Geopolymers: A new and smart way for a sustainable development

“Geopolymers” is a general term that describes a wide variety of inorganic and composite materials with limited restrictions on alumina and silica content. In the last decades, they have been also defined as “low-temperature aluminosilicate glasses”, “hydroceramics”, “inorganic polymer concrete” or “alkali bonded ceramics”. Recently, an updated definition has been proposed by the RILEM Technical Committee 224-AAM: “geopolymer materials are essential aluminosilicates activated with alkaline solution, excluding any other alkali-activated materials that should be classified apart” [1]

Dimensionamento de sistemas de tratamento (decantador e lagoas) e utilização de dejetos suínos.

Características dos dejetos; Equalizador; Decantador; Lagoas de tratamento; Adubação orgânica.bitstream/item/58411/1/CUsersPiazzonDocuments234.pd

Liquid Foam-Ethyl Vinyl Acetate Adhesive Systems for Lining Process of Paintings: Prospects of a User-Friendly, Harmless Alternative to Conventional Products

The lining of paintings is a process of conservation science and art restoration used to strengthen, flatten, or consolidate paintings on canvas by attaching by means of adhesives a second canvas to the back of the existing one. To this aim, the prospects of the use of ethyl vinyl acetate (EVA) resins in aqueous dispersion applied as an adhesive in a foam form have been investigated in the present study. The key physical properties of the foam have been investigated, with a deep focus on rheological behavior and the drying rate, comparing the results with those obtained using the liquid products that are commercially available. Dedicated mock-ups have been prepared to test the adhesive for the lining process, inspecting adhesion strength, colorimetric properties, and the influence on the possible chromatic and visual alteration of the surface, also looking at the chemical interaction with painting materials and the deterioration after an artificial ageing process. The results obtained clearly indicated that the proposed technology is very suitable for the targeted application, and an EVA water-based foamed dispersion can be used for paintings' lining, in view of the ease of application, being an appropriate adhesion, no chemical interaction, nor the deterioration of the painting

Toughening of complete solid solution cermets by graphite addition

(Ti0.95Ta0.05)(C0.5N0.5)-Co complete solid solution cermets (CSCs) were developed by a mechanochemical synthesis process and a pressureless sintering method. The effect of different percentages of graphite used as a sintering additive on the nature of the binder phase and the mechanical properties of the cermets was investigated. Microstructural and mechanical characterisations were carried out by X-ray diffraction, optical microscopy, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray spectroscopy, Vickers hardness, indentation fracture toughness and nanoindentation. The addition of graphite modified the carbon activity during sintering, reducing the dissolution of carbonitride ceramic particles into the molten binder. The amount of Ti and Ta remaining in the binder after sintering gradually decreased as the amount of graphite added increased, which induced a change in the nature of the binder phase. When no graphite was added, the binder consisted of the brittle TixTa1-xCo2 intermetallic phase. With the increase in the amount of graphite added, the formation of more ductile phases, such as TixTa1-xCo3 and α-Co, was observed, causing a significant improvement in the toughness of the cermets.Peer reviewe

Periodicidade do crescimento de espécies arbóreas da Floresta Estacional Semidecidual no Sul do Brasil.

