Antiferromagnetic order in (Ga,Mn)N nanocrystals: A density functional theory study

We investigate the electronic and magnetic properties of (Ga,Mn)N nanocrystals using the density functional theory. We study both wurtzite and zinc-blende structures doped with one or two substitutional Mn impurities. For a single Mn dopant placed close to surface, the behavior of the empty Mn-induced state, hereafter referred to as "Mn hole", is different from bulk (Ga,Mn)N. The energy level corresponding to this off-center Mn hole lies within the nanocrystal gap near the conduction edge. For two Mn dopants, the most stable magnetic configuration is antiferromagnetic, and this was unexpected since (Ga,Mn)N bulk shows ferromagnetism in the ground state. The surprising antiferromagnetic alignment of two Mn spins is ascribed also to the holes linked to the Mn impurities located close to surface. Unlike Mn holes in (Ga,Mn)N bulk, these Mn holes in confined (Ga,Mn)N nanostructures do not contribute to the ferromagnetic alignment of the two Mn spins

Optical spin control in nanocrystalline magnetic nanoswitches

We investigate the optical properties of (Cd,Mn)Te quantum dots (QDs) by looking at the excitons as a function of the Mn impurities positions and their magnetic alignments. When doped with two Mn impurities, the Mn spins, aligned initially antiparallel in the ground state, have lower energy in the parallel configuration for the optically active spin-up exciton. Hence, the photoexcitation of the QD ground state with antiparallel Mn spins induces one of them to flip and they align parallel. This suggests that (Cd,Mn)Te QDs are suitable for spin-based operations handled by light

First-principles calculations of the magnetic properties of (Cd,Mn)Te nanocrystals

We investigate the electronic and magnetic properties of Mn-doped CdTe nanocrystals (NCs) with 2 nm in diameter which can be experimentally synthesized with Mn atoms inside. Using the density-functional theory, we consider two doping cases: NCs containing one or two Mn impurities. Although the Mn d peaks carry five up electrons in the dot, the local magnetic moment on the Mn site is 4.65 mu_B. It is smaller than 5 mu_B because of the sp-d hybridization between the localized 3d electrons of the Mn atoms and the s- and p-type valence states of the host compound. The sp-d hybridization induces small magnetic moments on the Mnnearest- neighbor Te sites, antiparallel to the Mn moment affecting the p-type valence states of the undoped dot, as usual for a kinetic-mediated exchange magnetic coupling. Furthermore, we calculate the parameters standing for the sp-d exchange interactions. Conduction N0\alpha and valence N0\beta are close to the experimental bulk values when the Mn impurities occupy bulklike NCs' central positions, and they tend to zero close to the surface. This behavior is further explained by an analysis of valence-band-edge states showing that symmetry breaking splits the states and in consequence reduces the exchange. For two Mn atoms in several positions, the valence edge states show a further departure from an interpretation based in a perturbative treatment. We also calculate the d-d exchange interactions |Jdd| between Mn spins. The largest |Jdd| value is also for Mn atoms on bulklike central sites; in comparison with the experimental d-d exchange constant in bulk Cd0.95Mn0.05Te, it is four times smaller

Spatial sampling of the thermospheric vertical wind field at auroral latitudes

Results are presented from two nights of bistatic Doppler measurements of neutral thermospheric winds using Fabry!Perot spectrometers at Mawson and Davis stations in Antarctica. A scanning Doppler imager (SDI) at Mawson and a narrow-field Fabry-Perot spectrometer (FPS) at Davis have been used to estimate the vertical wind at three locations along the great circle joining the two stations, in addition to the vertical wind routinely observed above each station. These data were obtained from observations of the 630.0 nm airglow line of atomic oxygen, at a nominal altitude of 240 km. Low!resolution all-sky images produced by the Mawson SDI have been used to relate disturbances in the measured vertical wind field to auroral activity and divergence in the horizontal wind field. Correlated vertical wind responses were observed on a range of horizontal scales from ~150 to 480 km. In general, the behavior of the vertical wind was in agreement with earlier studies, with strong upward winds observed poleward of the optical aurora and sustained, though weak, downward winds observed early in the night. The relation between vertical wind and horizontal divergence was seen to follow the general trend predicted by Burnside et al. (1981), whereby upward vertical winds were associated with positive divergence and vice versa; however, a scale height approximately 3–4 times greater than that modeled by NRLMSISE-00 was required to best fit the data using this relation

