Patterson Function from Low-Energy Electron Diffraction Measured Intensities and Structural Discrimination

Surface Patterson Functions have been derived by direct inversion of experimental Low-Energy Electron Diffraction I-V spectra measured at multiple incident angles. The direct inversion is computationally simple and can be used to discriminate between different structural models. 1x1 YSi_2 epitaxial layers grown on Si(111) have been used to illustrate the analysis. We introduce a suitable R-factor for the Patterson Function to make the structural discrimination as objective as possible. From six competing models needed to complete the geometrical search, four could easily be discarded, achieving a very significant and useful reduction in the parameter space to be explored by standard dynamical LEED methods. The amount and quality of data needed for this analysis is discussed.Comment: 5 pages, 4 figure

Superconductivity and charge carrier localization in ultrathin La1.85Sr0.15CuO4/La2CuO4\mathbf{{La_{1.85}Sr_{0.15}CuO_4}/{La_2CuO_4}} bilayers

$\mathrm{La_{1.85}Sr_{0.15}CuO_4}$/$\mathrm{La_2CuO_4}$ (LSCO15/LCO) bilayers with a precisely controlled thickness of N unit cells (UCs) of the former and M UCs of the latter ([LSCO15\_N/LCO\_M]) were grown on (001)-oriented {\slao} (SLAO) substrates with pulsed laser deposition (PLD). X-ray diffraction and reciprocal space map (RSM) studies confirmed the epitaxial growth of the bilayers and showed that a [LSCO15\_2/LCO\_2] bilayer is fully strained, whereas a [LSCO15\_2/LCO\_7] bilayer is already partially relaxed. The \textit{in situ} monitoring of the growth with reflection high energy electron diffraction (RHEED) revealed that the gas environment during deposition has a surprisingly strong effect on the growth mode and thus on the amount of disorder in the first UC of LSCO15 (or the first two monolayers of LSCO15 containing one $\mathrm{CuO_2}$ plane each). For samples grown in pure $\mathrm{N_2O}$ gas (growth type-B), the first LSCO15 UC next to the SLAO substrate is strongly disordered. This disorder is strongly reduced if the growth is performed in a mixture of $\mathrm{N_2O}$ and $\mathrm{O_2}$ gas (growth type-A). Electric transport measurements confirmed that the first UC of LSCO15 next to the SLAO substrate is highly resistive and shows no sign of superconductivity for growth type-B, whereas it is superconducting for growth type-A. Furthermore, we found, rather surprisingly, that the conductivity of the LSCO15 UC next to the LCO capping layer strongly depends on the thickness of the latter. A LCO capping layer with 7~UCs leads to a strong localization of the charge carriers in the adjacent LSCO15 UC and suppresses superconductivity. The magneto-transport data suggest a similarity with the case of weakly hole doped LSCO single crystals that are in a so-called {"{cluster-spin-glass state}"

Routing in the Space Internet: A contact graph routing tutorial

A Space Internet is possible, as long as the delay and disruption challenges imposed by the space environment are properly tackled. Because these conditions are not well addressed by terrestrial Internet, more capable Delay-Tolerant Networking (DTN) protocols and algorithms are being developed. In particular, the principles and techniques for routing among ground elements and spacecraft in near-Earth orbit and deep-space are enacted in the Contact Graph Routing (CGR) framework. CGR blends a set of non-trivial algorithm adaptations, space operations concepts, time-dynamic scheduling, and specific graph models. The complexity of that framework suggests a need for a focused discussion to facilitate its direct and correct apprehension. To this end, we present an in-depth tutorial that collects and organizes first-hand experience on researching, developing, implementing, and standardizing CGR. Content is laid out in a structure that considers the planning, route search and management, and forwarding phases bridging ground and space domains. We rely on intuitive graphical examples, supporting code material, and references to flight-grade CGR implementations details where pertinent. We hope this tutorial will serve as a valuable resource for engineers and that researchers can also apply the insights presented here to topics in DTN research.Fil: Fraire, Juan Andres. Universidad Nacional de Córdoba. Facultad de Ciencias Exactas, Físicas y Naturales; Argentina. Universitat Saarland; AlemaniaFil: De Jonckère, Olivier. Technische Universität Dresden; AlemaniaFil: Burleigh, Scott C.. California Institute of Technology; Estados Unido

