2,523 research outputs found
-AlN-Mg(OH) vdW Bilayer Heterostructure: Tuning the excitonic characteristics
Motivated by recent studies that reported the successful synthesis of
monolayer Mg(OH) [Suslu \textit{et al.}, Sci. Rep. \textbf{6}, 20525
(2016)] and hexagonal (\textit{h}-)AlN [Tsipas \textit{et al}., Appl. Phys.
Lett. \textbf{103}, 251605 (2013)], we investigate structural, electronic, and
optical properties of vertically stacked -AlN and Mg(OH), through
\textit{ab initio} density-functional theory (DFT), many-body quasi-particle
calculations within the GW approximation, and the Bethe-Salpeter equation
(BSE). It is obtained that the bilayer heterostructure prefers the
stacking having direct band gap at the with Type-II band
alignment in which the valance band maximum and conduction band minimum
originate from different layer. Regarding the optical properties, the imaginary
part of the dielectric function of the individual layers and hetero-bilayer are
investigated. The hetero-bilayer possesses excitonic peaks which appear only
after the construction of the hetero-bilayer. The lowest three exciton peaks
are detailedly analyzed by means of band decomposed charge density and the
oscillator strength. Furthermore, the wave function calculation shows that the
first peak of the hetero-bilayer originates from spatially indirect exciton
where the electron and hole localized at -AlN and Mg(OH),
respectively, which is important for the light harvesting applications.Comment: Accepted by Physical Review
Recommended from our members
Identification of Recharge-Discharge Areas of the Palo Duro Basin, Texas Panhandle
This report presents the preliminary results of research to identify the recharge and discharge areas of the major aquifers in the Palo Duro Basin. Recharge has been investigated by studying the isotopic compositions of surface and shallow ground waters in New Mexico and Texas. Discharge studies have focused on identifying the source of the brine discharged in springs and seeps along the outcrop of Permian rocks east of the Caprock Escarpment.Bureau of Economic Geolog
Half-metallic properties of atomic chains of carbon-transition metal compounds
We found that magnetic ground state of one-dimensional atomic chains of
carbon-transition metal compounds exhibit half-metallic properties. They are
semiconductors for one spin-direction, but show metallic properties for the
opposite direction. The spins are fully polarized at the Fermi level and net
magnetic moment per unit cell is an integer multiple of Bohr magneton. The
spin-dependent electronic structure can be engineered by changing the number of
carbon and type of transition metal atoms. These chains, which are stable even
at high temperature and some of which keep their spin-dependent electronic
properties even under moderate axial strain, hold the promise of potential
applications in nanospintronics.Comment: 11 pages, 3 figures, 1 table
Strange Particles in Dense Matter and Kaon Condensates
We discuss the role of strangeness in dense matter and especially in neutron
stars. The early (in density) introduction of hyperons found in many
calculations is probably delayed by the decrease in vector mean field acting on
the neutron. The decrease results from both conventional many-body rescattering
effects and from the movement towards asymptotic freedom at high densities.
Subthreshold -meson production by the KaoS collaboration at GSI shows that
the -mass must be substantially lowered, by 200 MeV at . It is shown that explicit chiral symmetry breaking through the kaon
mass may be responsible for -nucleon and -nucleon scalar
attraction being weaker than obtained by simple quark scaling. The normal mode
of the strangeness minus, charge , excitation is constructed as a linear
combination of -meson and , neutron-hole state. Except for zero
momentum, where the terms are unmixed the "kaesobar" is a linear combination of
these two components.Comment: 10 pages, 8 postscript figures, Talk given at the International
Conference on Hypernuclear and Strange Particle Physics (HYP97), Brookhaven
Nat'l Lab., USA, October 13-18, 1997, to be published in Nucl. Phys.
Recommended from our members
Geologic and Hydrologic Investigations Reese Air Force Base, Lubbock, Texas
The Bureau of Economic Geology has characterized the geology and hydrology of the Ogallala and Blackwater Draw Formations at Reese Air Force Base to provide baseline information for better delineation of contamination on the base. Examination of five cores identified two predominant depositional facies: eolian sands and fluvial gravels. The gravels appear to be continuous across the base and may represent the major water-bearing unit; therefore, they may be the prime conduit for contaminant migration in the groundwater beneath the base. Continuous water-level recorder data from water-supply wells and monitoring wells on the base indicated typically confined and unconfined conditions. The degree of confinement may be controlled by the wells' proximity to the playa lakes on the base or by the relation of the water levels in the wells relative to the top of the water-bearing gravel unit. This variability in the degree of confinement indicates a more complex hydrologic setting than is normally recognized for the Ogallala aquifer.Bureau of Economic Geolog
Recommended from our members
Characterization of Facies and Permeability Patterns in Carbonate Reservoirs Based on Outcrop Analogs
More than 13 billion barrels (Bbbl) of mobile oil and 17 Bbbl of residual oil will remain in the San Andres and Grayburg reservoir at abandonment under current development practices. Through the development and application of new recovery technology, a large part of this resource can be recovered. This report focuses on research for the development and testing of new techniques for improving recovery of this resource. Outcrop and subsurface geologic and engineering data are utilized to develop new methodologies through the integration of geologic observations and engineering data for improving numerical models that predict reservoir performance more accurately.