Further refinements of the Heinz inequality

The celebrated Heinz inequality asserts that $2|||A^{1/2}XB^{1/2}|||\leq |||A^{\nu}XB^{1-\nu}+A^{1-\nu}XB^{\nu}|||\leq |||AX+XB|||$ for $X \in \mathbb{B}(\mathscr{H})$, A,B\in \+, every unitarily invariant norm $|||\cdot|||$ and $\nu \in [0,1]$. In this paper, we present several improvement of the Heinz inequality by using the convexity of the function $F(\nu)=|||A^{\nu}XB^{1-\nu}+A^{1-\nu}XB^{\nu}|||$, some integration techniques and various refinements of the Hermite--Hadamard inequality. In the setting of matrices we prove that \begin{eqnarray*} &&\hspace{-0.5cm}\left|\left|\left|A^{\frac{\alpha+\beta}{2}}XB^{1-\frac{\alpha+\beta}{2}}+A^{1-\frac{\alpha+\beta}{2}}XB^{\frac{\alpha+\beta}{2}}\right|\right|\right|\leq\frac{1}{|\beta-\alpha|} \left|\left|\left|\int_{\alpha}^{\beta}\left(A^{\nu}XB^{1-\nu}+A^{1-\nu}XB^{\nu}\right)d\nu\right|\right|\right|\nonumber\\ &&\qquad\qquad\leq \frac{1}{2}\left|\left|\left|A^{\alpha}XB^{1-\alpha}+A^{1-\alpha}XB^{\alpha}+A^{\beta}XB^{1-\beta}+A^{1-\beta}XB^{\beta}\right|\right|\right|\,, \end{eqnarray*} for real numbers $\alpha, \beta$.Comment: 15 pages, to appear in Linear Algebra Appl. (LAA

Thermospheric winds and temperatures above Mawson, Antarctica, observed with an all-sky imaging, Fabry-Perot spectrometer

A new all-sky imaging Fabry-Perot spectrometer has been installed at Mawson station (67°36' S, 62°52' E), Antarctica. This instrument is capable of recording independent spectra from many tens of locations across the sky simultaneously. Useful operation began in March 2007, with spectra recorded on a total of 186 nights. Initial analysis has focused on the large-scale daily and average behavior of winds and temperatures derived from observations of the 630.0 nm airglow line of atomic oxygen, originating from a broad layer centered around 240 km altitude, in the ionospheric F-region. <br><br> The 1993 Horizontal Wind Model (HWM93), NRLMSISE-00 atmospheric model, and the Coupled Thermosphere/Ionosphere Plasmasphere (CTIP) model were used for comparison. During the geomagnetically quiet period studied, observed winds and temperatures were generally well modelled, although temperatures were consistently higher than NRLMSISE-00 predicted, by up to 100 K. CTIP temperatures better matched our data, particularly later in the night, but predicted zonal winds which were offset from those observed by 70–180 ms<sup>−1</sup> westward. During periods of increased activity both winds and temperatures showed much greater variability over time-scales of less than an hour. For the active night presented here, a period of 45 min saw wind speeds decrease by around 180 ms<sup>−1</sup>, and temperatures increase by approximately 100 K. Active-period winds were poorly modelled by HWM93 and CTIP, although observed median temperatures were in better agreement with NRLMSISE-00 during such periods. <br><br> Average behavior was found to be generally consistent with previous studies of thermospheric winds above Mawson. The collected data set was representative of quiet geomagnetic and solar conditions. Geographic eastward winds in the afternoon/evening generally continued until around local midnight, when winds turned equatorward. Geographic meridional and zonal winds in the afternoon were approximately 50 ms<sup>−1</sup> weaker than expected from HWM93, as was the transition to equatorward flow around midnight. There was also a negligible geographic zonal component to the post-midnight wind where HWM93 predicted strong westward flow. Average temperatures between 19:00 and 04:00 local solar time were around 60 K higher than predicted by NRLMSISE-00

Dependence of exchange anisotropy and coercivity on the Fe–oxide structure in oxygen-passivated Fe nanoparticles

Ultrafine Fe particles have been prepared by the inert gas condensation method and subsequently oxygen passivated. The as-obtained particles consist in an Fe core surrounded by an amorphous Fe-oxide surface layer. The antiferromagnetic character of the Fe-oxide surface induces an exchange anisotropy in the ferromagnetic Fe core when the system is field cooled. Samples have been heat treated in vacuum at different temperatures. Structural changes of the Fe–O layer have been monitored by x-ray diffraction and transmission electron microscopy. Magnetic properties as coercivity, hysteresis loop shift, and evolution of magnetization with temperature have been analyzed for different oxide crystallization stages. A decrease of the exchange anisotropy strength is reported as the structural disorder of the surface oxide layer is decreased with thermal treatment