Control of trace metal distribution and variability in an interdunal wetland

Trace elements are serious pollutants in the natural environment and are of increasing concern due to the adverse effects at global scale. To refine the current understanding of trace metal distribution and variability in natural environments, concentrations of dissolved trace metals (Ag, Al, As, B, Ba, Be, Co, Cr, Cd, Cu, Fe, Hg, Mo, Ni, Pb, Sb, Se, Th,Tl, U, V, Mn, Zn), major ions, inorganic nutrients (NO3, PO4), TOC and stable isotopes of water were determined in water samples from rainwater, seven piezometers and a pond in the coastal Doñana wetland during four sampling campaigns between 2017 and 2019. Results show clear evaporation signatures of stable isotopes in the pond but not in the groundwater. Hydrochemical analyses yield significant, systematic changes in groundwater trace metal and nutrient composition along the flowpath from the dune belt to the pond, controlled by organic matter in the sediments. Whereas major ions reached maximum concentrations in the pond due to evapoconcentration, most trace metals showed highest concentrations at sites with lower redox levels, except for B, As and U, which showed very high concentrations in the pond. Cu, Zn, Ni, Sb and Tl yielded higher median concentrations in rainwater than in most of the groundwater points and in case of Cu and Zn higher even than in surface water which points to an atmospheric input source of these elements. Temporal variability of trace metals was related to lower hydraulic heads after an elongated dry period which led to lower redox levels and higher concentrations of most of the trace elements whereas major ions showed more constant concentration levels. This is of special concern regarding climate change and the predicted higher frequency of prolonged dry periods, which could modify the natural hydrochemical patterns in undisturbed wetlands systemsThis work has been financed by the CLIGRO Project (MICINN, CGL2016-77473-C3-1-R) of the Spanish National Plan for Scientific and Technical Research and Innovation. The infrastructure has been cofinanced by European Research Funds (SE Scientific Infrastructures and Techniques and Equipment 388 2013, IGME13-1E-2113). We are especially grateful for the technical support of Lidia Molano Leno and Daniel Jesus Martinez Suárez. The contracts of Lidia Molano Leno (PEJ-2014-A-68763) and Daniel Jesus Martinez Suárez (PTA2014-09579-I) were financed by the Ministry of Economy, Industry and Competitiveness of Spain (MINECO) and co-financed by the European Investment Bank (EIB) and the European Social Fund (ESF). The contract of Carmen Serrano Hidalgo was funded by the Industrial PhD grant supported by the Autonomous Region of Madrid, Spain (IND2018/AMB-9553). This work is also a contribution to the Andalusian research groups RNM-308 (Group of Hydrogeology) and RNM-126 (Group of water resources), the Lower Guadalquivir Basin convention between the CN IGME CSIC and Confederación Hidrológica del Guadalquivir (CHG) as well as the convention between Pablo de Olavide University and the Guadalquivir River Basin Board (Hydrological monitoring and modeling in Doñana temporary ponds

Response of soil bacterial community composition and its associated geochemical parameters to rapid short-term cyclic groundwater-level oscillations: soil column experiments

Groundwater-level oscillations change geochemical conditions, carbon cycling processes and bacterial community composition, and these changes may vary vertically with depth in a soil. In this study, soil column experiments were conducted to explore variations in soil bacterial community composition and its associated geochemical parameters to rapid short-term cyclic groundwater-level oscillations driven by natural fluctuations (NF) and rainfall infiltration (RI) and the results are compared with quasi static (QS) column. Water saturation patterns in vadose and oscillated zones, and oxygen level patterns, soil total organic carbon (TOC) removal rates and soil bacterial community composition in vadose, oscillated and saturated zones were evaluated. Results showed that water saturation and oxygen level oscillated with groundwater level in NF and RI columns. TOC removal rates in RI column were the highest across vadose (~38.4%), oscillated (~35.8%) and saturated (~35.2%) zones. Deltaproteobacteria, which was significantly correlated with TOC removal (p < 0.05), exhibited relatively higher abundances in the vadose and oscillated zones of RI column than those of QS and NF columns. Soil bacterial community structure was dynamic at the class level due to water saturation, oxygen level and TOC removal. TOC removal was the driver to separate distribution of bacterial community structure in the vadose and oscillated zones of RI column from those of QS and NF columns. This study suggests that RI induced rapid short-term cyclic groundwater-level oscillations could significantly influence both soil carbon cycle and bacterial community structure in vadose and oscillated zones

