9,587 research outputs found
Optical Properties of BN in the cubic and in the layered hexagonal phases
Linear optical functions of cubic and hexagonal BN have been studied within
first principles DFT-LDA theory. Calculated energy-loss functions compare well
with experiments and previous theoretical results both for h-BN and for c-BN.
Discrepancies arise between theoretical results and experiments in the
imaginary part of the dielectric function for c-BN. Possible explanation to
this mismatch are proposed and evaluated; lattice constant variations, h-BN
contamination in c-BN samples and self-energy effects.Comment: RevTex 42 pages, 16 postscript figures embedde
Native defects in hybrid C/BN nanostructures
First-principles calculations of substitutional defects and vacancies are
performed for zigzag-edged hybrid C/BN nanosheets and nanotubes which recently
have been proposed to exhibit half-metallic properties. The formation energies
show that defects form preferentially at the interfaces between graphene and BN
domains rather than in the middle of these domains, and that substitutional
defects dominate over vacancies. Chemical control can be used to favor
localization of defects at C- B interfaces (nitrogen-rich environment) or C-N
interfaces (nitrogen-poor environment). Although large defect concentrations
have been considered here (106 cm-1), half-metallic properties can subsist when
defects are localized at the C-B interface and for negatively charged defects
localized at the C- N interface, hence the promising magnetic properties
theoretically predicted for these zigzag-edged nanointerfaces might not be
destroyed by point defects if these are conveniently engineered during
synthesis.Comment: 6 pages, 5 figure
Origin of half-semimetallicity induced at interfaces of C-BN heterostructures
First-principles density functional calculations are performed in C-BN
heterojunctions. It is shown that the magnetism of the edge states in zigzag
shaped graphene strips and polarity effects in BN strips team up to give a spin
asymmetric screening that induces half-semimetallicity at the interface, with a
gap of at least a few tenths of eV for one spin orientation and a tiny gap of
hundredths of eV for the other. The dependence with ribbon widths is discussed,
showing that a range of ribbon widths is required to obtain
half-semimetallicity. These results open new routes for tuning electronic
properties at nanointerfaces and exploring new physical effects similar to
those observed at oxide interfaces, in lower dimensions.Comment: 4 pages, 4 figure
Significance of Boron Nitride in Composites and Its Applications
Boron nitride (BN) exists in several polymorphic forms such as a-BN, h-BN, t-BN, r-BN, m-BN, o-BN, w-BN, and c-BN phases. Among them, c-BN and h-BN are the most common ceramic powders used in composites to ensure enhanced material properties. Cubic boron nitride (c-BN) has exceptional properties such as hardness, strength than relating with other ceramics so that are most commonly used as abrasives and in cutting tool applications. c-BN possesses the second highest thermal conductivity after diamond and relatively low dielectric constant. Hence pioneer preliminary research in AMCs proven substitute composites than virgin AA 6061 traditionally used for fins in heat sinks. Moreover, poly-crystalline c-BN (PCBN) tools are most suitable for various machining tasks due to their unmatchable mechanical properties. h-BN also finds its own unique applications where polymer composites for high temperature applications and sp3 bonding in extreme temperature and compression conditions
Optical and Acoustic Phonons in Turbostratic and Cubic Boron Nitride Thin Films on Diamond Substrates
We report an investigation of the bulk optical, bulk acoustic, and surface
acoustic phonons in thin films of turbostratic boron nitride (t-BN) and cubic
boron nitride (c-BN) grown on B-doped polycrystalline and single-crystalline
diamond (001) and (111) substrates. The characteristics of different types of
phonons were determined using Raman and Brillouin-Mandelstam light scattering
spectroscopies. The atomic structure of the films was determined using
high-resolution transmission electron microscopy (HRTEM) and correlated with
