840 research outputs found
A SHORT DESCRIPTION OF SCORZONERA PLANT SPECIES PRESENT IN ALEXANDRU BELDIE HERBARIUM FROM I.N.C.D.S. BUCHAREST
The present paper reunites the morphological and ecological description of Scorzonera plant species present in the Al. Beldie Herbarium from Marin Drăcea National Institute for Research and Development in Forestry (INCDS) in Bucharest. Furthermore, this article organizes the herbarium exemplars based on species, harvest year, the place from where they were taken and the specialist that has gathered them. The first part of the article starts with a short description of the herbarium and its specific, followed by presenting the material and method used in elaborating the paper. As such, the material is represented by the 83 plates containing exemplars of some Scorzonera species. A very important aspect which must be specified is the fact that the herbarium has a significant number of rare endangered or endemic specimens. One example, the protect species Scorzonerarosea, is present in the herbarium with 26 plates that were mainly gathered in the year 1936 by Al. Beldie himself.  Another rare species, Scorzonera hispanica, is represented in 16 plates from within the herbarium and is of a high interest as it is the oldest species of the genre, being harvested in the year 1794. Beside the description of the gathered Scorzonera species, the present paper presents the gathering map of the species present in the herbarium at an European level, together with analyzing the gathering periods of these species. Some of the oldest gathered species are also presented in this article. The paper ends with some conclusions regarding the Scorzonera species’ analysis and exemplars present in the herbarium, while briefly presenting their most novel aspects and characteristics.
Observing Nearby Nuclei on Paramagnetic Trityls and MOFs via DNP and Electron Decoupling
Dynamic nuclear polarization (DNP) is an NMR sensitivity enhancement technique that mediates polarization transfer from unpaired electrons to NMR-active nuclei. Despite its success in elucidating important structural information on biological and inorganic materials, the detailed polarization-transfer pathway from the electrons to the nearby and then the bulk solvent nuclei, and finally to the molecules of interest-remains unclear. In particular, the nuclei in the paramagnetic polarizing agent play significant roles in relaying the enhanced NMR polarizations to more remote nuclei. Despite their importance, the direct NMR observation of these nuclei is challenging because of poor sensitivity. Here, we show that a combined DNP and electron decoupling approach can facilitate direct NMR detection of these nuclei. We achieved an ∼80 % improvement in NMR intensity via electron decoupling at 0.35 T and 80 K on trityl radicals. Moreover, we recorded a DNP enhancement factor of urn:x-wiley:09476539:media:chem202202556:chem202202556-math-0001 ∼90 and ∼11 % higher NMR intensity using electron decoupling on paramagnetic metal-organic framework, magnesium hexaoxytriphenylene (MgHOTP MOF)
Large scale shell model calculations for odd-odd Mn isotopes
Large scale shell model calculations have been carried out for odd-odd
Mn isotopes in two different model spaces. First set of calculations
have been carried out in full shell valence space with two recently
derived shell interactions namely GXPF1A and KB3G treating Ca
as core. The second set of calculations have been performed in
valence space with the interaction treating Ca as core and
imposing a truncation by allowing up to a total of six particle excitations
from the 0f orbital to the upper orbitals for protons and
from the upper orbitals to the 0g orbital for neutron. For
low-lying states in Mn, the KB3G and GXPF1A both predicts good results
and for Mn, KB3G is much better than GXPF1A. For negative parity and
high-spin positive parity states in both isotopes interaction is
required. Experimental data on Mn is sparse and therefore it is not
possible to make any definite conclusions. More experimental data on negative
parity states is needed to ascertain the importance of 0g and higher
orbitals in neutron rich Mn isotopes.Comment: 5 pages, 4 figures, Submitted to Eur. Phys. J.
Spectroscopy of the odd-odd fp-shell nucleus 52Sc from secondary fragmentation
The odd-odd fp-shell nucleus 52Sc was investigated using in-beam gamma-ray
spectroscopy following secondary fragmentation of a 55V and 57Cr cocktail beam.
Aside from the known gamma-ray transition at 674(5)keV, a new decay at
E_gamma=212(3) keV was observed. It is attributed to the depopulation of a
low-lying excited level. This new state is discussed in the framework of
shell-model calculations with the GXPF1, GXPF1A, and KB3G effective
interactions. These calculations are found to be fairly robust for the
low-lying level scheme of 52Sc irrespective of the choice of the effective
interaction. In addition, the frequency of spin values predicted by the shell
model is successfully modeled by a spin distribution formulated in a
statistical approach with an empirical, energy-independent spin-cutoff
parameter.Comment: accepted for publication in PR
Evolution of the energy spacing in odd-mass K, Cl and P isotopes for
The energy of the first excited state in the neutron-rich N=28 nucleus 45Cl
has been established via in-beam gamma-ray spectroscopy following proton
removal. This energy value completes the systematics of the
E(1/2^+_1)-E(3/2^+_1) level spacing in odd-mass K, Cl and P isotopes for
N=20-28. The results are discussed in the framework of shell-model calculations
in the sd-fp model space. The contribution of the central, spin-orbit and
tensor components is discussed from a calculation based on a proton single-hole
spectrum from G-matrix and pi + rho meson exchange potentials. A composite
model for the proton 0d_{3/2}-1s_{1/2} single-particle energy shift is
presented.Comment: Phys. Rev. C, in pres
One-neutron knockout in the vicinity of the N=32 sub-shell closure: 9Be(57Cr,56Cr+ gamma)X
The one-neutron knockout reaction 9Be(57Cr,56Cr + gamma)X has been measured
in inverse kinematics with an intermediate-energy beam. Cross sections to
individual states in 56Cr were partially untangled through the detection of the
characteristic gamma-ray transitions in coincidence with the reaction residues.
The experimental inclusive longitudinal momentum distribution and the yields to
individual states are compared to calculations that combine spectroscopic
factors from the full fp shell model and nucleon-removal cross sections
computed in a few-body eikonal approach.Comment: PRC, in pres
Variation with mass of \boldmath{B(E3; 0_1^+ \to 3_1^-)} transition rates in even-mass xenon nuclei
transition matrix elements have been measured for
even-mass Xe nuclei using sub-barrier Coulomb excitation in inverse
kinematics. The trends in energy and
excitation strengths are well reproduced using phenomenological models based on
a strong coupling picture with a soft quadrupole mode and an increasing
occupation of the intruder orbital.Comment: 5 pages, 4 figures, PRC in pres
Z=50 shell gap near Sn from intermediate-energy Coulomb excitations in even-mass Sn isotopes
Rare isotope beams of neutron-deficient Sn nuclei from the
fragmentation of Xe were employed in an intermediate-energy Coulomb
excitation experiment yielding transition strengths.
The results indicate that these values are much larger
than predicted by current state-of-the-art shell model calculations. This
discrepancy can be explained if protons from within the Z = 50 shell are
contributing to the structure of low-energy excited states in this region. Such
contributions imply a breaking of the doubly-magic Sn core in the light
Sn isotopes.Comment: 4 pages, 4 figure
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