The impact of hydrological conditions on salinisation and nitrate concentration in the coastal Velez River aquifer (southern Spain)

This study reports the impact of hydrological conditions on salinisation and nitrate concentrations of a coastal aquifer located at the Mediterranean Sea, southern Spain. Eighty-two samples of ground- and surface water taken during two extreme hydrological events between 1994 and 1996 at 25 different wells were evaluated with regard to hydrochemistry, focusing on nitrate concentrations and salinisation, which constitute the main hazard of this aquifer. Furthermore, hydrochemical data were analysed by principal component analysis (PCA). Additionally, in 2007 13 ground- and surface water samples taken at 12 different locations were analysed for stable isotopes of D/18O, and one sample was analysed for 15N. Since 1993 until present saltwater intrusion was observed only during dry hydrological conditions in 1994; it showed an irregular salinisation pattern probably related to locally elevated hydraulic conductivities. Nitrate concentrations increase significantly during wet hydrologic conditions owing to uptake of nitrate by rising groundwater. Stable isotopes of groundwater reveal an Atlantic origin of the precipitation that recharges the aquifer and a minor amount of groundwater recharge by the water coming from the La Viñuela reservoir, which is used for irrigation over the aquifer. 15N isotopes point to a considerable input of nitrates derived from organic fertilisers.Institute of Geological Sciences, Freie Universitát Berlin, AlemaniaInstituto del Agua, Universidad de Granada, EspañaUnidad de Murcia, Instituto Geológico y Minero de España, EspañaDepartmento de Geología, Universidad de Málaga, EspañaAlfred Wegener Institute, Alemani

The Sensitivity of Thermohaline Groundwater Circulation to Flow and Transport Parameters: A Numerical Study Based on Double-Diffusive Convection above a Salt Dome

This article explores double-diffusive convective fluid motion in an aquifer above a salt dome. Aside from the ambient regional flow regime, the hydraulic conditions in an aquifer connected with a salt formation are determined by differences in salinity. Whereas density-driven flow patterns induced by the effect of salt have been studied before we focus on the additional effect of temperature. For the model setup, we select typical parameter values that are characteristic of not only the lowlands in Germany and Poland. For the computation of flow in a vertical cross-section, we use numerical modeling with COMSOL Multiphysics. The size and strength of eddies in the high salinity region above the aquifer base are strongly influenced by thermal effects. A sensitivity study shows a wide range of convection phenomena, ranging from the absence of convective motions via steady and oscillating circulation to unsteady fluctuating patterns. The flow and transport parameters show the highest sensitivity to the thermal Rayleigh number

Einfluss wechselnder Wasserspiegelhoehen und schwankender Kapillarsaumbereiche auf die Grundwassergueteentwicklung von Speicherseen und Restseen im Lausitzer Braunkohlerevier Endbericht

