical curves to evaluate the stiffness degradation and the increase of damping ratio as a function of foundation rotation. Iterations are performed to ensure that admissible values of foundation rotations are complied with, in addition to the standard checks on structural displacements and drifts. Some examples of application of the approach to the design of bridge piers are provided. Design results are checked by means of nonlinear dynamic time-history analyses performed by a macro-element-based numerical tool, assuming nonlinear behavior of both structure and soil-foundation system

    Biomolecules extraction from coffee and cocoa by‐ and co‐products using deep eutectic solvents

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    BACKGROUND : Coffee pulp (CP), cocoa husk (CH), and pod husk (CPH) are the main agro‐residues from coffee and cocoa industries. They are sources of useful biomolecules, such as phenolic compounds, fibers, and alkaloids, among others. In this study, different compositions of deep eutectic solvents (DES) were investigated as a green and sustainable extraction media, with respect to their extraction capacity. The extraction yields were evaluated using heat stirring‐assisted extraction (HSE) or ultrasound‐probe assisted extraction (UPAE).RESULTS : The results showed an important effect of the DES composition. Choline chloride (ChCl) based‐DES were the most effective, specifically lactic acid:ChCl (2:1 mol ratio), and the extraction capacity of DES was higher with UPAE (3 min/constant duty cycle (200 W)), in comparison with HSE (1 h/30 min). Chlorogenic acid, caffeine, and theobromine were identified as the main bioactive compounds. Interestingly, under specific conditions, DES allowed the formation of a molecule, identified as furfural by ultrahigh‐performance liquid chromatography mass spectrometry (UPLC‐MS), which could not be obtained using conventional extraction solvent (ethanol 70% v/v).CONCLUSION : DES showed a sustainability and high extraction capacity of biomolecules. In addition, their use as extraction solvents could lead to the formation and production of valuable building block molecules from plant biomas
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