Extensive regional mapping of the 14-mile by 1,200-foot San Andres outcrop, located on the Algerita Escarpment, Guadalupe Mountains, New Mexico, demonstrates that the San Andres carbonate-ramp complex is composed of multiple depositional sequences that have significant basinward shifts in reservoir-quality facies tracts occurring across sequence boundaries. Detailed geologic and petrophysical mapping of three reservoir-quality facies tracts demonstrates that the fundamental scale of geologic description for reservoir characterization is the parasequence and its component rock-fabric-based facies. Descriptions of cores from the Seminole San Andres Unit illustrate that the parasequence is also the fundamental geologic scale for reservoir mapping in the subsurface.Bureau of Economic Geolog
AlN-based piezoelectric micropower generator for low ambient vibration energy harvesting
AbstractIn this paper a resonant micropower generator based on the transverse piezoelectric effect is presented. The generator consists of a large silicon mass attached to an polysilicon cantilever covered with an AlN thinfilm as piezoelectric material. To maximize the power density of the generator, a parametric study by means of analytical modeling and FEM simulation has been performed. Different optimized generators with resonance frequencies in the range from 100Hz up to 1kHz have been designed and fabricated, using dedicated MEMS technology processes. First unpackaged prototypes showed a quality factor of about 500 under atmospheric pressure and were able to generate an electrical output power of up to 1.9μW at an external acceleration of 1.6 m/s2
Aminolevulinic Acid mediated Photodynamic Therapy of Human Meningioma: an in vitro Study on Primary Cell Lines
Objective: Five-aminolevulinic acid (5-ALA)-induced porphyrins in malignant gliomas are potent photosensitizers. Promising results of ALA-PDT (photodynamic therapy) in recurrent glioblastomas have been published. Recently, 5-ALA-induced fluorescence was studied in meningioma surgery. Here, we present an experimental study of ALA-PDT in an in vitro model of primary meningioma cell lines. Methods: We processed native tumor material obtained intra-operatively within 24 h for cell culture. Epithelial membrane antigen (EMA) immunohistochemistry was performed after the first passage to confirm that cells were meningioma cells. For 5-ALA-PDT treatment, about 5000 cells per well were seeded in 20 wells of a blank 96-well plate. Each block of 4 wells was inoculated with 150 µL of 0, 25, 50 and 100 µg/mL 5-ALA solutions; one block was used as negative control without 5-ALA and without PDT. Following incubation for 3 h PDT was performed using a laser (635 nm, 18.75 J/cm2). The therapeutic response was analyzed by the water soluble tetrazolium salt (WST-1) cell viability assay 90 min after PDT. Results: 5-ALA-PDT was performed in 14 primary meningioma cell lines. EMA expression was verified in 10 primary cell cultures. The remaining 4 were EMA negative and PDT was without any effect in these cultures. All 10 EMA-positive cell lines showed a significant and dose-dependent decrease in viability rate (p < 0.001). Cell survival at 5-ALA concentrations of 12.5, 25, 50 and 100 μg/mL was 96.5% ± 7.6%, 67.9% ± 29.9%, 24.0% ± 16.7% and 13.8% ± 7.5%, respectively. For the negative controls (no 5-ALA/PDT and ALA/no PDT), the viability rates were 101.72% ± 3.5% and 100.17% ± 3.6%, respectively. The LD50 for 5-ALA was estimated between 25 and 50 µg/mL. Conclusion: This study reveals dose-dependent cytotoxic effects of 5-ALA-PDT on primary cell lines of meningiomas. Either 5-ALA or PDT alone did not affect cell survival. Further efforts are necessary to study the potential therapeutic effects of 5-ALA-PDT in vivo
Determination of structural parameters characterizing thin films by optical methods: A comparison between scanning angle reflectometry and optical waveguide lightmode spectroscopy
International audienceWe present a comparative study of the structural parameters characterizing thin macromolecular adsorbed films that are obtained from two optical techniques: optical waveguide lightmode spectroscopy ͑OWLS͒ and scanning angle reflectometry ͑SAR͒. We use polyelectrolyte multilayers and polyelectrolyte multilayers/protein films to perform this study. The comparison between the information obtained with the two methods is possible because the buildup of the polyelectrolyte multilayers is known to become substrate independent after the deposition of the first few polyelectrolyte layers. The analysis of the optical data requires usually to postulate a refractive index profile for the interface. Two profiles have been used: the homogeneous and isotropic monolayer and the bilayer profiles. When the refractive index profile of an adsorbed film is well approximated by a homogeneous and isotropic monolayer, as shown by using an analysis of the deposited films in terms of optical invariants, the two optical techniques lead to similar values for the film thickness and the optical mass. The situation is more complex in the case of the multilayers/protein films for which the calculated parameters can strongly depend upon the refractive index profile that is postulated to analyze the optical data. Whereas the optical mass and, to a lesser extent, the thickness seem fairly model independent for OWLS, they appear to be extremely sensitive to the model for SAR. For proteins deposited on top of the polyelectrolyte film, optical mass and protein thickness were found to be comparable when determined by OWLS and by SAR using the bilayer model. The data analysis of the SAR curves with the monolayer model leads to much larger and even physically unreasonable film thicknesses and optical masses. This was particularly noticeable for proteins having a large size ͑human serum albumin and fibrinogen͒, whereas both models lead to similar results for small sized proteins. By means of the different refractive index profiles, we show that great care must be taken in the physicochemical interpretation of the structural parameters determined by these optical techniques
- …