the Raman and Brillouin-Mandelstam spectroscopy data. The HRTEM analysis
revealed that the cubic boron nitride thin films consisted of a mixture of c-BN
and t-BN phases, with c-BN being the dominant phase. It was found that while
visible Raman spectroscopy provided information for characterizing the t-BN
phase, it faced challenges in differentiating the c-BN phase either due to the
presence of high-density defects or the overlapping of the Raman features with
those from the B-doped diamond substrates. In contrast, Brillouin-Mandelstam
spectroscopy clearly distinguishes the bulk longitudinal and surface acoustic
phonons of the c-BN thin films grown on diamond substrates. Additionally, the
angle-dependent surface Brillouin-Mandelstam scattering data show the peaks
associated with the Rayleigh surface acoustic waves, which have higher phase
velocities in c-BN films on diamond (111) substrates. These findings provide
valuable insights into the phonon characteristics of the c-BN and diamond
interfaces and have important implications for the thermal management of
electronic devices based on ultra-wide-band-gap materials.Comment: 27 pages; 4 figure
Phase Stability of Hexagonal/cubic Boron Nitride Nanocomposites
Boron nitride (BN) is an exceptional material and among its polymorphs,
two-dimensional (2D) hexagonal and three-dimensional (3D) cubic BN (h-BN and
c-BN) phases are most common. The phase stability regimes of these BN phases
are still under debate and phase transformations of h-BN/c-BN remain a topic of
interest. Here, we investigate the phase stability of 2D/3D h-BN/c-BN
nanocomposites and show that the co-existence of two phases can lead to strong
non-linear optical properties and low thermal conductivity at room temperature.
Furthermore, spark-plasma sintering of the nanocomposite shows complete phase
transformation to 2D h-BN with improved crystalline quality, where 3D c-BN
grain sizes governs the nucleation and growth kinetics. Our demonstration might
be insightful in phase engineering of BN polymorphs based nanocomposites with
desirable properties for optoelectronics and thermal energy management
applications.Comment: 29 pages, 5 figure
Anisotropic Dielectric Breakdown Strength of Single Crystal Hexagonal Boron Nitride
Dielectric breakdown has historically been of great interest from the
perspectives of fundamental physics and electrical reliability. However, to
date, the anisotropy in the dielectric breakdown has not been discussed. Here,
we report an anisotropic dielectric breakdown strength (EBD) for h-BN, which is
used as an ideal substrate for two-dimensional (2D) material devices. Under a
well-controlled relative humidity, EBD values in the directions both normal and
parallel to the c axis (EBD+c & EBD//c) were measured to be 3 and 12 MV/cm,
respectively. When the crystal structure is changed from sp3 of cubic-BN (c-BN)
to sp2 of h-BN, EBD+c for h-BN becomes smaller than that for c-BN, while EBD//c
for h-BN drastically increases. Therefore, h-BN can possess a relatively high
EBD concentrated only in the direction parallel to the c axis by conceding a
weak bonding direction in the highly anisotropic crystal structure. This
explains why the EBD//c for h-BN is higher than that for diamond. Moreover, the
presented EBD value obtained from the high quality bulk h-BN crystal can be
regarded as the standard for qualifying the crystallinity of h-BN layers grown
via chemical vapor deposition for future electronic applications
Photoluminescence from voids created by femtosecond-laser pulses inside cubic-BN
Photoluminescence (PL) from femtosecond-laser-modified regions inside cubic-boron nitride (c-BN) was measured under UV and visible light excitation. Bright PL at the red spectral range was observed, with a typical excited state lifetime of ∼4  ns. Sharp emission lines are consistent with PL of intrinsic vibronic defects linked to the nitrogen vacancy formation (via Frenkel pair) observed earlier in high-energy electron-irradiated and ion-implanted c-BN. These, formerly known as the radiation centers, RC1, RC2, and RC3, have been identified at the locus of the voids formed by a single femtosecond-laser pulse. The method is promising to engineer color centers in c-BN for photonic applications
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