Embora a sazonalidade climática seja menos evidente nas regiões tropicais que nas temperadas, muitas espécies tropicais apresentam crescimento rítmico. A avaliação do crescimento em circunferência do tronco (CCT) permitirá obter informações sobre o desenvolvimento dos indivíduos de espécies arbóreas desta região. Esse estudo teve como objetivo avaliar o CCT de 11 espécies arbóreas de uma floresta estacional semidecidual no sul do Brasil, visando testar duas hipóteses: (i) existe sazonalidade no CCT das árvores e este crescimento está relacionado às variações climáticas da região de estudo; (ii) as características dos indivíduos (posição sociológica, altura da árvore, grau de ocupação por lianas, deciduidade e diâmetro à altura do peito) influenciam no incremento acumulado em circunferência. Para detectar a periodicidade do CCT foram implantadas faixas dendrométricas permanentes no tronco (altura do DAP) de 156 indivíduos. O acompanhamento do crescimento foi realizado mensalmente por um período de 18 meses. Foram feitas correlações do CCT mensal com a precipitação, temperatura e fotoperíodo para verificar a influencia dos fatores ambientais e análise de covariância para averiguar se as características dos indivíduos também interferiram no incremento acumulado em circunferência do tronco. As espécies apresentaram um padrão sazonal de CCT, com as maiores taxas de crescimento de outubro a dezembro, sendo que os parâmetros ambientais avaliados atuaram em conjunto - principalmente o fotoperíodo e a temperatura - promovendo essa sazonalidade e confirmando a primeira hipótese. Considerando as características dos indivíduos, somente o diâmetro do tronco correlacionou-se negativamente com o incremento acumulado em circunferência (b = -0,32; p = 0,02), aceitando parcialmente a segunda hipótese

In vitro irradiation system for radiobiological experiments

Background: Although two-dimensional (2-D) monolayer cell cultures provide important information on basic tumor biology and radiobiology, they are not representative of the complexity of three-dimensional (3-D) solid tumors. In particular, new models reproducing clinical conditions as closely as possible are needed for radiobiological studies to provide information that can be translated from bench to bedside. Methods: We developed a novel system for the irradiation, under sterile conditions, of 3-D tumor spheroids, the in vitro model considered as a bridge between the complex architectural organization of in vivo tumors and the very simple one of in vitro monolayer cell cultures. The system exploits the same equipment as that used for patient treatments, without the need for dedicated and highly expensive instruments. To mimic the passage of radiation beams through human tissues before they reach the target tumor mass, 96-multiwell plates containing the multicellular tumor spheroids (MCTS) are inserted into a custom-built phantom made of plexiglass, the material most similar to water, the main component of human tissue. Results: The system was used to irradiate CAEP- and A549-derived MCTS, pre-treated or not with 20 \u3bcM cisplatin, with a dose of 20 Gy delivered in one session. We also tested the same treatment schemes on monolayer CAEP and A549 cells. Our preliminary results indicated a significant increment in radiotoxicity 20 days after the end of irradiation in the CAEP spheroids pre-treated with cisplatin compared to those treated with cisplatin or irradiation alone. Conversely, the effect of the radio- chemotherapy combination in A549-derived MCTS was similar to that induced by cisplatin or irradiation alone. Finally, the 20 Gy dose did not affect cell survival in monolayer CAEP and A549 cells, whereas cisplatin or cisplatin plus radiation caused 100% cell death, regardless of the type of cell line used. Conclusions: We set up a system for the irradiation, under sterile conditions, of tumor cells grown in 3-D which allows for the use of the same dose intensities and schedules utilized in clinical practice. This irradiation system, coupled with 3-D cell cultures, has the potential to generate information that could be used to individually tailor radiotherap

Ocorrência de tatu-de-rabo-mole, Cabassous unicinctus (Cingulata, Dasypodidae) no Pantanal, Brasil.

Há poucos registros na literatura científica sobre a ocorrência de tatu-de-rabo-mole (Cabassous unicinctus) na planície do Pantanal e nos planaltos adjacentes. Entretanto, dados relativamente recentes com base em espécimes coletados, registros fotográficos e observações de campo revelam que a espécie tem ampla distribuição na porção sul da planície, em regiões como Pantanal da Nhecolândia e Paiaguás, bem como no entorno do Pantanal (Diamantino, Taboco, Coxim, Terenos, Aquidauna, Bodoquena e Rochedo). A espécie apresenta ampla plasticidade ecológica em relação ao uso de habitat, sendo registrada tanto em campos com pastagens cultivadas (Brachiaria spp.), quanto campos inundáveis, capões, cerradão e cerrado. Com base em comparação dos exemplares fotografados no Pantanal e áreas do entorno com dados literários, verificou-se que os mesmos pertencem à subespécie Cabassous unicinctus squamicaudis.bitstream/CPAP-2010/57165/1/BP87.pd