Seasonal variations in the water levels of brown coal lakes result in oxidation, reduction and moisturizing processes in the resulting transition region. Additional oxygen supply involves a danger of enhanced acidification of pyritic/marcasitic sediments. The problem is particularly urgent in storage lakes, where water levels may vary by several meters. In dry years, low water may last for several months and may lead to permanent exposure of iron sulfide containing sediments. Careful and detailed studies are therefore required in the projecting stage in order to prevent supply shortages caused by regulation of the outfall ditches in maintenance of quality criteria. In this project, the Lohsa II storage system was analyzed by laboratory experiments and modelling in order to establish the effects of water level variations on water quality development. The data will be used in the further planning procedure for mining lake management especially in the Lausitz brown coal district. (orig.)Waehrend und nach der Durchfuehrung von Rekultivierungsmassnahmen an ehemaligen Braunkohletagebauen kann es betriebsbedingt oder saisonabhaengig zu Wasserspiegelschwankungen kommen. So entsteht ein wechselfeuchter Uebergangsbereich, in dem immer wieder Oxidations-, Reduktions- und Befeuchtungswechsel stattfinden. Aufgrund der Moeglichkeit der Nachlieferung von Luftsauerstoff besteht im Kontaktbereich mit pyrit/markasithaltigen Sedimenten eine erhoehte Versauerungsgefahr. Dies trifft sowohl auf Kippenbereiche, als auch auf gewachsene Sedimente zu, da durch die Wasserspiegelschwankungen ausreichend Feuchtigkeit und Sauerstoff fuer die Pyritverwitterung nachgeliefert wird. Ein besonderes Problem bilden die als Speicherseen vorgesehenen Restloecher, bei denen es zu Wasserspiegelschwankungen von mehreren Metern kommen kann. Die Nutzung des Speichervolumens zur Regulierung des Wasserhaushaltes der Vorfluter kann in trockenen Jahren zu einer viele Monate andauernden Absenkung des Wasserspiegels und damit zu einer dauerhaften Exposition von eisensulfidhaltigen Sedimenten fuehren. Fuer die Bewirtschaftung der Speicherseen muessen im Vorfeld detaillierte Untersuchungen durchgefuehrt werden, um etwaige Versorgungsengpaesse bei der Regulierung der Vorflutsysteme aufgrund von Qualitaetskriterien zu vermeiden. Am Beispiel des Speichersystems Lohsa II wurde der Einfluss von Wasserspiegelschwankungen auf die Entwicklung der Gewaesserguete mittels Laborversuchen und Modellierungen untersucht. Zudem wurden Felduntersuchungen durchgefuehrt, um soweit moeglich einen Vergleich zwischen Labor- und Insituvorgaengen zu erfassen. Im Rahmen des Projektes gewonnene Daten sollen einen grundlegenden Beitrag zur Planung der Bewirtschaftung von Speicherseen insbesondere im Lausitzer Braunkohlerevier liefern. (orig.)Available from TIB Hannover: F04B572+a / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekSIGLEBundesministerium fuer Bildung und Forschung (BMBF), Bonn (Germany)DEGerman

Control of trace metal distribution and variability in an interdunal wetland

[EN] Trace elements are serious pollutants in the natural environment and are of increasing concern due to the adverse effects at global scale. To refine the current understanding of trace metal distribution and variability in natural environments, concentrations of dissolved trace metals (Ag, Al, As, B, Ba, Be, Co, Cr, Cd, Cu, Fe, Hg, Mo, Ni, Pb, Sb, Se, Th,Tl, U, V, Mn, Zn), major ions, inorganic nutrients (NO3, PO4), TOC and stable isotopes of water were determined in water samples from rainwater, seven piezometers and a pond in the coastal Doñana wetland during four sampling campaigns between 2017 and 2019. Results show clear evaporation signatures of stable isotopes in the pond but not in the groundwater. Hydrochemical analyses yield significant, systematic changes in groundwater trace metal and nutrient composition along the flowpath from the dune belt to the pond, controlled by organic matter in the sediments. Whereas major ions reached maximum concentrations in the pond due to evapoconcentration, most trace metals showed highest concentrations at sites with lower redox levels, except for B, As and U, which showed very high concentrations in the pond. Cu, Zn, Ni, Sb and Tl yielded higher median concentrations in rainwater than in most of the groundwater points and in case of Cu and Zn higher even than in surface water which points to an atmospheric input source of these elements. Temporal variability of trace metals was related to lower hydraulic heads after an elongated dry period which led to lower redox levels and higher concentrations of most of the trace elements whereas major ions showed more constant concentration levels. This is of special concern regarding climate change and the predicted higher frequency of prolonged dry periods, which could modify the natural hydrochemical patterns in undisturbed wetlands systems.This work has been financed by the CLIGRO Project (MICINN, CGL2016-77473-C3-1-R) of the Spanish National Plan for Scientific and Technical Research and Innovation. The infrastructure has been co-financed by European Research Funds (SE Scientific Infrastructures and Techniques and Equipment 388 2013, IGME13-1E-2113). The contracts of Lidia Molano Leno (PEJ-2014-A-68763) and Daniel Jesus Martinez Suárez (PTA2014-09579-I) were financed by the Ministry of Economy, Industry and Competitiveness of Spain (MINECO) and co-financed by the European Investment Bank (EIB) and the European Social Fund (ESF). The contract of Carmen Serrano Hidalgo was funded by the Industrial PhD grant supported by the Autonomous Region of Madrid, Spain (IND2018/AMB-9553). This work is also a contribution to the Andalusian research groups RNM-308 (Group of Hydrogeology) and RNM-126 (Group of water resources), the Lower Guadalquivir Basin convention between the CN IGME CSIC and Confederación Hidrológica del Guadalquivir (CHG) as well as the convention between Pablo de Olavide University and the Guadalquivir River Basin Board (Hydrological monitoring and modeling in Doñana temporary ponds).Peer reviewe

