239 research outputs found

    The formation of water droplets in an air-breathing PEMFC

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    Air-Breathing Proton Exchange Membrane Fuel Cells (AB-PEMFC) have the potential to supersede lithium-ion batteries in portable electronics. However, their water management issue has yet to be resolved to ensure optimum cell performance and safe system operation. In this paper, the formation of water droplets and their aggregation in the cathode flow channels of an operating AB-PEMFC is investigated by direct visualisation under various operating conditions. The developed optical set-up enables observation of droplet formation on the surface of the membrane from the top and side view of the channels simultaneously. The two orthogonal views reveal that during formation the receding and advancing droplet contact angles are almost identical with values that increase, in a similar trend to the droplet height, with increasing droplet diameter. Water films were able to develop and maintain direct contact with the side wall of the channels even under the effect of gravitational force. The aggregation of water droplets in the channels was strongly influenced by the change in the air and hydrogen stoichiometry conditions. However, these operating parameters appear to have no significant effect on the water extraction from the channels contrary to load and temperature, where temperature has proved to be the most effective water removal mechanism with minimum reduction in the current density of AB-PEMFC

    The potential of di-methyl ether (DME) as an alternative fuel for compression-ignition engines: A review

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    This paper reviews the properties and application of di-methyl ether (DME) as a candidate fuel for compression-ignition engines. DME is produced by the conversion of various feedstock such as natural gas, coal, oil residues and bio-mass. To determine the technical feasibility of DME, the review compares its key properties with those of diesel fuel that are relevant to this application. DME’s diesel engine-compatible properties are its high cetane number and low auto-ignition temperature. In addition, its simple chemical structure and high oxygen content result in soot-free combustion in engines. Fuel injection of DME can be achieved through both conventional mechanical and current common-rail systems but requires slight modification of the standard system to prevent corrosion and overcome low lubricity. The spray characteristics of DME enable its application to compression-ignition engines despite some differences in its properties such as easier evaporation and lower density. Overall, the low particulate matter production of DME provides adequate justification for its consideration as a candidate fuel in compression-ignition engines. Recent research and development shows comparable output performance to a diesel fuel led engine but with lower particulate emissions. NOx emissions from DME-fuelled engines can meet future regulations with high exhaust gas recirculation in combination with a lean NOx trap. Although more development work has focused on medium or heavy-duty engines, this paper provides a comprehensive review of the technical feasibility of DME as a candidate fuel for environmentally-friendly compression-ignition engines independent of size or application
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