Ab-initio molecular dynamics simulation of hydrogen diffusion in α\alpha-iron

First-principles atomistic molecular dynamics simulation in the micro-canonical and canonical ensembles has been used to study the diffusion of interstitial hydrogen in $\alpha$-iron. Hydrogen to Iron ratios between $\theta=1/16 and 1/2 have been considered by locating interstitial hydrogen atoms at random positions in a$2 \times 2 \times 2$ supercell. We find that the average optimum absorption site and the barrier for diffusion depend on the concentration of interestitials. Iron Debye temperature decreases monotonically for increasing concentration of interstitial hydrogen, proving that iron-iron interatomic potential is significantly weakened in the presence of a large number of diffusing hydrogen atoms

Hydrogen in α\alpha-iron: stress and diffusion

First-principles density-functional theory has been used to investigate equilibrium geometries, total energies, and diffusion barriers for H as an interstitial impurity absorbed in $\alpha$-Fe. Internal strains/stresses upon hydrogen absorption are a crucial factor to understand preferred absorption sites and diffusion. For high concentrations, H absorbs near the octahedral site favoring a large tetragonal distortion of the BCC lattice. For low concentration, H absorbs near the tetrahedral site minimizing the elastic energy stored on nearby cells. Diffusion paths depend on the concentration regime too; hydrogen diffuses about ten times faster in the distorted BCT lattice. External stresses of several GPa modify barriers by $\approx$ 10%, and diffusion rates by $\approx$ 30%

The complex nature of the nuclear star cluster in FCC 277

Recent observations have shown that compact nuclear star clusters (NSCs) are present in up to 80% of galaxies. However, detailed studies of their dynamical and chemical properties are confined mainly to spiral galaxy hosts, where they are more easily observed. In this paper we present our study of the NSC in FCC 277, a nucleated elliptical galaxy in the Fornax cluster. We use a combination of adaptive optics assisted near-infrared integral field spectroscopy, Hubble Space Telescope imaging, and literature long slit data. We show that while the NSC does not appear to rotate within our detection limit of ~6 km/s, rotation is detected at larger radii, where the isophotes appear to be disky, suggesting the presence of a nuclear disk. We also observe a distinct central velocity dispersion drop that is indicative of a dynamically cold rotating sub-system. Following the results of orbit-based dynamical modelling, co-rotating as well as counter-rotating stellar orbits are simultaneously needed to reproduce the observed kinematics. We find evidence for varying stellar populations, with the NSC and nuclear disk hosting younger and more metal rich stars than the main body of the galaxy. We argue that gas dissipation and some level of merging have likely played an important role in the formation of the nucleus of this intermediate-mass galaxy. This is in contrast to NSCs in low-mass early- type galaxies, which may have been formed primarily through the infall of star clusters.Comment: 10 pages, 11 figures, MNRAS in press, changes to this version: co-author adde

Polymer brush collapse under shear flow

Shear responsive surfaces offer potential advances in a number of applications. Surface functionalisation using polymer brushes is one route to such properties, particularly in the case of entangled polymers. We report on neutron reflectometry measurements of polymer brushes in entangled polymer solutions performed under controlled shear, as well as coarse-grained computer simulations corresponding to these interfaces. Here we show a reversible and reproducible collapse of the brushes, increasing with the shear rate. Using two brushes of greatly different chain lengths and grafting densities, we demonstrate that the dynamics responsible for the structural change of the brush are governed by the free chains in solution rather than the brush itself, within the range of parameters examined. The phenomenon of the brush collapse could find applications in the tailoring of nanosensors, and as a way to dynamically control surface friction and adhesion

Cavography with hydrogen peroxide. Accidental injection of hydrogen peroxide into the inferior vena cava

Contrast cavography during removal of a vena cava filter in pa- tients treated via thrombectomy for pulmonary embolism is a widely performed procedure, which may involve potentially serious com- plications if the human factor fails. Accidental injection of hydrogen peroxide (H2O2) after mistaking it for contrast material can have fatal consequences. We present the case of a patient who was acciden- tally injected with a high quantity of hydrogen peroxide. The prepa- ration of a preoperative checklist, the amount of H202 injected and the operator’s skill in aspirating the substance are decisive factors in avoiding such complications