A geochemical study of the impact of irrigation and aquifer lithology on groundwater in the Upper Yakima River Basin, Washington, USA

The Yakima River, a major tributary of the Columbia River, is currently overallocated in its surface water usage in part because of large agricultural water use. As a result, groundwater availability and surface water/groundwater interactions have become an important issue in this area. In several sub-basins, the Yakima River water is diverted and applied liberally to fields in the summer creating artificial recharge of shallow groundwater. Major ion, trace element, and stable isotope geochemistry of samples from 26 groundwater wells from a transect across the Yakima River and 24 surface waters in the Kittitas sub-basin were used to delineate waters with similar geochemical signatures and to identify surface water influence on groundwater. Major ion chemistry and stable isotope signatures combined with principal component analysis revealed four major hydrochemical groups. One of these groups, collected from shallow wells within the sedimentary basin fill, displays temporal variations in NO3 and SO4 along with high δ18O and δD values, indicating significant contribution from Yakima River and/or irrigation water. Two other major hydrochemical groups reflect interaction with the main aquifer lithologies in the basin: the Columbia River basalts (high-Na groundwaters), and the volcaniclastic rocks of the Ellensburg Formation (Ca–Mg–HCO3 type waters). The fourth major group has interacted with the volcaniclastic rocks and is influenced to a lesser degree by surface waters. The geochemical groupings constrain a conceptual model for groundwater flow that includes movement of water between underlying Columbia River basalt and deeper sedimentary basin fill and seasonal input of irrigation water

A hydrochemical approach to estimate mountain front recharge in an aquifer system in Tamilnadu, India

© 2017 Science Press, Institute of Geochemistry, CAS and Springer-Verlag GmbH Germany Mountain-front recharge (MFR) is a process of recharging an aquifer by infiltration of surface flow from streams and adjacent basins in a mountain block and along a mountain front (MF). This is the first attempt in India to estimate MFR along the foothills of Courtallam using hydrogeochemistry and geostatistical tools. The estimation of MFR has been carried out by collecting groundwater samples along the foothills of Courtallam. Collected water samples were analyzed for major cations and anions using standard procedures. Hydrogeochemical facies show the existence of four water types in this region. Calcium-rich water derived from gneissic rock terrain indicates significant recharge from higher elevation. Log pCO 2 and ionic strength of the samples were also calculated to identify the geochemical process. Majority of the collected samples have sodium-rich water and weak ionic strength, which indicate foothill recharge and low residence time. Silicate and carbonate weathering have an equal interplay along the foothills with a relatively large fraction of Mg from the MF. The spatial diagrams of three factors show that the southern part of the study area is dominated by both weathering and anthropogenic processes, whereas the northern part is dominated by both leaching and weathering processes. Thus, the dominant weathering process represented by the second factor indicates the large recharge process along the foothills